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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Combination Thermal Barrier And Wear Coatings For Engines

Thermal-barrier layers covered with self-lubricating surface layers. Zirconia thermal-barrier coat applied to surface of combustion chamber in engine by plasma-arc spraying. Then PS-200 plasma-arc sprayed onto zirconia. Self-lubricating coat prevents sliding contact between thermal barrier and piston ring, effectively preventing both wear and production of additional heat via friction. Other combinations of thermal-barrier and self-lubricating, wear-resistant coating materials used as long as two materials adhere to each other, applied by use of similar or compatible processes, have similar coefficients of thermal expansion, sufficiently strong at high temperatures, and affordable.

Weingart, Mike↗

Coating with overlay metallic-cermet alloy systems

A base layer of an oxide dispersed, metallic alloy (cermet) is arc plasma sprayed onto a substrate, such as a turbine blade, vane, or the like, which is subjected to high temperature use. A top layer of an oxidation, hot corrosion, erosion resistant alloy of nickel, cobalt, or iron is then arc plasma sprayed onto the base layer. A heat treatment is used to improve the bonding. The base layer serves as an inhibitor to interdiffusion between the protective top layer and the substrate. Otherwise, the 10 protective top layer would rapidly interact detrimentally with the substrate and degrade by spalling of the protective oxides formed on the outer surface at elevated temperatures.

Gedwill, M. A.↗

High-Emissivity Coatings For High-Temperature Surfaces

Plasma-sprayed coatings increase cooling by thermal radiation. Coating of zirconium diboride on tungsten or molybdenum increases emissivity of surface to more than 0.6 at 2,000 degree C. Applied by plasma-arc spraying after surface cleaned and roughened to ensure adhesion.

Deininger, William D.↗

Illuminating Development

Through the support of the NASA SBIR program, Control Vision, Inc. developed novel video techniques for clear, high resolution, real-time imaging of high temperature, high-energy industrial processes, such as welding, plasma arc spraying (coating), arc furnaces, metal casting and refractories (ceramics) melting. The Control Vision systems use reflected laser or strobe illumination, combined with ultra-short exposure times to create video, including the allowance of particle imaging velocimetry (PIV) of fast moving powder particles buried within a plasma stream.

Source record↗

Protective coating withstands high temperature in oxidizing atmosphere

Protective coating containing a plasma arc sprayed mixture of hafnium oxide and zirconium diboride will withstand high temperatures in an oxygen rich atmosphere. Used on a homogeneous tungsten thermocouple, it does not flake or crack on subsequent cooling and reheating, and does not degrade the thermocouple response time.

Mellor, C. H.↗

Heat-barrier coatings for combustion chambers

Arc-plasma-sprayed layered coating of graded Inconel and zirconia protects film-coolant ring below injector plate of rocket engine combustion chamber. Interfacial temperature is designed for minimum buildup of stress and to avoid melting of the metal phase in the graded layers.

Carpenter, H. W.↗

High-friction mechanical grips

Plasma-arc spraying offers method of preparing required surface at greatly reduced cost. Coarse-grained, tungsten carbide bonded-nickel coating is applied by spraying. Coating has been used successfully on wedge-shaped mechanical test grips.

Stevens, E. G.↗

Effective thermal conductivities of four metal ceramic composite coatings in hydrogen-oxygen rocket firings

An experimental investigation was conducted to determine the effective conductivities of four plasma-arc-sprayed, metal-ceramic gradated coatings on hydrogen-oxygen thrust chambers. The effective thermal conductivities were not a function of pressure or oxidant-to-fuel ratio. The various materials that made up these composites do not seem to affect the thermal conductivity values as much as the differences in the thermal conductivities of the parent materials would lead one to expect. Contact resistance evolving from the spraying process seems to be the controlling factor. The thermal conductivities of all the composites tested fell in the range of 0.75 to 7.5 watts per meter kelvin.

Schacht, R. L.↗

Ultimate intrinsic-coercivity samarium-cobalt magnet: An Earth-based feasibility study for space-shuttle missions

Techniques for containerless melting and solidification of the samarium-cobalt alloy without excessive oxidation were developed. The rationale for extending these experiments in a weightless environment is also discussed. The effect of oxygen content from 0.15 to 0.63 weight percent and grain size in the range of 2 to 10 micrometers has been examined on arc-plasma-sprayed SmCo5 magnets. Contrary to expectations, the larger grain sizes tended to improve the coercivities. This was attributed to an increase in homogeneity resulting from higher temperature treatments used to produce larger grain size. No significant differences in coercivity were observed on the basis of oxygen content in the range examined. It is expected that more meaningful data on the relationship between oxygen content and coercivity will be seen when the oxygen content can be lowered to less than 0.1 weight percent.

Das, D. K.↗

Rocket thrust chamber thermal barrier coatings

Subscale rocket thrust chamber tests were conducted to evaluate the effectiveness and durability of thin yttria stabilized zirconium oxide coatings applied to the thrust chamber hot-gas side wall. The fabrication consisted of arc plasma spraying the ceramic coating and bond coat onto a mandrell and then electrodepositing the copper thrust chamber wall around the coating. Chambers were fabricated with coatings .008, and .005 and .003 inches thick. The chambers were thermally cycled at a chamber pressure of 600 psia using oxygen-hydrogen as propellants and liquid hydrogen as the coolant. The thicker coatings tended to delaminate, early in the cyclic testing, down to a uniform sublayer which remained well adhered during the remaining cycles. Two chambers with .003 inch coatings were subjected to 1500 thermal cycles with no coating loss in the throat region, which represents a tenfold increase in life over identical chambers having no coatings. An analysis is presented which shows that the heat lost to the coolant due to the coating, in a rocket thrust chamber design having a coating only in the throat region, can be recovered by adding only one inch to the combustion chamber length.

Quentmeyer, R. J.↗

Microstructure and Wear Resistance of FeCrBSi Plasma-Sprayed Coating Remelted by Gas Tungsten Arc Welding Process

Herein, an FeCrBSi coating was fabricated via plasma spray on AISI1045 steel, and subsequently, a gas tungsten arc welding (GTA) process was employed to remelt the coating. The microstructure, microhardness, fracture toughness and surface roughness of the coating before and after remelting were investigated, as well as the wear resistance was tested by a UMT-3-type sliding wear apparatus. The results showed that, upon remelting, most defects in the as-sprayed coating were effectively eliminated, the surface roughness decreased by 43%, and the coating–substrate interface bonding changed from mechanical to metallurgical. The phase composition of the as-sprayed coating was primarily α-Fe and a small amount of hard Fe{sub 3}B phase, while the remelted coating consisted of α-Fe and (Fe,Cr){sub 23}C{sub 6} and a small quantity of CrB. In addition, remelting the coating was found to induce a 287.6% increase in the fracture toughness, a 33.4% increase in the average microhardness, and a 47.5% decrease in the wear volume, while the failure mechanism changed from abrasive wear to fatigue wear upon remelting. Therefore, GTA remelting of plasma-sprayed coating was found to be a feasible method to obtain a coating with good wear resistance.

36 MATERIALS SCIENCE↗

Morphology of zirconia particles exposed to D.C. arc plasma jet

Zirconia particles were sprayed into water with an arc plasma gun in order to determine the effect of various gun operating parameters on their morphology. The collected particles were examined by XRD and SEM techniques. A correlation was established between the content of spherical (molten) particles and the operating parameters by visual inspection and regression analysis. It was determined that the composition of the arc gas and the power input were the predominant parameters that affected the melting of zirconia particles.

Zaplatynsky, Isidor↗

Development of a 2 ns duration high current electron beam source using CsI coated carbon fibre cathode

A 50 ampere beam current having a rise time lesser than 500 pico-seconds with its energy 50 keV is generated using field emission mechanism. Beam duration was 2 ns. CsI coating on carbon fibre cathode was done using plasma spray coating. The results obtained from this cathode were compared to the carbon fibre cathode and the reason behind higher current density in the case of CsI coating has been explained. (author)

43 PARTICLE ACCELERATORS↗

Electrolytic Plasma Surface Polishing of Complex Components Produced by Selective Laser Melting

The applicability of electrolytic plasma surface polishing to complex components produced by selective laser melting (SLM) is analyzed. By electrolytic plasma polishing by electrolyte spraying, the surface quality of components produced by SLM may be improved. This technology is found to decrease the surface roughness from R{sub a} = 5.6 μm to 1.4 μm. The optimal pressure of the electrolyte jet is 0.02–0.05 MPa. At high pressures, the process becomes unstable. By electrolytic plasma polishing on the basis of electrolyte jets, uniform external and internal surface roughness of components produced by SLM may be ensured.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Preparation of the spacer for narrow electrode gap configuration in ionization-based gas sensor

Carbon nanotubes (CNTs) have started to be developed as the sensing element for ionization-based gas sensors due to the demand for improved sensitivity, selectivity, stability and other sensing properties beyond what can be offered by the conventional ones. Although these limitations have been overcome, the problems still remain with the conventional ionization-based gas sensors in that they are bulky and operating with large breakdown voltage and high temperature. Recent studies have shown that the breakdown voltage can be reduced by using nanostructured electrodes and narrow electrode gap. Nanostructured electrode in the form of aligned CNTs array with evenly distributed nanotips can enhance the linear electric field significantly. The later is attributed to the shorter conductivity path through narrow electrode gap. The paper presents the study on the design consideration in order to realize ionization based gas sensor using aligned carbon nanotubes array in an optimum sensor configuration with narrow electrode gap. Several deposition techniques were studied to deposit the spacer, the key component that can control the electrode gap. Plasma spray deposition, electron beam deposition and dry oxidation method were employed to obtain minimum film thickness around 32 {mu}m. For plasma spray method, sand blasting process is required in order to produce rough surface for strong bonding of the deposited film onto the surface. Film thickness, typically about 39 {mu}m can be obtained. For the electron beam deposition and dry oxidation, the film thickness is in the range of nanometers and thus unsuitable to produce the spacer. The deposited multilayer film consisting of copper, alumina and ferum on which CNTs array will be grown was found to be removed during the etching process. This is attributed to the high etching rate on the thin film which can be prevented by reducing the rate and having a thicker conductive copper film.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗