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Results for “PLASMA COMPOSITION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Observations of several unusual plasma compositional signatures within small interplanetary magnetic flux ropes

Interplanetary coronal mass ejections (ICMEs) often show unusual plasma compositional signatures (high He/P ratio, high O{sup 7+}/O{sup 6+} ratio, and high Fe charge states), and their enhanced charge states of oxygen and iron are caused by flare-related heating in the corona. We investigated the abnormal plasma composition of small interplanetary magnetic flux ropes (IMFRs) in terms of He/P ratio, O{sup 7+}/O{sup 6+} ratio, and mean Fe charge state. We discover that 18 of the 24 small IMFRs showed high He/P ratios. In addition, 12 and 8 of the 24 events showed high Fe charge states and O{sup 7+}/O{sup 6+} ratios, respectively. This observation implies that these small IMFRs and ICMEs may be caused by the same coronal eruptions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Composite plasma polymerized sulfonated polystyrene membrane for PEMFC

Highlights: • Methyl methane sulfonate (MMS) is used as the sulfonating agent. • The proton conductivity of the membrane is found to be 0.141 S cm{sup −1}. • Power density of fuel cell with styrene/MMS membrane is 0.5 W cm{sup −2}. • The membrane exhibits thermal stability up to 140 °C. - Abstract: This work presents the introduction of an organic compound methyl methane sulfonate (MMS) for the first time in fabrication of polystyrene based proton exchange membrane (PEM) by plasma polymerization process. The membrane is fabricated by co-polymerizing styrene and MMS in capacitively coupled continuous RF plasma. The chemical composition of the plasma polymerized polymer membrane is investigated using Fourier Transform Infrared Spectroscopy which reveals the formation of composite structure of styrene and MMS. The surface morphology studied using AFM and SEM depicts the effect of higher partial pressure of MMS on surface topography of the membrane. The proton transport property of the membrane studied using electrochemical impedance spectroscopy shows the achievement of maximum proton conductivity of 0.141 S cm{sup −1} which is comparable to Nafion 117 membrane. Fuel cell performance test of the synthesized membrane shows a maximum power density of 500 mW cm{sup −2} and current density of 0.62 A cm{sup −2} at 0.6 V.

36 MATERIALS SCIENCE↗
DOE OSTI2017

The Warm Plasma Composition in the Inner Magnetosphere during 2012–2015

Ionospheric heavy ions play an important role in the dynamics of Earth's magnetosphere. The greater mass and gyro radius of ionospheric oxygen differentiates its behavior from protons at the same energies. Oxygen may have an impact on tail reconnection processes, and it can at least temporarily dominate the energy content of the ring current during geomagnetic storms. At sub-keV energies, multi-species ion populations in the inner magnetosphere form the warm plasma cloak, occupying the energy range between the plasmasphere and the ring current. Lastly, cold lighter ions from the mid-latitude ionosphere create the co-rotating plasmasphere whose outer regions can interact with the plasma cloak, plasma sheet, ring current, and outer electron belt. Here in this paper we present a statistical view of warm, cloak-like ion populations in the inner magnetosphere, contrasting in particular the warm plasma composition during quiet and active times. We study the relative abundances and absolute densities of warm plasma measured by the Van Allen Probes, whose two spacecraft cover the inner magnetosphere from plasmaspheric altitudes close to Earth to just inside geostationary orbit. We observe that warm (>30 eV) oxygen is most abundant closer to the plasmasphere boundary whereas warm hydrogen dominates closer to geostationary orbit. Warm helium is usually a minor constituent, but shows a noticeable enhancement in the near-Earth dusk sector.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Inverse rendering of fusion plasmas: Inferring plasma composition from imaging systems

In this work, we develop a differentiable rendering pipeline for visualising plasma emission within tokamaks, and estimating the gradients of the emission and estimating other physical quantities. Unlike prior work, we are able to leverage arbitrary representations of plasma quantities and easily incorporate them into a non-linear optimisation framework. The efficiency of our method enables not only estimation of a physically plausible image of plasma, but also recovery of the neutral Deuterium distribution from imaging and midplane measurements alone. We demonstrate our method with three different levels of complexity showing first that a poloidal neutrals density distribution can be recovered from imaging alone, second that the distributions of neutral Deuterium, electron density and electron temperature can be recovered jointly, and finally, that this can be done in the presence of realistic imaging systems that incorporate sensor cropping and quantisation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2013

Plasma composition in a sigmoidal anemone active region

Using spectra obtained by the EUV Imaging Spectrometer (EIS) instrument onboard Hinode, we present a detailed spatially resolved abundance map of an active region (AR)-coronal hole (CH) complex that covers an area of 359'' × 485''. The abundance map provides first ionization potential (FIP) bias levels in various coronal structures within the large EIS field of view. Overall, FIP bias in the small, relatively young AR is 2-3. This modest FIP bias is a consequence of the age of the AR, its weak heating, and its partial reconnection with the surrounding CH. Plasma with a coronal composition is concentrated at AR loop footpoints, close to where fractionation is believed to take place in the chromosphere. In the AR, we found a moderate positive correlation of FIP bias with nonthermal velocity and magnetic flux density, both of which are also strongest at the AR loop footpoints. Pathways of slightly enhanced FIP bias are traced along some of the loops connecting opposite polarities within the AR. We interpret the traces of enhanced FIP bias along these loops to be the beginning of fractionated plasma mixing in the loops. Low FIP bias in a sigmoidal channel above the AR's main polarity inversion line, where ongoing flux cancellation is taking place, provides new evidence of a bald patch magnetic topology of a sigmoid/flux rope configuration.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Thermomagnetic instability of plasma composition gradients

In this paper, we show that, under Braginskii magneto-hydrodynamics, anti-parallel gradients in an average ion charge state and electron temperature can be unstable to the growth of self-generated magnetic fields. The instability is analogous to the field-generating thermomagnetic instability, although it is driven by the collisional thermal force magnetic source term rather than the Biermann battery term. The gradient in ion charge state causes a gradient in collisionality, which couples with temperature perturbations to create a self-generated magnetic field. This magnetic field deflects the electron heat flux in a way that reinforces the temperature perturbation. The derived linearized growth rate, typically on hydrodynamic timescales, includes resistive and thermal smoothing. It increases with large ion composition gradients and electron heat flux, conditions typical of the hohlraum walls or contaminant mix jets in inertial confinement fusion implosions. However, extended magneto-hydrodynamic simulations indicate that the instability is usually dominated and stabilized by nonlinear Nernst advection, in a similar manner to the standard thermomagnetic instability.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2017

The Evolution of the Plasma Sheet Ion Composition: Storms and Recoveries: Plasma Sheet Ion Composition

The ion plasma sheet (~few hundred eV to ~few 10s keV) is usually dominated by H + ions. Here, changes in ion composition within the plasma sheet are explored both during individual events, and statistically during 54 calm-to-storm events and during 21 active-to-calm events. Ion composition data from the HOPE (Helium, Oxygen, Proton, Electron) instruments onboard Van Allen Probes satellites provide exceptional spatial and temporal resolution of the H + , O + , and He + ion fluxes in the plasma sheet. H+ shown to be the dominant ion in the plasma sheet in the calm-to-storm transition. However, the energy-flux of each ion changes in a quasi-linear manner during extended calm intervals. Heavy ions (O + and He + ) become increasingly important during such periods as charge-exchange reactions result in faster loss for H + than for O + or He + . Results confirm previous investigations showing that the ion composition of the plasma sheet can be largely understood (and predicted) during calm intervals from knowledge of: (a) the composition of previously injected plasma at the onset of calm conditions, and (b) use of simple drift-physics models combined with calculations of charge-exchange losses.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2019

Determining Plasma Isotopic Composition from the Alfvén Oscillation Frequency in the TUMAN-3M Tokamak

We discuss the possibility of determining the evolution of the isotopic composition of plasma by the frequency of Alfvén oscillations in ohmic discharges in the compact TUMAN-3M tokamak with pulsed deuterium puffing into a hydrogen plasma and hydrogen puffing into a deuterium plasma. The isotopic ratios, i.e., relative concentrations of hydrogen n{sub H}/(n{sub H} + n{sub D}) and deuterium n{sub D}/(n{sub H} + n{sub D}) in the mixed hydrogen–deuterium plasma obtained by this method are in qualitative agreement with the results of spectroscopic measurements and neutral particle analysis data.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Effect of Ti-Al cathode composition on plasma generation and plasma transport in direct current vacuum arc

DC arc plasma from Ti, Al, and Ti{sub 1-x}Al{sub x} (x = 0.16, 0.25, 0.50, and 0.70) compound cathodes was characterized with respect to plasma chemistry and charge-state-resolved ion energy. Scanning electron microscopy, X-ray diffraction, and Energy-dispersive X-ray spectroscopy of the deposited films and the cathode surfaces were used for exploring the correlation between cathode-, plasma-, and film composition. Experimental work was performed at a base pressure of 10{sup −6} Torr, to exclude plasma-gas interaction. The plasma ion composition showed a reduction of Al of approximately 5 at. % compared to the cathode composition, while deposited films were in accordance with the cathode stoichiometry. This may be explained by presence of neutrals in the plasma/vapour phase. The average ion charge states (Ti = 2.2, Al = 1.65) were consistent with reference data for elemental cathodes, and approximately independent on the cathode composition. On the contrary, the width of the ion energy distributions (IEDs) were drastically reduced when comparing the elemental Ti and Al cathodes with Ti{sub 0.5}Al{sub 0.5}, going from ∼150 and ∼175 eV to ∼100 and ∼75 eV for Ti and Al ions, respectively. This may be explained by a reduction in electron temperature, commonly associated with the high energy tail of the IED. The average Ti and Al ion energies ranged between ∼50 and ∼61 eV, and ∼30 and ∼50 eV, respectively, for different cathode compositions. The attained energy trends were explained by the velocity rule for compound cathodes, which states that the most likely velocities of ions of different mass are equal. Hence, compared to elemental cathodes, the faster Al ions will be decelerated, and the slower Ti ions will be accelerated when originating from compound cathodes. The intensity of the macroparticle generation and thickness of the deposited films were also found to be dependent on the cathode composition. The presented results may be of importance for choice of cathodes for thin film depositions involving compound cathodes.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

The Composition of Plasma inside Geostationary Orbit Based on Van Allen Probes Observations

The composition of the inner magnetosphere is of great importance for determining the plasma pressure, and thus the currents and magnetic field configuration. In this study, we perform a statistical survey of equatorial plasma pressure distributions and investigate the relative contributions of ions and electron with different energies inside of geostationary orbit under two AE levels based on over sixty months of observations from the HOPE and RBSPICE mass spectrometers on board Van Allen Probes. We find that the total and partial pressures of different species increase significantly at high AE levels with Hydrogen (H + ) pressure being dominant in the plasmasphere. The pressures of the heavy ions and electrons increase outside the plasmapause and develop a strong dawn-dusk asymmetry with ion pressures peaking at dusk and electron pressure peaking at dawn. In addition, ring current H + with energies ranging from 50 keV up to several hundred keV is the dominant component of plasma pressure during both quiet (> 90%) and active times (> 60%), while Oxygen (O + ) with 10 < E < 50 keV and electrons with 0.1 < E < 40 keV become important during active times contributing more than 25% and 20% on the nightside, respectively, while the Helium (He + ) contribution is generally small. The results presented in this study provide a global picture of the equatorial plasma pressure distributions and the associated contributions from different species with different energy ranges, which advance our knowledge of wave generation and provide models with a systematic baseline of plasma composition.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Ionic composition of a humid air plasma under ionizing radiation

A kinetic model is proposed for ion–molecular processes involving charged particles of a humid air plasma produced by a fast electron beam. The model includes more than 600 processes involving electrons and 41 positive and 14 negative ions, including hydrated ions H{sub 3}O{sup +} (H{sub 2}O){sub n} and O{sub 2}{sup −}(H{sub 2}O){sub n} with n = 1, 2, …, 12. The energy costs of production of electron–ion pairs and electronic and vibrational (for water molecules, also rotational) excitation of molecules are calculated in nitrogen, oxygen, water vapor, air, and humid air. A method is proposed for calculating the energy costs in mixtures by the calculation data in pure gases. The evolution of the plasma composition is studied by the numerical solution of a system of 56 time-dependent balance equations for the number of charged particles of plasma by the fourth-order Runge–Kutta method. The steady-state composition of plasma is determined by solving nonlinear steady-state balance equations for the ionization rates of humid air from 10 to 10{sup 16} cm{sup –3}/s and the fraction of water molecules from 10{sup –3}% to 1.5%. It is established that, for water vapor content (the ratio of the number density of water molecules to the total number density of air molecules) of 0.015–1.5% in air at atmospheric pressure and room temperature, the main ion species are two types of positive ions H{sub 3}O{sup +} (H{sub 2}O){sub n} with the number of water molecules n = 5, 6 and three species of negative ions O{sub 2}{sup −}(H{sub 2}O){sub n} with n = 5, 8, 9.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

Functional composites of plasmas and metamaterials: Flexible waveguides, and variable attenuators with controllable phase shift

Numerical predictions and experimental results in this study verify that plasmas with negative permittivity work as functional media for electromagnetic waves and that their composites with metallic metamaterials show further extraordinary properties. Chain structures of individual plasmas with negative permittivity, forming a straight line and a L-shaped bent line, serve flexible waveguides via coupling structures of localized surface waves standing around each plasma. Further progresses as wave controllers are achievable in an array of the composites of plasmas and micro metallic resonators; functions of phase shifters and attenuators are individually controlled, with rotation of working points on the complex refractive index plane by varying gas conditions and permeability modulation. Such proposed sets of flexible combination will lead to advanced scientific products with novel functions.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Discovering tungsten-based composites as plasma facing materials for future high-duty cycle nuclear fusion reactors

Abstract Despite of excellent thermal properties and high sputtering resistance, pure tungsten cannot fully satisfy the requirements for plasma facing materials in future high-duty cycle nuclear fusion reactions due to the coupled extreme environments, including the high thermal loads, plasma exposure, and radiation damage. Here, we demonstrated that tungsten-based composite materials fabricated using spark-plasma sintering (SPS) present promising solutions to these challenges. Through the examination of two model systems, i.e., tungsten-zirconium composite for producing porous tungsten near the surface and dispersoid-strengthened tungsten, we discussed both the strengths and limitations of the SPS-fabricated materials. Our findings point towards the need for future studies aimed at optimizing the SPS process to achieve desired microstructures and effective control of oxygen impurities in the tungsten-based composite materials.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2015

Numerical calculation of ion runaway distributions

Ions accelerated by electric fields (so-called runaway ions) in plasmas may explain observations in solar flares and fusion experiments; however, limitations of previous analytic work have prevented definite conclusions. In this work, we describe a numerical solver of the 2D non-relativistic linearized Fokker-Planck equation for ions. It solves the initial value problem in velocity space with a spectral-Eulerian discretization scheme, allowing arbitrary plasma composition and time-varying electric fields and background plasma parameters. The numerical ion distribution function is then used to consider the conditions for runaway ion acceleration in solar flares and tokamak plasmas. Typical time scales and electric fields required for ion acceleration are determined for various plasma compositions, ion species, and temperatures, and the potential for excitation of toroidal Alfvén eigenmodes during tokamak disruptions is considered.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Resolving the bulk ion region of millimeter-wave collective Thomson scattering spectra at ASDEX Upgrade

Collective Thomson scattering (CTS) measurements provide information about the composition and velocity distribution of confined ion populations in fusion plasmas. The bulk ion part of the CTS spectrum is dominated by scattering off fluctuations driven by the motion of thermalized ion populations. It thus contains information about the ion temperature, rotation velocity, and plasma composition. To resolve the bulk ion region and access this information, we installed a fast acquisition system capable of sampling rates up to 12.5 GS/s in the CTS system at ASDEX Upgrade. CTS spectra with frequency resolution in the range of 1 MHz are then obtained through direct digitization and Fourier analysis of the CTS signal. We here describe the design, calibration, and operation of the fast receiver system and give examples of measured bulk ion CTS spectra showing the effects of changing ion temperature, rotation velocity, and plasma composition.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2017

Formation of Heliospheric Arcs of Slow Solar Wind

A major challenge in solar and heliospheric physics is understanding the origin and nature of the so-called slow solar wind. The Sun’s atmosphere is divided into magnetically open regions, known as coronal holes, where the plasma streams out freely and fills the solar system, and closed regions, where the plasma is confined to coronal loops. The boundary between these regions extends outward as the heliospheric current sheet (HCS). Measurements of plasma composition strongly imply that much of the slow wind consists of plasma from the closed corona that escapes onto open field lines, presumably by field-line opening or by interchange reconnection. Both of these processes are expected to release closed-field plasma into the solar wind within and immediately adjacent to the HCS. Mysteriously, however, slow wind with closed-field plasma composition is often observed in situ far from the HCS. We use high-resolution, three-dimensional, magnetohydrodynamic simulations to calculate the dynamics of a coronal hole with a geometry that includes a narrow corridor flanked by closed field and is driven by supergranule-like flows at the coronal-hole boundary. These dynamics produce giant arcs of closed-field plasma that originate at the open-closed boundary in the corona, but extend far from the HCS and span tens of degrees in latitude and longitude at Earth. We conclude that such structures can account for the long-puzzling slow-wind observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Characterization of plasma catalytic decomposition of methane: role of atomic O and reaction mechanism

In this work, we investigated atmospheric pressure plasma jet (APPJ)-assisted methane oxidation over a Ni-SiO 2 /Al 2 O 3 catalyst. We evaluated possible reaction mechanisms by analyzing the correlation of gas phase, surface and plasma-produced species. Plasma feed gas compositions, plasma powers, and catalyst temperatures were varied to expand the experimental parameters. Real-time Fourier-transform infrared spectroscopy was applied to quantify gas phase species from the reactions. The reactive incident fluxes generated by plasma were measured by molecular beam mass spectroscopy using an identical APPJ operating at the same conditions. A strong correlation of the quantified fluxes of plasma-produced atomic oxygen with that of CH 4 consumption, and CO and CO 2 formation implies that O atoms play an essential role in CH 4 oxidation for the investigated conditions. With the integration of APPJ, the apparent activation energy was lowered and a synergistic effect of 30% was observed. We also performed in-situ diffuse reflectance infrared Fourier-transform spectroscopy to analyze the catalyst surface. The surface analysis showed that surface CO abundance mirrored the surface coverage of CH n at 25 °C. This suggests that CH n adsorbed on the catalyst surface as an intermediate species that was subsequently transformed into surface CO. We observed very little surface CH n absorbance at 500 °C, while a ten-fold increase of surface CO and stronger CO 2 absorption were seen. This indicates that for a nickel catalyst at 500 °C, the dissociation of CH 4 to CHn may be the rate-determining step in the plasma-assisted CH 4 oxidation for our conditions. We also found the CO vibrational frequency changes from 2143 cm –1 for gas phase CO to 2196 cm –1 for CO on a 25 °C catalyst surface, whereas the frequency of CO on a 500 °C catalyst was 2188 cm –1 . Here, the change in CO vibrational frequency may be related to the oxidation of the catalyst.

methane oxidation↗
DOE OSTI2015

FIP BIAS EVOLUTION IN A DECAYING ACTIVE REGION

Solar coronal plasma composition is typically characterized by first ionization potential (FIP) bias. Using spectra obtained by Hinode’s EUV Imaging Spectrometer instrument, we present a series of large-scale, spatially resolved composition maps of active region (AR)11389. The composition maps show how FIP bias evolves within the decaying AR during the period 2012 January 4–6. Globally, FIP bias decreases throughout the AR. We analyzed areas of significant plasma composition changes within the decaying AR and found that small-scale evolution in the photospheric magnetic field is closely linked to the FIP bias evolution observed in the corona. During the AR’s decay phase, small bipoles emerging within supergranular cells reconnect with the pre-existing AR field, creating a pathway along which photospheric and coronal plasmas can mix. The mixing timescales are shorter than those of plasma enrichment processes. Eruptive activity also results in shifting the FIP bias closer to photospheric in the affected areas. Finally, the FIP bias still remains dominantly coronal only in a part of the AR’s high-flux density core. We conclude that in the decay phase of an AR’s lifetime, the FIP bias is becoming increasingly modulated by episodes of small-scale flux emergence, i.e., decreasing the AR’s overall FIP bias. Our results show that magnetic field evolution plays an important role in compositional changes during AR development, revealing a more complex relationship than expected from previous well-known Skylab results showing that FIP bias increases almost linearly with age in young ARs.

79 ASTRONOMY AND ASTROPHYSICS↗