Optical and infrared spectroscopy
Optical and infrared spectroscopic studies of single crystal fluoride perovskites and potassium compounds to determine transmission spectra and ferroelectricity
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Optical and infrared spectroscopic studies of single crystal fluoride perovskites and potassium compounds to determine transmission spectra and ferroelectricity
Desalination is considered a promising solution to alleviate water shortages, yet current methods are often restricted, due to challenges like high energy consumption, significant cost, or limited desalination capacity. In this study, we present a novel approach of redox flow desalination (RFD) utilizing the highly aqueous-soluble and reversible redox-active compound, potassium 1,1'-bis(sulfonate) ferrocene (1,1'-FcDS). This water-soluble organic compound yielded stable and rapid desalination, sustaining extended operation without notable decay and achieving an impressive desalination rate of up to 457.5 mmol·h -1 ·m -2 and energy consumption as low as 40.2 kJ·mol NaCl -1 . Specifically, the RFD device effectively desalinated a 50 mM NaCl solution to potable standards within 6000 s using 1,1'-FcDS. It maintained an average energy consumption of 178.16 kJ·mol NaCl -1 and exhibited negligible deterioration in desalination rate, energy efficiency, and charge efficiency throughout a rigorous 12,000 s cycling test. Furthermore, the versatility of this method was demonstrated by effectively treating saline water with varying initial concentrations from 10 mM to 50 mM, showcasing its potential across a broad spectrum of applications.
Oxygen recovery from potassium carbonate and potassium bromate by bromine trifluoride method
Analysis of oxygen in liquid alkali metals
Insulation material of fibrous potassium titanate and asbestos fibers bonded with colloidal silica for radiant heating environment protection
Development of battery systems with lithium anodes in nonaqueous electrolytes of propylene carbonate and potassium thiocyanate
Three-dimensional X-ray diffraction data to determine structure of crystal of potassium barium hexanitrocobaltate, discussing Jahn-Teller effect
Electrocaloric effect in single crystal of potassium di-hydrogen arsenate
Hydrogen-oxygen regenerative fuel cell - single cell tests, membrane fabrication, matrix screening test, and potassium titanate analytical tests
Cobalt 60 radiation effects on kinetics of thermal decomposition of potassium permanganate
Gallium arsenide, gallium phosphide, and potassium tantalate niobate crystals for electro-optic light modulator
Crystal structure of dipotassium tetranitroethide determined by single crystal X-ray diffraction techniques
Hydrogen-oxygen electrolytic regenerative fuel cells with potassium titanate and Teflon matrix structures
A fast, sensitive, simple, and highly reproducible method for routine assay of ammonium ion (NH4+) was developed by using HPLC equipment. The method is based on the reaction of NH4+ with o-phthalaldehyde (OPA) in the presence of 2-mercaptoethanol. After an on-line derivatization, the resulting NH4(+)-OPA product was quantified by using fluorometric or spectrophotometric detection. For fluorometric detection, the excitation and emission wavelengths were 410 and 470 nm, respectively. The spectrophotometric detection was made by measuring absorbance at 410 nm. Results on the effects of OPA-reagent composition and pH, reaction temperature, sample matrix, and linearity of the assay are presented. Even though it took about 2 min from the time of sample injection to the appearance of sample peak, sample injections could be overlapped at an interval of about 1 min. Thus, the actual time needed for analysis was about 1 min per assay. The method can be used in a fully automated mode by using an autosampler injector.
Recently, USDA ARS researchers genetically modified plums for rapid breeding work and noticed the plants could flower and develop fruit rapidly on relatively small plants. We have tested several of these genetically modified (GM) plums in plant chambers to assess their potential as a space crop. We have been able to clone these genetic lines using cuttings that are rooted using growth regulating compounds. Results showed that the GM plums indeed flower and fruit on small plants in controlled environments similar to what might be used in space, but they require cross-pollination with pollen from a standard plum. Analysis of stomatal conductance and leaf transpiration showed that water use went up in the light period, as expected, and but that GM types typically showed higher conductance than a standard plum. Analysis of tissue showed that fruit could be a good source of potassium and phenolic compounds, which could be beneficial as a bone loss countermeasure (Smith et al., 2014). These findings are all promising for using dwarf GM plums as a supplemental food for space, but further horticultural testing is needed before they are ready.
Near-ultraviolet, visible and infrared spectroscopy of sodium and potassium thiocyanate
Measuring nonequilibrium ionization and its effects in alkali metal, sodium potassium, and seeded argon plasma
Semicrystallinity gives rise to tough, solvent-resistant polymers. New polyimides prepared from reaction of aromatic dianhydrides with new diamines containing carbonyl and ether connecting groups between aromatic rings. Damines prepared from reaction of 4-aminophenol with activated aromatic difluoro compounds in presence of potassium carbonate. These types of polymers have potential applications in molded products, films, adhesives, and composites.