Containment system for experiments on radioactive and other hazardous materials in a Paris-Edinburgh press
Abstract not provided
Jacobsen, Matthew K.↗
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Ultra-low thermal conductivities of hot-pressed attapulgite and its potential as thermal insulation material
In the past, there have been very few reports on thermal properties of attapulgite which is a widely used clay mineral. In this work, we report on extremely low thermal conductivities in attapulgite samples synthesized by hot-pressing. Attapulgite powder was hot-pressed at different temperatures into bulk samples, and a systematic study was conducted on the microstructures and thermal properties. Differential scanning calorimetry analysis shows that hot-pressing induces a rapid dehydration of the attapulgite powders. X-ray diffraction data and scanning/transmission electron microscopy reveal that the hot-pressed attapulgite features high porosity and complex microstructures, including an amorphous phase. As a result, the hot-pressed attapulgite exhibits thermal conductivity less than 2.5Wm -1 K -1 up to 600 °C. For one sample with porosity of 45.7%, the thermal conductivity is as low as 0.34Wm -1 K -1 at 50 °C. Finally, this suggests the potential of hotpressed attapulgite as a candidate for thermal barrier materials.
36 MATERIALS SCIENCE↗
Consolidation of composite cathodes with NCM and sulfide solid-state electrolytes by hot pressing for all-solid-state Li metal batteries
In this study, hot pressing was evaluated as a method of cell fabrication to increase the energy density of next-generation all-solid-state batteries with NCM active material and sulfide solid-state electrolyte. Hot pressing involves consolidating glassy sulfide electrolyte by the application of pressure at a temperature above the electrolyte’s glass transition temperature. Typically, cell stacks are formed at room temperature and retain 15–30% porosity that limits cell energy density. On the other hand, the porosity of hot-pressed cell stacks is reduced to less than 10%. The electrochemical function of hot-pressed cathode composites was assessed as a function of active material and solid-state electrolyte compositions. Specifically, LiNi 0.85 Co 0.10 Mn 0.05 O 2 and LiNi 0.6 Co 0.2 Mn 0.2 O 2 were studied in combination with either glassy Li 7 P 3 S 11 , glassy Li 3 PS 4 , or β-Li 3 PS 4 solid-state electrolytes. Cathode composites composed of LiNi 0.6 Co 0.2 Mn 0.2 O 2 and Li 3 PS 4 maintained the best function after hot pressing at 200 °C and 370 MPa for 10 min. It was found that LiNi 0.6 Co 0.2 Mn 0.2 O 2 ’s resistance to microcracking and the inherent stability of Li 3 PS 4 ’s fully de-networked local structure are critical to maintain good electrochemical function after hot pressing. Furthermore, the results of this study show that hot pressing reduces porosity in the cathode composite and confirms the feasibility of cathode support of consolidated, reinforced glass separators.
25 ENERGY STORAGE↗
X-ray imaging for studying behavior of liquids at high pressures and high temperatures using Paris-Edinburgh press
Several X-ray techniques for studying structure, elastic properties, viscosity, and immiscibility of liquids at high pressures have been integrated using a Paris-Edinburgh press at the 16-BM-B beamline of the Advanced Photon Source. In this paper, we report the development of X-ray imaging techniques suitable for studying behavior of liquids at high pressures and high temperatures. White X-ray radiography allows for imaging phase separation and immiscibility of melts at high pressures, identified not only by density contrast but also by phase contrast imaging in particular for low density contrast liquids such as silicate and carbonate melts. In addition, ultrafast X-ray imaging, at frame rates up to ~10 5 frames/second (fps) in air and up to ~10 4 fps in Paris-Edinburgh press, enables us to investigate dynamics of liquids at high pressures. Very low viscosities of melts similar to that of water can be reliably measured. These high-pressure X-ray imaging techniques provide useful tools for understanding behavior of liquids or melts at high pressures and high temperatures.
47 OTHER INSTRUMENTATION↗
Properties of Veneered Flat Pressed Wood Plastic Composites by One-Step Process Pressing
The aim of this study was to develop, manufacture and determine properties of veneer overlaid flat pressed wood plastic composite (WPC) panels from recycled low density polyethylene (rLDPE), wood particles and different kinds of veneer (rotary-cut birch veneer and sliced oak veneer) using various adhesives by one-step hot pressing. Food packaging polyethylene film (PE film) as recycled stretch wraps, recycled low density polyethylene (rLDPE) particles and phenol formaldehyde (PF) resin were applied as adhesive for the bonding of veneer to the surface of WPC. No modification additives were used for the manufacture of WPC. It was found that compared with non-veneered WPC, the panels sandwiched with natural veneers greatly improved their properties. The bending strength was improved in 1.9–2.6 and 7.9–10 times across and along veneer fibers respectively for both types of investigated veneer. The highest values of bending strength were observed in WPC panels veneered with rotary-cut birch veneer. However, the water resistance of veneered WPC panels was reduced in comparison with non-veneered. The WPC specimens veneered with both types of veneer using PE film had better mechanical properties and water resistance than those of the specimens made with other two types of adhesives. The veneering of WPC panels enables to significantly improve adhesion properties of these veneered surfaces for their further finishing. In addition, the veneering of WPC panels hides the surface defects and provides a uniform application of different paints, varnishes and films to the surface of such materials. Overlaying WPC panels with wood veneers improves their appearance and properties resulting in eco-friendly value-added products.
36 MATERIALS SCIENCE↗
Low-resistivity bulk silicon prepared by hot-pressing boron- and phosphorus-hyperdoped silicon nanocrystals
Technologically important low-resistivity bulk Si has been usually produced by the traditional Czochralski growth method. We now explore a novel method to obtain low-resistivity bulk Si by hot-pressing B- and P-hyperdoped Si nanocrystals (NCs). In this work bulk Si with the resistivity as low as ∼ 0.8 (40) mΩ•cm has been produced by hot pressing P (B)-hyperdoped Si NCs. The dopant type is found to make a difference for the sintering of Si NCs during the hot pressing. Bulk Si hot-pressed from P-hyperdoped Si NCs is more compact than that hot-pressed from B-hyperdoped Si NCs when the hot-pressing temperature is the same. This leads to the fact that P is more effectively activated to produce free carriers than B in the hot-pressed bulk Si. Compared with the dopant concentration, the hot-pressing temperature more significantly affects the structural and electrical properties of hot-pressed bulk Si. With the increase of the hot-pressing temperature the density of hot-pressed bulk Si increases. The highest carrier concentration (lowest resistivity) of bulk Si hot-pressed from B- or P-hyperdoped Si NCs is obtained at the highest hot-pressing temperature of 1050 °C. The mobility of carriers in the hot-pressed bulk Si is low (≤ ∼ 30 cm{sup -2}V{sup -1}s{sup -1}) mainly due to the scattering of carriers induced by structural defects such as pores.
36 MATERIALS SCIENCE↗
Expanded Analysis of Hot Isostatic Pressed Iodine-Loaded Silver-Exchanged Mordenite
Reduced silver-exchanged mordenite (Ag0Z) is being evaluated as a potential material to control the release of radioactive iodine that is released during the reprocessing of used nuclear fuel into the plant off-gas streams. The purpose of this study was to determine if hot pressing could directly convert this iodine loaded sorbent into a waste form suitable for long-term disposition. The minimal pretreatment required for production of pressed pellets makes hot pressing a technically and economically desirable process. Initial scoping studies utilized hot uniaxial pressing (HUPing) to prepare samples of non-iodine-loaded reduced silver exchanged mordenite (Ag0Z). The resulting samples were very fragile due to the low pressure (~ 28 MPa) used. It was recommended that hot isostatic pressing (HIPing), performed at higher temperatures and pressures, be investigated. HIPing was carried out in two phases, with a third and final phase currently underway. Phase I evaluated the effects of pressure and temperature conditions on the manufacture of a pressed sample. The base material was an engineered form of silver zeolite. Six samples of Ag0Z and two samples of I-Ag0Z were pressed. It was found that HIPing produced a pressed pellet of high density. Analysis of each pressed pellet by scanning electron microscopy-energy dispersive spectrophotometry (SEM-EDS) and X-ray diffraction (XRD) demonstrated that under the conditions used for pressing, the majority of the material transforms into an amorphous structure. The only crystalline phase observed in the pressed Ag0Z material was SiO2. For the samples loaded with iodine (I-Ag0Z) iodine was present as AgI clusters at low temperatures, and transformed into AgIO4 at high temperatures. Surface mapping and EDS demonstrate segregation between silver iodide phases and silicon dioxide phases. Based on the results of the Phase I study, an expanded test matrix was developed to examine the effects of multiple source materials, compositional variations, and an expanded temperature range. Each sample was analyzed with the approach used in Phase I. In all cases, there is nothing in the SEM or XRD analyses that indicates creation of any AgI-containing silicon phase, with the samples being found to be largely amorphous. Phase III of this study has been initiated and is the final phase of scoping tests. It will expand upon the test matrix completed in Phase II and will examine the durability of the pressed pellets through product consistency testing (PCT) studies. Transformation of the component material into a well-characterized iodine-containing mineral phase would be desirable. This would limit the additional experimental testing and modeling required to determine the long-term stability of the pressed pellet, as much of that information has already been learned for several common iodine-containing minerals. However, this is not an absolute requirement, especially if pellets produced by hot isostatic pressing can be demonstrated through initial PCT studies to retain iodine well despite their amorphous composition.
hot isostatic pressing↗
Influence of velocity of pressing in RCS processed AA8090 Al-Li alloy
Highlights: • For the first time the Influence of RCS on the properties of AA 8090 has been studied by processing velocity. • It is found that the properties vary according to pressing velocity and number of passes. • Reported significant property improvement achieved through the pressing velocity of 1.5mm/s. - Abstract: The effect of the velocity of pressing on grain refinement in AA8090 Al-Li alloy sheets during repetitive corrugation and straightening (RCS) at 300 °C is studied. V-groove corrugation dies and flattening dies were used at three different pressing velocities of 1.5 mm/s, 2 mm/s and 2.5 mm/s. The specimen temperature was maintained at 300 °C. Grain refinement was significantly influenced by the pressing velocity. The samples processed for 8 passes at a pressing velocity of 1.5 mm/s had an improved microhardness value of 104 HV and an increased tensile strength of 405 MPa which is respectively 39% and 113% more than the corresponding values in the parent material. TEM analysis showed that samples processed at a pressing velocity of 1.5 mm/s had in places a grain size down to 50 nm and the EBSD results revealed that the average grain size was 2 μm, with 86% of the total number of grain boundaries of the high angle type.
36 MATERIALS SCIENCE↗
Enery Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications
This is the final technical report for the Department of Energy NETL project NT01931 Energy Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications. Titanium has been identified as one of the key materials with the required strength that can reduce the weight of automotive components and thereby reduce fuel consumption. Working with newly developed sources of titanium powder, Webster-Hoff will develop the processing technology to manufacture low cost vehicle components using the single press/single sinter techniques developed for iron based powder metallurgy today. Working with an automotive or truck manufacturer, Webster-Hoff will demonstrate the feasibility of manufacturing a press and sinter titanium component for a vehicle application. The project objective is two-fold, to develop the technology for manufacturing press and sinter titanium components, and to demonstrate the feasibility of producing a titanium component for a vehicle application. The lowest cost method for converting metal powder into a net shape part is the Powder Metallurgy Press and Sinter Process. The method involves compaction of the metal powder in a tool (usually a die and punches, upper and lower) at a high pressure (up to 60 TSI or 827 MPa) to form a green compact with the net shape of the final component. The powder in the green compact is held together by the compression bonds between the powder particles. The sinter process then converts the green compact to a metallurgically bonded net shape part through the process of solid state diffusion. The goal of this project is to expand the understanding and application of press and sinter technology to Titanium Powder applications, developing techniques to manufacture net shape Titanium components via the press and sinter process. In addition, working with a vehicle manufacturer, demonstrate the feasibility of producing a titanium component for a vehicle. This is not a research program, but rather a project to develop a process for press and sinter of net shape Titanium components. All of these project objectives have been successfully completed.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Proof Testing of Small-Scale HE Press Shielding
High explosives pressing activities at Los Alamos National Laboratory have played a critical role in meeting the core missions of the lab since its early days. Small scale pressing (25 grams of energetic material or less) constitutes a significant portion of current production and much of this occurs as an attended operation. Workers that are present during HE pressing operations are to be protected from blast and fragment dangers associated with the potential violent reaction of the energetic material being pressed. Safety is paramount in all HE operations, and the ongoing evolution of analysis and mitigation of hazards contributes strongly to the development of adequate protections for personnel. Attended pressing operations satisfying Class 1 Level Protection criteria, until recently, have been allowed for small scale pressing activities on the basis of an undocumented design of shielding enclosures used at LANL. Recent review of the shield design has determined the necessity of proof testing an adequate enclosure and thoroughly documenting the test results and fabrication specifications. This will provide a basis for continuing attended operations and guidance for future design iterations. The results of the testing described in this report provide sufficient assurance that the new shield design is adequate to protect attendant workers against injury from direct blast and fragments resulting from full detonation of the maximum allowable mass of explosives (less than 25 grams) confined in a uniaxial pressing configuration typical for Los Alamos National Laboratory.
42 ENGINEERING↗
Process design of press hardening with gradient material property influence
Press hardening is currently used in the production of automotive structures that require very high strength and controlled deformation during crash tests. Press hardening can achieve significant reductions of sheet thickness at constant strength and is therefore a promising technology for the production of lightweight and energy-efficient automobiles. The manganese-boron steel 22MnB5 have been implemented in sheet press hardening owing to their excellent hot formability, high hardenability, and good temperability even at low cooling rates. However, press-hardened components have shown poor ductility and cracking at relatively small strains. A possible solution to this problem is a selective increase of steel sheet ductility by press hardening process design in areas where the component is required to deform plastically during crash tests. To this end, process designers require information about microstructure and mechanical properties as a function of the wide spectrum of cooling rates and sequences and austenitizing treatment conditions that can be encountered in production environments. In the present work, a Continuous Cooling Transformation (CCT) diagram with corresponding material properties of sheet steel 22MnB5 was determined for a wide spectrum of cooling rates. Heating and cooling programs were conducted in a quenching dilatometer. Motivated by the importance of residual elasticity in crash test performance, this property was measured using a micro-bending test and the results were integrated into the CCT diagrams to complement the hardness testing results. This information is essential for the process design of press hardening of sheet components with gradient material properties.
36 MATERIALS SCIENCE↗
Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments
We developed a six-axis multi-anvil press, ATSUHIME, for high-pressure and high-temperature in situ time-of-flight neutron powder diffraction experiments. The press has six orthogonally oriented hydraulic rams that operate individually to compress a cubic sample assembly. Experiments indicate that the press can generate pressures up to 9.3 GPa and temperatures up to 2000 K using a 6-6-type cell assembly, with available sample volume of about 50 mm{sup 3}. Using a 6-8-type cell assembly, the available conditions expand to 16 GPa and 1273 K. Because the six-axis press has no guide blocks, there is sufficient space around the sample to use the aperture for diffraction and place an incident slit, radial collimators, and a neutron imaging camera close to the sample. Combination of the six-axis press and the collimation devices realized high-quality diffraction pattern with no contamination from the heater or the sample container surrounding the sample. This press constitutes a new tool for using neutron diffraction to study the structures of crystals and liquids under high pressures and temperatures.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗