Effects of various additives on physical properties and performance of monomethylhydrazine
Effects of various additives on physical properties of monomethyl hydrazine liquid propellant - nitrogen compounds and water
NITROGEN COMPOUND↗
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Surveyor Vernier engine fuel blend - A constrained optimization.
Propellant composition variation for improving cooling characteristics of Surveyor vernier propulsion system
PROPELLANT COMPOUND↗
A History of Space Toxicology Mishaps: Lessons Learned and Risk Management
After several decades of human spaceflight, the community of space-faring nations has accumulated a diverse and sometimes harrowing history of toxicological events that have plagued human space endeavors almost from the very beginning. Lessons have been learned in ground-based test beds and others were discovered the hard way - when human lives were at stake in space. From such lessons one can build a risk-management framework for toxicological events to minimize the probability of a harmful exposure, while recognizing that we cannot foresee all events. Space toxicologists have learned that relatively harmless compounds can be converted by air revitalization systems into compounds that cause serious harm to the crew. Our toxic risk management strategy now includes an assessment of the fate of any compound that might be released into the atmosphere. Propellants are highly toxic compounds, yet we have not always been able to thoroughly isolate the crew from exposure to these toxicants. Leakage of fluids from systems has resulted in hazardous conditions at times, and the behavior of such compounds inside a spacecraft has taught us how to manage potentially harmful escapes should they occur. Potential combustion events are an ever-present threat to the wellbeing of the crew. Such events have been sufficiently common that we have learned that one cannot judge the health threat of a given fire by the magnitude of the event. Management of such risks demands monitoring of combustion products. In the category of unpredictable toxic events, if one assumes that fires are predictable, we can place experience with toxic microbial metabolites, upsets during repair operations, and discharges from filters that have accumulated a substantial load of pollutants in their absorption beds. Management of such events requires a broad-spectrum, real-time analytical capability to discern the identity and concentrations of pollutants if they enter the atmosphere. Adverse events are an integral part of any human activity, and the spacefaring community must learn as much as possible from mistakes and near misses.
James, John T.↗
Suppressants for lowering propellant binder burning rate
Addition of boron compound to lower burning rate of solid propellant binder is reported. Chemical reactions involved in propellant binder modification are described. Advantages of method for lowering burning rate are analyzed.
Thompson, W. W.↗
A basic study of the nitrogen tetroxide- hydrazine reaction
Hydrazine-nitrogen tetroxide rocket propellant reaction study
NITROGEN COMPOUND↗
Managing Toxicological Risks: The Legacy of Shuttle Operations
Space toxicology greatly matured as a result of research and operations associated with the Shuttle. Materials offgassing had been a manageable concern since the Apollo days, but we learned to pay careful attention to compounds that could escape containment, to combustion events, to toxic propellants, to overuse of utility compounds, and to microbial and human metabolites. We also learned that flying real-time hardware to monitor air pollutants was a pathway with unanticipated speed bumps. Each new orbiter was tested for any excess offgassing products that could pollute the air during flight. In the late 1990s toxicologists and safety experts developed a 5-level toxicity rating system to guide containment of toxic compounds. This system is now in use aboard the International Space Station (ISS). Several combustion events during Shuttle Mir and also during Shuttle free-flight impelled toxicologists to identify hardware capable of monitoring toxic products; however, rapid adaptation of the hardware for the unique conditions of spaceflight caused unexpected missteps. Current and planned combustion analyzers would be useful to commercial partners that wish to manage the risk of health effects from thermal events. Propellants received special attention during the Shuttle program because of the possibility of bringing them into the habitable volume on extravehicular activity suits. Monitors for the airlocks were developed to mitigate this risk. Utility materials, such as lubricants, posed limited toxicological problems because water was not recovered. One clearly documented case of microbial metabolites polluting the Shuttle atmosphere was noted, and this has implications for commercial flights and control of microbes. Finally, carbon dioxide, the major human metabolite, episodically presented air quality problems aboard Shuttle, especially when nominal air flows were obstructed. Commercial vehicles must maintain robust air circulation given the anticipated high density of human occupants.
James, John T.↗
A study of solid-propellant vaporization and diffusion processes Final technical report
Vaporization rate and diffusion coefficient determined for organic additives to polyurethane solid propellants - dioctyl adipate and ferrocene
SOLID PROPELLANT↗
NASA Advanced Explorations Systems: Concepts for Logistics to Living
The NASA Advanced Exploration Systems (AES) Logistics Reduction and Repurposing (LRR) project strives to enable a largely mission-independent cradle-to-grave-to-cradle approach to minimize logistics contributions to total mission architecture mass. The goals are to engineer logistics materials, common crew consumables, and container configurations to meet the following five basic goals: 1. Minimize intrinsic logistics mass and improve ground logistics flexibility. 2. Allow logistics components to be directly repurposed for on-orbit non-logistics functions (e.g., crew cabin outfitting) thereby indirectly reducing mass/volume. 3. Compact and process logistics that have not been directly repurposed to generate useful on-orbit components and/or compounds (e.g., radiation shielding, propellant, other usable chemical constituents). 4. Enable long-term stable storage and disposal of logistics end products that cannot be reused or repurposed (e.g., compaction for volume reduction, odor control, and maintenance of crew cabin hygienic conditions). 5. Allow vehicles in different mission phases to share logistics resources. This paper addresses the work being done to meet the second goal, the direct repurposing of logistics components to meet other on-orbit needs, through a strategy termed Logistics to Living (L2L). L2L has several areas but can be defined as repurposing or converting logistical items (bags, containers, foam, components, etc.) into useful crew items or life support augmentation on-orbit after they have provided their primary logistics function. The intent is that by repurposing items, dedicated crew items do not have to be launched and overall launch mass is decreased. For non-LEO missions, the vehicle interior volume will be relatively fixed so L2L will enable this volume to be used more effectively through reuse and rearrangement of logistical components. Past work in the area of L2L has already conceptually developed several potential technologies [Howe, Howard 2010]. Several of the L2L concepts that have shown the most potential in the past are based on NASA cargo transfer bags (CTBs) or their equivalents which are currently used to transfer cargo to and from the ISS. A high percentage of all logistics supplies are packaging mass and for a 6-month mission a crew of four might need over 100 CTBs. These CTBs are used for on-orbit transfer and storage but eventually becomes waste after use since down mass is very limited. The work being done in L2L also considering innovative interior habitat construction that integrate the CTBs into the walls of future habitats. The direct integration could provide multiple functions: launch packaging, stowage, radiation protection, water processing, life support augmentation, as well as structure. Reuse of these CTBs would reduce the amount of waste generated and also significantly reduce future up mass requirements for exploration missions. Also discussed here is the L2L water wall , an innovative reuse of an unfolded CTB as a passive water treatment system utilizing forward osmosis. The bags have been modified to have an inner membrane liner that allows them to purify wastewater. They may also provide a structural water-wall element that can be used to provide radiation protection and as a structural divider. Integration of the components into vehicle/habitat architecture and consideration of operations concepts and human factors will be discussed. In the future these bags could be designed to treat wastewater, concentrated brines, and solid wastes, and to dewater solid wastes and produce a bio-stabilized construction element. This paper will describe the follow-on work done in design, fabrication and demonstrations of various L2L concepts, including advanced CTBs for reuse/repurposing, internal outfitting studies and the CTB-based forward osmosis water wall.
Shull, Sarah A.↗
Versatile Nuclear Thermal Propulsion (NTP)
A study was initiated to investigate propulsion stage and mission architecture options potentially enabled by fission energy. One initial concept is a versatile Nuclear Thermal Propulsion (NTP) system with a maximum specific impulse of 900 s and a maximum thrust (per engine) of 15 klbf. The system assumes a monopropellant stage (hydrogen), and is designed to also provide 300 lbf of thrust (potentially split between multiple thrusters) at an Isp > 500 s for orbital maneuvering and station keeping. Boost pumps are used to assist with engine decay heat removal and low thrust engine burns, and to compensate for partial tank depressurization during full thrust engine burns. Potential stage assembly orbits that take full advantage of launch vehicle payload mass and volume capabilities are being assessed. The potential for using NTP engines to also generate a small to moderate amount of electrical power is also being evaluated. A first generation versatile NTP stage could enable 8 of 9 upcoming opportunities for short (less than 24 month) round trip human missions to Mars. A second generation versatile NTP is under consideration that could potentially provide a maximum specific impulse of 1800 s at 15 klbf, and enable ambitious missions throughout the solar system. The second generation NTP system under consideration would also allow a choice of volatiles to be used as propellant. This would potentially allow in-situ resources such as water, ammonia, methane, or other compounds to be used directly as propellant by the second generation engine.
Houts, Michael G.↗
Versatile Nuclear Thermal Propulsion (NTP)
A study was initiated to investigate propulsion stage and mission architecture options potentially enabled by fission energy. One initial concept is a versatile Nuclear Thermal Propulsion (NTP) system with a maximum specific impulse of 900 s and a maximum thrust (per engine) of 15 klbf. The system assumes a monopropellant stage (hydrogen), and is designed to also provide 300 lbf of thrust (potentially split between multiple thrusters) at an Isp > 500 s for orbital maneuvering and station keeping. Boost pumps are used to assist with engine decay heat removal and low thrust engine burns, and to compensate for partial tank depressurization during full thrust engine burns. Potential stage assembly orbits that take full advantage of launch vehicle payload mass and volume capabilities are being assessed. The potential for using NTP engines to also generate a small to moderate amount of electrical power is also being evaluated. A first generation versatile NTP stage could enable 8 of 9 upcoming opportunities for short (less than 24 month) round trip human missions to Mars. A second generation versatile NTP is under consideration that could potentially provide a maximum specific impulse of 1800 s at 15 klbf, and enable ambitious missions throughout the solar system. The second generation NTP system under consideration would also allow a choice of volatiles to be used as propellant. This would potentially allow in-situ resources such as water, ammonia, methane, or other compounds to be used directly as propellant by the second generation engine.
Houts, Mike↗
Review of the Toxicity of the Metallic Compounds Proposed for Use in the New Green Missile Formulation
In an effort to modernize and minimize hazards posed by the toxic components of missile propellant, the USACHPPM has been tasked to provide a comparison of the toxicity of compounds currently in use as missile propellants and the suite of compounds proposed to replace them. This report deals with the portion of this work concerning the toxicity of the organometallic compounds used in these formulations. Toxicity assessments of the organic compounds used in these formulations are published elsewhere. In general, toxicity data were available for all the metal compounds of concern or for closely related compounds that can serve as surrogates for the assessment of toxicity. We have high confidence in the reliability of these comparisons. This report is organized by element to provide the reader with an in-depth assessment with a minimum of redundancy. The narrative will first describe general concepts about the toxicity of each metal and then provide a summary of the toxicological information available for the specific compound.
Major, Michael A.↗
Mitigating Problems in Measuring Hypergolic Fuels
To monitor hydrazine concentrations accurately and safely, hydrazine is converted into a stable derivative that will be monitored and correlated to the actual hydrazine concentration. The hydrazine's reactivity is harnessed to produce a chemical reaction that will form a stable gas-phase derivative which will not react or decompose before it reaches the detector. Hydrazine, monomethylhydrazine, and unsymmetrical dimethylhydrazine belong to a class of compounds known as hypergolic fuels. These fuels self-ignite upon mixing with hypergolic oxidizer (dinitrogen tetroxide), without need of a spark or other ignition source. The resulting reaction produces thrust with exceptionally high energy, making these compounds particularly useful as rocket propellants. Hydrazines are also highly toxic and corrosive. The combined properties of reactivity, corrosivity, and toxicity present the potential for a leak, a disastrous situation in a hypergol-loaded system. Consequently, leak detection is of the utmost importance in protecting equipment and personnel. Hydrazine vapor quantification presents many challenges in addition to the safety concerns. The reactivity of these compounds causes thermal and catalytic decomposition, which results in significant losses. Further complications arise from the sticky nature of hydrazine. Molecules adsorb irreversibly to virtually any surface they make contact with before detection, which results in instrument drift. These properties make it difficult to accurately quantify hydrazines. Current analytical methods seek to minimize these interactions. After an extensive literature search to determine appropriate chemical reactions, a method was devised to quantify hydrazines, without the limitations of monitoring hydrazines.
Source record↗
Plasma Igniter for Reliable Ignition of Combustion in Rocket Engines
A plasma igniter has been developed for initiating combustion in liquid-propellant rocket engines. The device propels a hot, dense plasma jet, consisting of elemental fluorine and fluorine compounds, into the combustion chamber to ignite the cold propellant mixture. The igniter consists of two coaxial, cylindrical electrodes with a cylindrical bar of solid Teflon plastic in the region between them. The outer electrode is a metal (stainless steel) tube; the inner electrode is a metal pin (mild steel, stainless steel, tungsten, or thoriated-tungsten). The Teflon bar fits snugly between the two electrodes and provides electrical insulation between them. The Teflon bar may have either a flat surface, or a concave, conical surface at the open, down-stream end of the igniter (the igniter face). The igniter would be mounted on the combustion chamber of the rocket engine, either on the injector-plate at the upstream side of the engine, or on the sidewalls of the chamber. It also might sit behind a valve that would be opened just prior to ignition, and closed just after, in order to prevent the Teflon from melting due to heating from the combustion chamber.
Martin, Adam↗
Preliminary design of an auxiliary power unit for the space shuttle. Volume 2: Component and system configuration screening analysis
The auxiliary power unit (APU) for the space shuttle is required to provide hydraulic and electrical power on board the booster and orbiter vehicles. Five systems and their associated components, which utilize hot gas turbines to supply horsepower at gearbox output pads, were studied. Hydrogen-oxygen and storable propellants were considered for the hot gas supply. All APU's were required to be self contained with respect to dissipating internally generated heat. These five systems were evaluated relative to a consistent criteria. The system supplied with high pressure gaseous hydrogen and oxygen was recommended as the best approach. It included a two-stage pressure-compounded partial-admission turbine, a propellant conditioning system with recuperation, a control system, and a gearbox. The gearbox output used was 240 HP. At the close of the study a 400 HP level was considered more appropriate for meeting the prime shuttle vehicle needs, and an in-depth analysis of the system at the 400 HP output level was recommended.
Burriss, W. L.↗
Preliminary design of an auxiliary power unit for the space shuttle: Component and system configuration screening analysis
The auxiliary power unit (APU) for the space shuttle is required to provide hydraulic and electrical power on board the booster and orbiter vehicles. Five systems and their associated components, which utilize hot gas turbines to supply horsepower at gearbox output pads, were studied. Hydrogen-oxygen and storable propellants were considered for the hot gas supply. All APU's were required to be self-contained with respect to dissipating internally generated heat. These five systems were evaluated relative to a consistent criteria. The system supplied with high pressure gaseous hydrogen and oxygen was recommended as the best approach. It included a two-stage pressure-compounded partial-admission turbine, a propellant conditioning system with recuperation, a control system, and a gearbox. The gearbox output used was 240 hp. At the close of the study a 400 hp level was considered more appropriate for meeting the prime shuttle vehicle needs, and an in-depth analysis of the system at the 400 hp output level was recommended.
Binsley, R. L.↗
Lead-Free Propellant for Propellant Actuated Devices
Naval Surface Warfare Center, Indian Head Division's CAD/PAD Department has been working to remove toxic compounds from our products for about a decade. In 1992, we embarked on an effort to develop a lead-free double base propellant to replace that of a foreign sole source. At the time there were availability concerns. In 1995, the department developed a strategic proposal to include a wider range of products. Efforts included such efforts as removing lead sheathing from linear explosives and replacing lead azide and lead styphnate compounds. This paper will discuss efforts specifically related to developing non-leaded double base propellant for use in various Propellant Actuated Devices (PADs) for aircrew escape systems. The propellants can replace their leaded counterparts, mitigating lead handling, processing, or toxic exposure to the environment and personnel. This work eliminates the use of leaded compounds, replacing them with a more environmentally benign metal-organic salt. Historically double-base propellants have held an advantage over other families of energetic materials through their relative insensitivity of the burning rate to changes in temperature and pressure. This desirable ballistic effect has been obtained with the use of a lead-organic salt alone or in a physical mixture with a copper-organic salt, or more recently with a lead-copper complex. These ballistic modifiers are typically added to the double-base 'paste' prior to gelatinization on heated calendars or one type or another. The effect of constant burning rate over a pressure range is called a 'plateau' while an even more beneficial effect of decreasing burning rate with increasing pressure is termed a 'mesa.' The latter effect results in very low temperature sensitivity of the propellant burning rate. Propellants with such effects are ideal tactical rocket motor propellants. The use of lead compounds poses a concern for the environment and personnel safety due to the metal's toxic nature when introduced into the atmosphere by propellant manufacturing, rocket firings, and disposal. Two separate programs are underway at Indian Head to replace the leaded ballistic modifiers in NOSIH-AA-2 and KU propellants. Although the system requirements were very different, the programs gained valuable information from one another throughout their course.
Goodwin, John L.↗
Saturated hydrocarbon polymeric binder for advanced solid propellant and hybrid solid grains Quarterly report no. 2, 1 Feb. - 30 Apr. 1966
Synthesis and analysis of ethylene-neohexene copolymers with other non ketene-imine group free radicals for solid and hybrid grain propellant saturated hydrocarbon binder program
FREE RADICAL↗
Combustion Instability Analysis and the Effects of Drop Size on Acoustic Driving Rocket Flow
High frequency combustion instability, the most destructive kind, is generally solved on a per engine basis. The instability often is the result of compounding acoustic oscillations, usually from the propellant combustion itself. To counteract the instability the chamber geometry can be changed and/or the method of propellant injection can be altered. This experiment will alter the chamber dimensions slightly; using a cylindrical shape of constant diameter and the length will be varied from six to twelve inches in three-inch increments. The main flowfield will be the products of a high OF hydrogen/oxygen flow. The liquid fuel will be injected into this flowfield using a modulated injector. It will allow for varied droplet size, feed rate, spray pattern, and location for the mixture within the chamber. The response will be deduced from the chamber pressure oscillations.
Harper, Brent↗