Evaluation of Energy and PSD Readout Methods for SiPMs Using FPGAs
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Leland, John Alexander [Sandia National Laboratori↗
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Morphological Characterization of Uranyl Fluoride Particles via Atomic Force Microscopy
Uranium hexafluoride (UF 6 ) undergoes a rapid hydrolysis reaction when exposed to atmospheric water. In addition to producing hazardous HF gas, the hydrolysis reaction produces uranyl fluoride (UO 2 F 2 ), a radioactive solid phase particulate material. Because of the technological utility of UF 6 in the nuclear fuel cycle, understanding the transport properties of UO 2 F 2 aerosol produced via UF 6 hydrolysis is important for accident scenarios. Moreover, the fundamental chemical and physical properties of the UF 6 hydrolysis reaction are not completely understood. Recently, several experiments on the aerosol phase properties of UO 2 F 2 produced in this way have shown that under most relevant conditions, the particle size distribution (PSD) of UO 2 F 2 can be extremely small, approximately 3 to 5 nm, which is well below the threshold that can be routinely observed via scanning electron microscopy (SEM). Although readily observable in the aerosol phase, observation of nanometer-sized particles in the condensed phase (i.e. deposited on surfaces) remains a challenge. Here, in this study, we have used atomic force microscopy (AFM) to study the PSD and morphological characteristics of UO 2 F 2 deposited at low and high concentrations under different humidity conditions, a primary variable in the hydrolysis reaction. Here, we find strong agreement between PSD measured in the aerosol phase via scanning mobility particle sizing and PSD measured via AFM, with particle sizes peaked below 4 nm for low-humidity conditions. At higher humidity, the distribution is centered around 5 to 10 nm but extends up to 20 nm. These results are in stark contrast to previous measurements using SEM that show PSD on the order of 300- to 1000-nm particle sizes; moreover, these are the first direct measurements of individual particles of UO 2 F 2 having been produced via UF 6 hydrolysis deposited on surfaces. These measurements, therefore, open a new avenue for collecting and detecting UO 2 F 2 in the condensed phase and further refine the PSD, which is critical for environmental transport determinations.
Uranium hexafluoride↗
Performance stability of plastics for neutron-gamma pulse shape discrimination
The introduction of the first commercially available plastic scintillators with pulse shape discrimination (PSD) offered by Eljen Technology marked progress towards potentially replacing liquid scintillators in neutron detection. However, use of these plastics over several recent years has revealed an important flaw in these materials: the eventual degradation of scintillation light output and PSD performance. Here, studies described in this paper considered possible reasons for this degradation. Experiments conducted with numerous lab-prepared and commercial EJ-276 samples showed that the main factor affecting the instability is oxidation that involves highly reactive radicals generated during the polymerization process or from the further breakdown of polymer chains under oxygen/air exposure. Based on the obtained results, the stability of scintillation performance for PPO (2,5-Diphenyloxazole)-based PSD plastics has been improved through modifications of the composition via the utilization of scintillation dyes and compounds with antioxidant properties that diminish the effects of oxidation. Elements of these studies were used in the commercial production of the most recent EJ-276D PSD plastic version for fast neutron detection and 6Li-loaded plastics for thermal neutron and antineutrino detection applications. Performance projections of the new PSD plastics indicate a likely degradation of less than 10 % over 5–10 years in comparison to previous EJ-276 that might lose up to 30–40 % of the scintillation light during 1–2 years of storage or deployment under ambient conditions.
36 MATERIALS SCIENCE↗
Outer Radiation Belt Dynamics During the October 2012 Storm Revisited: Rapid Inward Radial Transport From a Dynamic Outer Boundary
Earth's outer radiation belt electron flux is highly variable and can be enhanced by over an order of magnitude over timescales less than one day, as observed during the October 2012 storm. Previous studies of this storm (e.g., Reeves et al., 2013, https://doi.org/10.1126/science.1237743) have invoked local acceleration to explain this. However, here, we argue that the observations can instead be explained by fast inward radial transport. One method often invoked to distinguish between these two acceleration processes is the existence of local peaks in electron phase space density (PSD) as a function of L* at fixed first, M, and second, K, adiabatic invariants. However, this method relies on the assumption that the evolution of the PSD as a function of L* occurs over timescales slower than the satellite orbital period. Here, high spatiotemporal resolution data from the Global Positioning System (GPS) spacecraft constellation is used to show that enhancements in the PSD occur during the October 2012 storm over short timescales not resolvable by the Van Allen Probes. In addition, Geostationary Operational Environmental Satellite spacecraft data also indicate that these enhancements are consistent with relativistic electron injections. A radial diffusion model is shown to reproduce the PSD dynamics observed by the Van Allen Probes, once rapid variations at the simulation outer boundary are included, consistent with GPS data. This verifies that apparently “locally growing” peaks in PSD along high apogee satellite orbits can be produced by fast inward radial transport without requiring the action of any local acceleration processes.
99 GENERAL AND MISCELLANEOUS↗
Development of Parameters for the Particle Size Distribution of TATB
Laser light scattering (LLS), manual counting of scanning electron microscopy (SEM) images, and reduction of SEM images using ImageJ (open source program) to determine Feret (caliper) diameters were applied to determine particle size distribution (PSD) of four preparations of 1,3,5‐triamino‐2,4,6‐trinitrobenzene (TATB) and yttria‐stabilized zirconia (YSZ), an SEM certified standard. Mie theory was used to reduce the LLS data. The spherical nature of the YSZ made it a good candidate for LLS. Variations in n , the refractive index, and iκ, the imaginary component, produced very little change in the PSD. However, changing the carrier liquid from H 2 O to a 40% aqueous sucrose solution, thereby changing the carrier refractive index, n 0 , substantially affected the PSD. The Mie complex refractive indices for the YSZ were n = 2.200, iκ = 0.100, with a 40% aqueous sucrose solution, n 0 = 1.400. The triclinic crystal structure of TATB made refractive index determinations more difficult, so a study was conducted varying Mie parameters and comparing them to the same data reduced using the Fraunhofer theory. Changing the n and κ parameters produced PSD with a small concentration of particles less than 1 µm in size or none in this range. SEM images, Feret data, manual counting, and Fraunhofer data reduction indicate particles less than 1 µm are probably < 5% in concentration. The final selection of Mie parameters for TATB was n = 2.283, iκ = 0.1, and suspension medium, n 0 = 1.330. Finally, computations, using density functional theory produced similar parameters.
Feret diameter↗
Comparative analysis of new crystal and plastic scintillators for fast and thermal neutron detection
This paper considers scintillation and physical properties of efficient organic scintillators tested as single crystals and as components of plastics with pulse shape discrimination (PSD). For the first time, single crystals of 9,9-dimethyl-2-phenyl-9H-fluorene (PhF) were grown for studies of the basic scintillation properties of this new compound. Comparison to classical organic crystals, like anthracene, trans-stilbene, and p-terphenyl, and to more recently introduced organic glass showed that the new crystal belongs to a group of the most efficient scintillators, with light output exceeding that of trans-stilbene and PSD comparable to that of p-terphenyl. Furthermore, additional studies were conducted to evaluate scintillation performance and physical properties, like hardness and dye leaching, of plastic scintillators prepared with PhF, organic glass, and liquid diisopropylnaphthalene (DIPN) that were considered as examples for potential replacement of PPO (2,5-diphenyloxazole) in current commercial PSD plastic scintillators. Comparison of the highest performing plastic scintillators prepared with these dyes shows that PhF formulations produced a record light output (LO) increase of 69 % relative to EJ-200. Similar improvements obtained with 6 Li-loaded formulations showed that future development of PSD plastics should not be limited to use of PPO but must involve the search and exploration of new efficient dyes that may lead to discovery of much brighter organic scintillators with improved physical properties required for fast and thermal neutron detection, fast neutron spectroscopy, and antineutrino detection applications.
9,9-dimethyl-2-phenyl-9H-fluorene↗
Quantifying the Effect of Pore‐Size Dependent Wettability on Relative Permeabilities Using Lattice Boltzmann Simulation
Relative permeability is a crucial two-phase property in porous media that can be significantly impacted by wettability conditions. While traditional research has predominantly examined homogeneous wettability, this work explores the less studied pore-size dependent (PSD) wettability, featured by a pore-size dependent wettability distribution. Leveraging high-fidelity Lattice Boltzmann simulations on CT-scanned porous samples, we demonstrate how PSD wettability would impact relative permeability at the pore scale. Our findings reveal that the deviation of relative permeability from the homogeneous wettabilitity induced by PSD wettability can be 5%–20%. The deviation of relative permeability curves increases as the spanning range of the contact angle increases. We also find that this impact is less pronounced as the capillary number increases. By adopting a pore-size-dependent contact angle relationship, our approach provides a more accurate and nuanced understanding of how PSD wettability would impact two-phase flow. These findings discovered at the pore scale may also provide valuable insights on relative permeability at the core to reservoir scales.
25 ENERGY STORAGE↗
Pushing the limits of pulse shape discrimination in a large liquid xenon detector
Abstract The LUX-ZEPLIN (LZ) experiment is a direct-detection dark matter experiment, optimized to search for weakly interacting massive particles (WIMPs) through WIMP-nucleon interactions. The main challenge in dark matter detection is differentiating between WIMP signals and background events. In LZ, the ratio of ionization to scintillation signals (charge-to-light) is the primary method for rejecting electronic recoil (ER) background. Pulse shape discrimination (PSD) offers a method for additional ER backgrounds rejection in liquid xenon detectors. In this paper, the discrimination power of PSD with the LZ experiment is discussed. To precisely characterize the scintillation pulse shape, an analysis framework is developed to reconstruct the detection time of individual photons. Using LZ calibration data, the photon-timing tail fraction discriminator is optimized and achieves ER leakage as low as $$15\%$$ 15 % . For specific background processes such as $$^{124}$$ 124 Xe double electron capture, the leakage is reduced further to about $$5\%$$ 5 % . PSD is combined with charge-to-light to form two-factor discrimination (TFD). The optimized TFD performance is compared with the performance of the charge-to-light method, with the corresponding false positive rate reduced by up to a factor of two for large scintillation pulses. Finally, PSD and TFD are applied to data from LZ’s WS2024 run and their performance is summarized.
Akerib, D. S. [SLAC National Accelerator Laborator↗
Pushing the Limits of Pulse Shape Discrimination in a Large Liquid Xenon Detector
The LUX-ZEPLIN (LZ) experiment is a direct-detection dark matter experiment, optimized to search for weakly interacting massive particles (WIMPs) through WIMP-nucleon interactions. The main challenge in dark matter detection is differentiating between WIMP signals and background events. In LZ, the ratio of ionization to scintillation signals (charge-to-light) is the primary method for rejecting electronic recoil (ER) background. Pulse shape discrimination (PSD) offers a method for additional ER backgrounds rejection in liquid xenon detectors. In this paper, the discrimination power of PSD with the LZ experiment is discussed. To precisely characterize the scintillation pulse shape, an analysis framework is developed to reconstruct the detection time of individual photons. Using LZ calibration data, the photon-timing prompt fraction discriminator is optimized and achieves ER leakage as low as $15\%$. For specific background processes such as $^{124}$Xe double electron capture, the leakage is reduced further to about $5\%$. PSD is combined with charge-to-light to form two-factor discrimination (TFD). The optimized TFD performance is compared with the performance of the charge-to-light method, with the corresponding false positive rate reduced by up to a factor of two for large scintillation pulses. Finally, PSD and TFD are applied to data from LZ's WS2024 run and their performance is summarized.
Akerib, D. S. [SLAC; KIPAC, Menlo Park]↗
Global quantification of the dispersion effect with POLDER satellite data
Increased aerosols can modify the shape of the cloud Particle Size Distribution (PSD), thereby influencing the radiative properties of clouds, known as the Dispersion Effect (DE). However, a global, observation-based quantification of its impact on Aerosol-Cloud Interactions (ACI) is lacking, leading to DE being typically ignored in satellite-based estimates of ACI forcing. Here we propose a physics-based method that combines polarimetric satellite data on cloud PSD to achieve global observational quantification of DE’s impact on ACI in liquid-phase stratiform clouds. Globally, DE offsets ACI changes induced by droplet number concentration variation and liquid water path adjustment by 7% and −1.4%, respectively. Furthermore, a parameterization based on the global dataset of PSD shape parameters is developed to improve DE estimation in large-scale models. Both the quantification and parameterization enhance our understanding of DE and facilitate the inclusion of this non-negligible impact of DE on ACI in estimating aerosol climate forcing.
54 ENVIRONMENTAL SCIENCES↗
Mesoscale simulation of granular materials under weak shock compaction–pore size distribution effects
This research established a systematic method to generate various pore-size distributions (PSDs) and studied the effect of PSDs on the shock compaction response of granular materials using two-dimensional mesoscale simulations under identical porosity. Simulations utilized various PSDs for three particle shapes (circle, ellipse, and square). Contacting particle configurations using three PSDs, characterized by spatially uniform distributed pores to heterogeneous distributed pores, and non-contacting particle configurations under a single case of PSD were tested. The PSD of generated particle sets was characterized using coordination number, mean diameter, and bimodality coefficient as statistical metrics. Mesoscale simulations showed that regardless of the conditions of pore distributions, shock compaction of granular materials consistently demonstrates a precursor, shock compaction front, and end. However, the shock compaction velocity of contacting particles was dependent on the PSDs despite the constant initial porosity. The compaction velocity was faster in particle configurations with relatively uniform pore distributions than in heterogeneous pore distributions, which our study demonstrated can be attributed to particle rearrangement during compaction. Circular-shaped particles had high sensitivity in shock compaction response to the various PSDs. Furthermore, a contacting particle configuration tended to propagate the shock compaction wave relatively faster than particles that were in a non-contact configuration. This study established the relative importance of considering PSD as a metric over the coordination number in studies of the shock compaction response of granular materials. Further, insights are provided on the evolving shock substructure to characterize the shock compaction response of granular materials.
36 MATERIALS SCIENCE↗
Properties of different LLM-105 preparations
LLM-105 (2,6-diamino-3,5-dinitropyrazine-1-oxide) has been prepared at several different size quantities (~10–70 Kg) and not subjected to further purification, such as recrystallization. Chemical and physical properties were compared—small-scale safety testing (impact, friction, ESD), thermal (chemical reactivity, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), one-dimensional time-to-explosion (ODTX)), morphological (particle-size distribution (PSD), scanning electron microscopy (SEM), powder x-ray diffraction (PXRD), skeletal density). Each preparation had similar properties to the other preparations except for PSD and PXRD. For PSD, all preparations exhibited a mono-modal distribution with a variation in median values from ~ 40 μm to over 80 μm. All PXRD values indicated the same morphology with minor variations in crystal orientations. Possible polymorphism was also observed in a few cases. SEM images and PXRD indicate all preparations to be diamond-type and X-type crystals with some twinning. Impact, friction, and ESD and thermal sensitivities values are consistent with these type of crystal habits as seen in vast literature studies.
Explosive characterization↗
Determining the tilt of the Raman laser beam using an optical method for atom gravimeters
The tilt of a Raman laser beam is a major systematic error in precision gravity measurement using atom interferometry. The conventional approach to evaluating this tilt error involves modulating the direction of the Raman laser beam and conducting time-consuming gravity measurements to identify the error minimum. In this work, we demonstrate a method to expediently determine the tilt of the Raman laser beam by transforming the tilt angle measurement into characterization of parallelism, which integrates the optical method of aligning the laser direction, commonly used in freely falling corner-cube gravimeters, into an atom gravimeter. A position-sensing detector (PSD) is utilized to quantitatively characterize the parallelism between the test beam and the reference beam, thus measuring the tilt precisely and rapidly. After carefully positioning the PSD and calibrating the relationship between the distance measured by the PSD and the tilt angle measured by the tiltmeter, we achieved a statistical uncertainty of less than 30 µrad in the tilt measurement. Furthermore, we compared the results obtained through this optical method with those from the conventional tilt modulation method for gravity measurement. The comparison validates that our optical method can achieve tilt determination with an accuracy level of better than 200 µrad, corresponding to a systematic error of 20 µGal in g measurement. This work has practical implications for real-world applications of atom gravimeters.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Binary pseudo-random array standard for extreme ultraviolet lithography tool characterization
Extreme ultraviolet (EUV) imaging tools play a crucial role in EUV lithography. Achieving high accuracy in EUV metrology is essential for advanced semiconductor manufacturing. A thorough characterization of the instrumentation in use is required. Binary pseudo-random arrays (BPRAs) are an established standard for calibrating and characterizing optical instruments in the frequency domain. Here, we expand the BPRA standard to applications in EUV imaging. To extend the technology to the EUV spectral range, a high-resolution BPRA target with the smallest feature size of 40 nm is developed. The EUV BPRA target establishes an in situ and portable calibration and alignment standard for EUV imaging. The target is patterned by means of electron-beam lithography, using a nickel absorber with a thickness of 39 nm. The substrate is a 4″ silicon wafer with a molybdenum/silicon multilayer coating. To demonstrate the efficacy of the target and develop the instrument calibration protocol, the target is imaged on the Sharp Hyper-NA Actinic Reticle Review Project EUV mask microscope. Power spectral density (PSD) data are presented. The characteristics of the imaging system are imprinted on the PSD. The modulation transfer function is extracted from the PSD data. A partially coherent imaging model is used as a reference to the experimental results.
BPRA↗
Topography restoration in white-light interferometry using an instrument transfer function evaluated with binary pseudo-random arrays
Accurate knowledge of the instrument transfer function (ITF) is vital for topography measurements using white-light interferometry (WLI). To this end, we derive a complete set of analytical expressions for the power spectral density (PSD) of a discretely sampled binary pseudo-random array (BPRA) as a theoretical benchmark. We then determine the ITF by comparing this theoretical PSD with the measured PSD of the BPRA. For the Zygo ZeGage Pro HR with a objective, the determined ITF closely matches the nominal modulation transfer function (MTF). Accordingly, we integrate the nominal MTF into Fourier-domain restoration filters and apply them to practical WLI topography data, yielding restored topographies that show improved agreement with atomic force microscopy measurements. Overall, our integrated BPRA-based ITF measurement and filtering methodology offers a robust yet practical means of characterizing WLI performance and enhancing the accuracy of surface measurements.
Hirose, Shigenobu [Japan Agency for Marine Earth S↗
Passive Confirmation of the Presence Of High-Explosive Material Via Neutron Transmission Spectroscopy
The goal of this project was to explore a novel approach for identifying presence and potential types of high explosives (HE) in treaty-controlled items with passive neutron sources by using passive neutron transmission spectroscopy. We predominantly look to measure relative elemental abundance of Carbon, Hydrogen, Oxygen, and Nitrogen (CHON) since most relevant materials are certain mix of these elements, as shown in Table 1. Previously, most studies exploring potential identification of CHON elemental content of targets in the vicinity of passive neutron source were focused solely on gamma spectroscopy using high resolution gamma detectors. Using neutron transmission spectroscopy with pulse-shape discrimination (PSD) capable organic scintillators is not only a novel idea in of itself, but arguably necessary for accurate identification of the CHON elemental content of an interrogated target. While high resolution gamma spectroscopy in principle can determine a presence of hydrogen and nitrogen, it is effectively blind to a quantitatively measuring areal densities of C, O. The initially proposed approach, described in detail in the project proposal, was to leverage previous Monte Carlo study on neutron transmission spectroscopy using slab shaped target interrogated with well-collimated (“pencil”) neutron beam. In this study, a simulated test CO 2 target was interrogated by a pencil neutron beam and transmitted neutron spectra were measured using PSD capable organic scintillator using MLEM based unfolding technique. To establish relative elemental content of carbon and oxygen, the unfolded neutron spectrum was fit with a parametrized combination of their respective elemental spectral templates. The individual spectral template was calculated by convoluting ENDF neutron crosssection with the known resolution of the PSD detector used in the study. This approach in the studied configuration successfully quantitatively established relative elemental composition of carbon and oxygen.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
A Novel Optical Instrument for On-Line Measurement of Particle Size Distribution—Application to Clean Coal Technologies
A flow cell is a critical measurement interface for many optical instruments. However, the flows are often sampled under harsh conditions, such as under high pressure and/or high temperature, in the presence of particles, moisture, vapors with high dew points or corrosive gases. Therefore, obtaining a high-optical-quality flow cell that does not perturb the measurement is a significant challenge. To address this challenge, we proposed a new flow cell that employs a unique laminar coaxial flow field (for the purge and sample flows). A test system was built to conduct particle size distribution (PSD) measurements with no sampling bias using a state-of-the-art analyzer (Malvern Panalytical Insitec). The results revealed that the measurement zone is well defined solely by the sample flow, and the optical windows are well protected by the purge flow, with minimal risk of any depositions from the sample flow. Using this flow cell, the Insitec can successfully measure PSD under high pressure and temperature under moist, corrosive conditions without generating any sampling bias. Importantly, we successfully applied this flow cell for on-line PSD measurement for the flue gas of a 100 kWth pressurized oxy-coal combustor operating at 15 bara.
Cheng, Mao (ORCID:0000000213273900)↗
Miscanthus × giganteus increases soil maximum water holding capacity compared to maize
Soil ecosystem services, like the ability to store water, have been depleted after a century of conventional, annual cropping, and perennial crops offer a solution to this and other agricultural environmental issues. We assessed the impact of Miscanthus × giganteus (miscanthus), a perennial biomass crop, on soil water holding capacity and structure compared to continuous maize (Zea mays L.) at two sites in Iowa. After three growing seasons, we measured the following: (1) maximum water holding capacity (MWHC) with and without soil structure, and (2) total porosity and pore size distribution (PSD) via micro-computed tomography (microCT). Miscanthus increased MWHC by 14.7% across both sites relative to maize (p = 0.002), and we attributed this to structural changes due to the lack of a crop effect when measured on structureless soils. No significant changes were detected in soil organic matter, texture, total porosity, or PSD that could explain the increase in MWHC under miscanthus. Our findings suggest that the increases in MWHC are primarily due to structural changes rather than increases in soil organic matter or porosity (at least porosity detectable by microCT). This study highlights miscanthus' potential to enhance soil water storage and underscores the need for further investigation to clarify the mechanisms through which this biomass crop influences soil structural properties.
60 APPLIED LIFE SCIENCES↗