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At least 19 records

Managing Fire Risk During Drought: The Influence of Certification and El Nino on Fire-Driven Forest Conversion for Oil Palm in Southeast Asia

Indonesia and Malaysia have emerged as leading producers of palm oil in the past several decades, expanding production through the conversion of tropical forests to industrial plantations. Efforts to produce "sustainable" palm oil, including certification by the Roundtable on Sustainable Palm Oil (RSPO), include guidelines designed to reduce the environmental impact of palm oil production. Fire-driven deforestation is prohibited by law in both countries and a stipulation of RSPO certification, yet the degree of environmental compliance isunclear, especially during El Niño events when drought conditions increase fire risk. Here, we used time series of satellite data to estimate the spatial and temporal patterns of fire-driven deforestation on and around oil palm plantations. In Indonesia, fire-driven deforestation accounted for one-quarter of total forest losses on both certified and noncertified plantations. After the first plantations in Indonesia received RSPO certification in 2009,forest loss and fire-driven deforestation declined on certified plantations but did not stop altogether. Oil palm expansion in Malaysia rarely involved fire; only 5 % of forest loss on certified plantations had coincident activefire detections. Interannual variability in fire detections was strongly influenced by El Nino and the timing of certification. Fire activity during the 2002, 2004, and 2006 El Nino events was similar among oil palm plantations in Indonesia that would later become certified, noncertified plantations, and surrounding areas. However, total fire activity was 75% and 66% lower on certified plantations than noncertified plantations during the 2009 and 2015 El Nino events, respectively. The decline in fire activity on certified plantations, including during drought periods, highlights the potential for RSPO certification to safeguard carbon stocks in peatlands and remaining forests in accordance with legislation banning fires. However, aligning certification standards with satellite monitoring capabilities will be critical to realize sustainable palm oil production and meet industry commitments to zero forestation.

Noojipady, Praveen↗

Biofuel production from palm oil deoxygenation using nickel-molybdenum on zirconia catalyst using glycerol as a hydrogen donor

The growing demand for renewable energy has generated interest in biofuels as alternatives to fossil fuels. Second-generation biofuels, derived from deoxygenating fats and oils, have garnered a higher level of interest from industry and academia due to their potential for direct replacement of diesel and jet fuels. Palm oil, mostly cultivated in Thailand and composed of C16 and C18 fatty acids, is a primary feedstock sought for biofuel production. Palm oil deoxygenation contains several pathways that may or may not require hydrogen gas. This study aimed to produce biofuels in different fuel ranges, such as gasoline, jet fuel, and diesel, through palm oil deoxygenation using glycerol as a hydrogen source. Glycerol, a low-value byproduct, was used as a hydrogen donor, whereas nickel-molybdenum-supported catalysts were chosen for their high efficiency in deoxygenation and cost-effectiveness. The study investigated the impact of reaction time, temperature, and catalyst activation method on palm oil deoxygenation. Catalyst characterization methods, including XRD, SEM, TEM, XPS, FTIR, TGA, and nitrogen-sorption, were employed to understand the role of catalysts’ activity during palm oil upgrading. Findings indicated that alkane hydrocarbons are the major components in liquid products. The presence of excess hydrogen in post reaction gaseous phase proves the hydrogen donation capability of glycerol. Increased reaction time and temperature facilitated the removal of oxygen from palm oil. Nickel-molybdenum on zirconia activated by sulfidation demonstrated higher stability than by reduction activation.

09 BIOMASS FUELS↗

Life-cycle energy use and greenhouse gas emissions of palm fatty acid distillate derived renewable diesel

This study aims to quantify life-cycle fossil energy use and greenhouse gas (GHG) emissions for palm fatty acid distillate (PFAD) derived renewable diesel (RD) taking into consideration different feedstock classifications that are applicable to PFAD (residue, byproduct, or coproduct), and incorporating updated data for key processes. Under the three classifications, the PFAD to RD pathway was modeled using the Greenhouse gases, Regulated Emissions, and Energy Use in Technologies (GREET®) model. PFAD-derived RD could reduce fossil energy consumption by 77%–88%, relative to petroleum diesel. GHG emissions are very sensitive to PFAD classification and coproduct handling methods. Considering the production of palm oil and PFAD and economic value, we maintain that PFAD should be treated as a byproduct in palm oil refineries. With this treatment, PFAD-derived RD could achieve 84% GHG emissions reductions, compared to the emissions of petroleum diesel. We also employed a substitution method to address the substitution of PFAD by other materials in the marketplace. Compared to coproduct allocation results, we found substituting PFAD by tallow, soy oil, barley, and canola oil results in lower GHG emissions. Due to high induced land-use change emissions associated with palm farming, if PFAD is treated as a coproduct with refined palm oil, PFAD-derived RD may not deliver GHG reductions. A sensitivity analysis identified key parameters such as palm fruit yield, oil extraction efficiency in oil mills, and energy use intensity for RD production affects LCA results significantly; future efforts to improve these parameters could result in further GHG reductions.

09 BIOMASS FUELS↗

Controlling Palm-Object Interactions via Friction for Enhanced In-Hand Manipulation

In-hand manipulation is necessary, yet challenging for robotic hands as robots begin to interact with real-world objects and environments. The intentional incorporation of an active palm can lead to improved dexterity. In this work, we demonstrate how controlling the palm-object interaction enables access to different sets of motion primitives. We first discuss how various properties of the palm affect in-hand manipulation, as well as grasping. Here, we focus on varying the friction force between the object and the palm by either changing the coefficient of friction or the normal load. We explore how these two design factors can be actively controlled to enable 5-degree-of-freedom object motion within the hand. We present variable-friction and variable-preload palms that enable on-the-fly switching between in-plane and out-of-plane manipulation modes. Additionally, we discuss their impact on grasp stability. Finally, we demonstrate how an object can be translated and pivoted within the hand by sequentially performing synchronized palm and finger actions.

Clark B Teeple↗

Soil Carbon Dynamics Following Land Use Changes and Conversion to Oil Palm Plantations in Tropical Lowlands Inferred From Radiocarbon

We measured the 14C and 13C isotopic values of soil organic carbon in mineral soil from lowland tropical forests to provide insight into how quickly carbon is turning over in the soil following conversion of primary forests to oil palm plantations. In addition to areas converted to oil palm plantations in Peru, Indonesia, and Cameroon, we examine pastures and secondary forests in Peru as a comparison to the carbon cycling processes operating in the oil palm plantations.This dataset includes radiocarbon (Δ14C) and stable carbon (δ13C) isotopes of soil organic carbon in mineral soils from natural lowland forests and oil palm plantations in Peru, Indonesia, and Cameroon. We additionally examine plots of secondary forests following agricultural use and pastures on cleared natural forest in Peru. In addition to isotopic data, this dataset includes soil carbon and nitrogen concentrations and stock, soil texture (percent sand, silt, and clay), pH, ECEC (effective cation exchange capacity), base saturation, and bulk density. Soils were sampled in 4 depth increments to 100 cm depth.This dataset supports the publication Finstad et al., 2020. Finstad, K., van Straaten, O., Veldkamp, E., & McFarlane, K. (2020). Soil carbon dynamics following land use changes and conversion to oil palm plantations in tropical lowlands inferred from radiocarbon. Global Biogeochemical Cycles, 34, e2019GB006461. https://doi.org/10.1029/2019GB006461

54 ENVIRONMENTAL SCIENCES↗

Towards multiscale modeling of ocean surface turbulent mixing using coupled MPAS-Ocean v6.3 and PALM v5.0

A multiscale modeling approach for studying the ocean surface turbulent mixing is explored by coupling an ocean general circulation model (GCM) MPAS-Ocean with the Parallelized Large Eddy Simulation Model (PALM). The coupling approach is similar to the superparameterization approach that has been used to represent the effects of deep convection in atmospheric GCMs. However, the focus of this multiscale modeling approach is on the small-scale turbulent mixing and their interactions with the larger-scale processes in the ocean, so that a more flexible coupling strategy is used. To reduce the computational cost, a customized version of PALM is ported on the general-purpose graphics processing unit (GPU) with OpenACC, achieving 10–16 times overall speedup as compared to running on a single CPU. Even with the GPU-acceleration technique, a superparameterization-like approach to represent the ocean surface turbulent mixing in GCMs using embedded high fidelity and three-dimensional large eddy simulations (LESs) over the global ocean is still computationally intensive and infeasible for long simulations. However, running PALM regionally on selected MPAS-Ocean grid cells is shown to be a promising approach moving forward. The flexible coupling between MPAS-Ocean and PALM allows further exploration of the interactions between the ocean surface turbulent mixing and larger-scale processes, as well as future development and improvement of ocean surface turbulent mixing parameterizations for GCMs.

54 ENVIRONMENTAL SCIENCES↗

Thermal and Flame Retardancy Behavior of Oil Palm Based Epoxy Nanocomposites

The aim of present study was to investigate the thermal properties and flame retardancy behavior of flame retardant (FR) epoxy nanocomposites from chemically treated (bromine water and tin chloride) oil palm empty fruit bunch (OPEFB) nano filler at different filler loading (1, 3, 5%). Thermal properties were evaluated through thermogravimetry analyzer, derivative thermogravimetry and differential scanning calorimetry. FR properties of nanocomposites are evaluated through UL-94 vertical burning test and limiting oxygen index (LOI). The functional group analysis of all composites was made by FTIR spectroscopy. Thermal analysis shows that degradation temperature of epoxy composites shifts from 370 to 410 °C and char yield also increases for 3% loading. Furthermore LOI value of 29% and UL-94 rating of V-0 with no flame dripping and cotton ignition, revealed that 3% oil palm nano filler filled epoxy nanocomposites display satisfactory flame retardancy. The superior flame retardancy of epoxy nanocomposites are attributed to the chemical reactions occurred in the gaseous phases and the profound synergistic flame retardation effect of tin with bromine in the treated nano OPEFB filler. All the epoxy nanocomposites displayed almost similar FTIR spectra with the characteristics metal-halogen bond supporting the synergism. Homogeneous dispersion of 3% oil palm nano filler act as highly effective combustion chain terminating agent compared with 1 and 5% nano OPEFB/epoxy nanocomposites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Boosting Thailand’s palm oil yield with advanced seasonal predictions

Palm oil, an indispensable global commodity, plays a crucial role in Thailand's economy (Maluin et al 2020). This versatile product, found in everything from food to biodiesel and industrial applications (Kamil and Omar 2017, Chiarawipa et al 2020), cements Thailand's position as the third-largest producer in the world. The industry is particularly vital in the southern regions, where most plantations are located (Dallinger 2011), providing employment opportunities in rural areas and bolstering the nation's GDP and foreign exchange earnings through exports. However, oil palm productivity hinges on climatic conditions, with precipitation patterns being especially influential. Both local climate and remote forces like El Niño-Southern Oscillation (ENSO) significantly impact production. In neighboring Malaysia, research by Kamil and Omar (2017) has uncovered the consequential role of ENSO events on precipitation and, subsequently, palm oil productivity.

54 ENVIRONMENTAL SCIENCES↗

Palm oil deoxygenation with glycerol as a hydrogen donor for renewable fuel production using nickel-molybdenum catalysts: The effect of support

Palm oil, one of the most widely used vegetable oils, offers significant potential as a sustainable feedstock for biofuel production. This study explores the deoxygenation of palm oil using glycerol as a hydrogen donor, with nickel-molybdenum (NiMo) catalysts supported on commercial alumina (Al 2 O 3 ), and zeolite (HZSM-5) comparing with self-prepared zirconia (ZrO 2 ). The catalysts were synthesized via incipient wetness impregnation and evaluated for their performance in biofuel production. NiMo/Al 2 O 3 exhibited the lowest oxygen removal efficiency (68.5 %), while NiMo/HZSM-5 achieved a higher oxygen removal (74.3 %) but also demonstrated the highest coke formation. The type of support material influenced the resulting biofuel range, with NiMo/HZSM-5 and NiMo/ZrO 2 favoring jet fuel production, whereas NiMo/Al 2 O 3 was more suitable for diesel production. Notably, NiMo/ZrO 2 exhibited the highest performance in palm oil deoxygenation while minimizing coke formation. These findings highlight NiMo/ZrO 2 as a promising catalyst for efficient and stable biofuel production, with the support material significantly influencing product yield and fuel quality.

36 MATERIALS SCIENCE↗

The impact of hurricane disturbances on a tropical forest: implementing a palm plant functional type and hurricane disturbance module in ED2-HuDi V1.0

Hurricanes commonly disturb and damage tropical forests. Hurricane frequency and intensity are predicted to change under the changing climate. The short-term impacts of hurricane disturbances to tropical forests have been widely studied, but the long-term impacts are rarely investigated. Modeling is critical to investigate the potential response of forests to future disturbances, particularly if the nature of the disturbances is changing with climate. Unfortunately, existing models of forest dynamics are not presently able to account for hurricane disturbances. Therefore, we implement the Hurricane Disturbance in the Ecosystem Demography model (ED2) (ED2-HuDi). The hurricane disturbance includes hurricane-induced immediate mortality and subsequent recovery modules. The parameterizations are based on observations at the Bisley Experimental Watersheds (BEW) in the Luquillo Experimental Forest in Puerto Rico. We add one new plant functional type (PFT) to the model – Palm, as palms cannot be categorized into one of the current existing PFTs and are known to be an abundant component of tropical forests worldwide. The model is calibrated with observations at BEW using the generalized likelihood uncertainty estimation (GLUE) approach. The optimal simulation obtained from GLUE has a mean relative error of –21 %, –12 %, and –15 % for stem density, basal area, and aboveground biomass, respectively. The optimal simulation also agrees well with the observation in terms of PFT composition (+1 %, –8 %, –2 %, and +9 % differences in the percentages of “Early”, “Mid”, “Late”, and “Palm” PFTs, respectively) and size structure of the forest (+0.8 % differences in the percentage of large stems). Lastly, using the optimal parameter set, we study the impact of forest initial condition on the recovery of the forest from a single hurricane disturbance. The results indicate that, compared to a no-hurricane scenario, a single hurricane disturbance has little impact on forest structure (+1 % change in the percentage of large stems) and composition (<1 % change in the percentage of each of the four PFTs) but leads to 5 % higher aboveground biomass after 80 years of succession. The assumption of a less severe hurricane disturbance leads to a 4 % increase in aboveground biomass.

54 ENVIRONMENTAL SCIENCES↗

The application of the quasi-geostrophic Eliassen-Palm flux to the analysis of stratospheric data

The quasi-geostrophic form of the Eliassen-Palm flux is calculated for steady linear planetary wave 1 in a realistic zonal flow with dissipation. This flux shows a region of divergence in the polar stratosphere that is similar to that found in time averages of observations. Comparison with the full primitive equation form of the Eliassen-Palm flux indicates that in the model this divergent region is spurious and results from the overestimation of the momentum flux divergence when it is calculated from geostrophic winds. An approximate expression for the Eliassen-Palm flux in terms of balanced winds is suggested as an alternative to the quasi-geostrophic form.

Robinson, W. A.↗

Hydrochloric Acid Hydrolysis of Pulps from Oil Palm Empty Fruit Bunches to Produce Cellulose Nanocrystals

Cellulose nanocrystals (CNCs) were successfully isolated by hydrochloric acid hydrolysis followed by ultrasonic homogenization of oil palm empty fruit bunches (OPEFB), which are a major form of agricultural waste in Southeast Asia. Currently sulfuric acid is mainly used in CNC preparation to achieve high dispersibility; however, we demonstrated that CNC suspensions prepared from OPEFB by hydrochloric acid hydrolysis remained stable without any sedimentation over 6 months. The obtained CNCs were fully characterized by elemental analysis, electron microscopic observation, X-ray diffraction measurement, and thermal analysis. The OPEFB-derived CNCs exhibited higher aspect ratios of 23–29 and higher thermal stability of 347–359 °C as maximum degradation temperature, as compared with those of woody CNCs prepared by sulfuric acid hydrolysis (15 and 311 °C, respectively). Although as-prepared CNCs showed comparable morphological and physicochemical properties to those prepared from oil palm biomass by other methods including sulfuric acid hydrolysis, use of hydrochloric acid and ultrasonication for hydrolysis of OPEFB was effective to yield crystalline CNCs with long-term nanodispersibility showing clear birefringence. Graphical Abstract: .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Novel Rigid PU Foam Based on Modified Used Palm Oil as Sound Absorbing Material

Novel bio-polyol was successfully synthesized from used palm oil (UPO) and was further tested for preparing rigid polyurethane (PU) foams. In this work, the modified used palm oil (MUPO) was synthesized in a single step process, by epoxidation together with ring opening reactions. The reagent ratios and reaction time for MUPO synthesis were also studied. The chemical structure of MUPO was confirmed by {sup 1}H-NMR spectroscopy and FTIR. The hydroxyl value of MUPO increased with reaction time and depended also on reagent ratio. The GPC trace of MUPO showed a bimodal distribution and the molecular weight slightly decreased with OH value. New rigid PU foams were prepared from MUPO. The foam cell size and compressive strength at 10% strain increased with OH value. All the rigid PU foams had excellent sound absorption coefficients. The lowest OH value (OHV = 100 mg KOH/g) provided sound absorption from 2200 Hz. In addition, the flammability of PU foams was improved by adding 30% wt of triphosphate (TPP) as flame retardant. The investigations showed that a bio-polyol based on UPO was suitable for preparing rigid PU foams that could serve as alternative sound absorbing materials. Graphical Abstract: .

36 MATERIALS SCIENCE↗

Results from the PALM-3000 High-Order Adaptive Optics System

The first of a new generation of high actuator density AO systems developed for large telescopes, PALM-3000 is optimized for high-contrast exoplanet science but will support operation with natural guide stars as faint as V approx. 18. PALM-3000 began commissioning in June 2011 on the Palomar 200" telescope and has to date over 60 nights of observing. The AO system consists of two Xinetics deformable mirrors, one with 66 by 66 actuators and another with 21 by 21 actuators, a Shack-Hartman WFS with four pupil sampling modes (ranging from 64 to 8 samples across the pupil), and a full vector matrix multiply real-time system capable of running at 2KHz frame rates. We present the details of the completed system, and initial results. Operating at 2 kHz with 8.3cm pupil sampling on-sky, we have achieved a K-band Strehl ratio as high as 84% in approx.1.0 arcsecond visible seeing.

Palomar↗

Hydrometeorological sensitivities of net ecosystem carbon dioxide and methane exchange of an Amazonian palm swamp peatland

Here, we report ecosystem-scale CO 2 and CH 4 flux observations for an Amazonian palm swamp peatland over a two-year period in relation to hydrometeorological forcings. Seasonal and short-term variations in hydrometeorological forcing had a strong effect on carbon dioxide and methane fluxes. High air temperature and vapor pressure deficit exerted an important limitation on photosynthesis during the dry season, while latent heat flux appeared to be insensitive to these climate drivers. Evidence from light-response analyses and flux partitioning support that photosynthetic activity was downregulated during dry conditions, while ecosystem respiration was either inhibited or enhanced depending on water table position. The cumulative net ecosystem carbon dioxide exchange indicated that the peatland was a significant carbon dioxide sink ranging from –465 (–279 to –651) g C m -2 y -1 in 2018 to –462 (–277 to –647) g C m -2 y -1 in 2019. The forest was a methane source of 22 (20 to 24) g C m -2 y -1 , similar in magnitude to other tropical peatlands and larger than boreal and arctic peatlands. Furthermore, the annual carbon budget of this Amazonian palm swamp peatland appears to be a major carbon sink under current hydrometeorological conditions, but evidence indicates that the sink strength is vulnerable to future climate change.

54 ENVIRONMENTAL SCIENCES↗

Green synthesis of N, S co-doped carbon quantum dots from triflic acid treated palm shell waste and their application in nitrophenol sensing

Highlights: • Novel Triflic Acid Treated Palm Shell based Carbon Quantum Dots were fabricated. • The fabrication process is green and sustainable. • The quantum dots exhibited greenish fluorescence. • CQDs were used as fluorescence probe for nitrophenols with good detection limits. - Abstract: Herein, we report N and S co-doped Carbon quantum dots (CQDs) prepared using palm shell powder (PSP) and triflic acid. The CQDs possessed a graphitic-like structure with narrow size distribution and exhibited a bright green fluorescence. The fluorescent property of CQDs was found to be independent of the excitation wavelength and was used as fluorescence probe for nitrophenols (NPs) with good detection limits (0.079 μM, 0.165 μM, 0.082 μM for NP, DNP and TNP respectively) and linearity in the range 0.2–0.40 μM, 0.5–85 μM, 0.20–40 μM for NP, DNP and TNP respectively.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Generalization of the quasi-geostrophic Eliassen-Palm flux to include eddy forcing of condensation heating

A modified Eulerian form of the Eliassen-Palm flux which includes the effect of eddy forcing on condensation heating is defined. With the two-dimensional vector flux in the meridional plane which is a function of the zonal mean eddy fluxes replaced by the modified flux, both the Eliassen-Palm theorem and a modified but more general form of the nonacceleration theorem for quasi-geostrophic motion still hold. Calculations of the divergence of the modified flux and of the eddy forcing of the moisture field are presented.

Stone, P. H.↗

Properties of Poly(Vinyl Alcohol)/Chitosan Nanocomposite Films Reinforced with Oil Palm Empty Fruit Bunch Amorphous Lignocellulose Nanofibers

The objective of this study was to investigate the properties of poly(vinyl alcohol)/chitosan nanocomposite films reinforced with different concentration of amorphous LCNFs. The properties analyzed were morphological, physical, chemical, thermal, biological, and mechanical characteristics. Oil palm empty fruit bunch LCNFs obtained from multi-mechanical stages were more dominated by amorphous region than crystalline part. Varied film thickness, swelling degree, and transparency of PVA/chitosan nanocomposite films reinforced with amorphous part were produced. Aggregated LCNFs, which reinforced PVA/chitosan polymer blends, resulted in irregular, rough, and uneven external surfaces as well as protrusions. Based on XRD analysis, there were two or three imperative peaks that indicated the presence of crystalline states. The increase in LCNFs concentration above 0.5% to PVA/chitosan polymer blends led to the decrease in crystallinity index of the films. A noticeable alteration of FTIR spectra, which included wavenumber and intensity, was obviously observed along with the inclusion of amorphous LCNFs. That indicated that a good miscibility between amorphous LCNFs and PVA/chitosan polymer blend generated chemical interaction of those polymers during physical blending. Reinforcement of PVA/chitosan polymer blends with amorphous LCNFs influenced the changes of T{sub g} (glass transition temperature), T{sub m} (melting point temperature), and T{sub max} (maximum degradation temperature). Three thermal phases of PVA/chitosan/LCNFs nanocomposite films were also observed, including absorbed moisture evaporation, PVA and chitosan polymer backbone structural degradation and LCNFs pyrolysis, and by-products degradation of these polymers. The addition of LCNFs 0.5% had the highest tensile strength and the addition of LCNFs above 0.5% decreased the strength. The incorporation of OPEFB LCNFs did not show anti-microbial and anti-fungal properties of the films. The addition of amorphous LCNFs 0.5% into PVA/chitosan polymer blends resulted in regular and smooth external surfaces, enhanced tensile strength, increased crystallinity index, and enhanced thermal stability of the films.

77 NANOSCIENCE AND NANOTECHNOLOGY↗