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Materials Data on PbCClO2 by Materials Project

PbCO2Cl crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pb2+ is bonded in a 9-coordinate geometry to four equivalent O2- and five equivalent Cl1- atoms. There are two shorter (2.54 Å) and two longer (2.77 Å) Pb–O bond lengths. There are a spread of Pb–Cl bond distances ranging from 3.09–3.27 Å. C3+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both C–O bond lengths are 1.27 Å. O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C3+ atom. Cl1- is bonded in a 5-coordinate geometry to five equivalent Pb2+ atoms.

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