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TmPd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm is bonded in a body-centered cubic geometry to eight equivalent Pd atoms. All Tm–Pd bond lengths are 3.00 Å. Pd is bonded in a body-centered cubic geometry to eight equivalent Tm atoms.
TmPd3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm is bonded to twelve equivalent Pd atoms to form a mixture of face and corner-sharing TmPd12 cuboctahedra. All Tm–Pd bond lengths are 2.90 Å. Pd is bonded in a distorted square co-planar geometry to four equivalent Tm atoms.