Materials Data on PdN4OF2 by Materials Project
PdN2O(NF)2 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of eight monofluoroamine molecules and two PdN2O ribbons oriented in the (0, 0, 1) direction. In each PdN2O ribbon, Pd2+ is bonded in a linear geometry to two equivalent N+0.50+ atoms. Both Pd–N bond lengths are 1.90 Å. N+0.50+ is bonded in a bent 120 degrees geometry to one Pd2+ and one O2- atom. The N–O bond length is 1.34 Å. O2- is bonded in a bent 120 degrees geometry to two equivalent N+0.50+ atoms.
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