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Results for “Pore collapse process”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Numerical Modelling of the Deep Impact Mission Experiment

NASA s Deep Impact Mission (launched January 2005) will provide, for the first time ever, insights into the interior of a comet (Tempel 1) by shooting a approx.370 kg projectile onto the surface of a comets nucleus. Although it is usually assumed that comets consist of a very porous mixture of water ice and rock, little is known about the internal structure and in particular the constitutive material properties of a comet. It is therefore difficult to predict the dimensions of the excavated crater. Estimates of the crater size are based on laboratory experiments of impacts into various target compositions of different densities and porosities using appropriate scaling laws; they range between 10 s of meters up to ~250 m in diameter [1]. The size of the crater depends mainly on the physical process(es) that govern formation: Smaller sizes are expected if (1) strength, rather than gravity, limits crater growth; and, perhaps even more crucially, if (2) internal energy losses by pore-space collapse reduce the coupling efficiency (compaction craters). To investigate the effect of pore space collapse and strength of the target we conducted a suite of numerical experiments and implemented a novel approach for modeling porosity and the compaction of pores in hydrocode calculations.

Wuennemann, K.↗

Deformational mass transport and invasive processes in soil evolution

Channels left in soil by decayed roots and burrowing animals allow organic and inorganic precipitates and detritus to move through soil from above, to depths at which the minuteness of pores restricts further passage. Consecutive translocation-and-root-growth phases stir the soil, constituting an invasive, dilatational process which generates cumulative strains. Below the depths thus affected, mineral dissolution by descending organic acids leads to internal collapse; this softened/condensed precursor horizon is then transformed into soil via biological activity that mixes and expands the evolving residuum through root and micropore-network invasion.

Brimhall, George H.↗

Optimization of Aerogels for High Temperature Applications

Aerogels can be used in spaceflight applications as thermal insulators due to their low density, low thermal conductivity, and tortuous path for solid conduction. However, the aerogel formulation must be optimized to increase the thermal stability of the aerogels as drastic densification and decrease in surface area is often exhibited after high-temperature exposure. Current research investigates yttria-stabilized zirconia (YSZ) aerogels, which have low thermal conductivity and are expected to be used between 600°C and 1000°C. We anticipate that new sol-gel chemistries and processing will yield YSZ aerogels that display retained mesoporous structure, increased surface area, and minimized shrinkage upon exposure to higher temperatures in the projected use range. This work investigates the cationic surfactant, cetrimonium bromide (CTAB), as a templating agent to prevent the collapse of the aerogel pore structure upon gelation and drying. It was determined that adding one-half times the critical micelle concentration (CMC) of CTAB increased the surface area and pore volume of the aerogels, as compared to aerogels without CTAB or with twice the CMC of CTAB, following high-temperature exposure. By optimizing CTAB, the thermal stability of YSZ aerogels can be enhanced to make these materials more efficient when used as thermal management systems.

Rebecca C Walker↗

Manufacture of porous biodegradable polymer conduits by an extrusion process for guided tissue regeneration

We have fabricated porous, biodegradable tubular conduits for guided tissue regeneration using a combined solvent casting and extrusion technique. The biodegradable polymers used in this study were poly(DL-lactic-co-glycolic acid) (PLGA) and poly(L-lactic acid) (PLLA). A polymer/salt composite was first prepared by a solvent casting process. After drying, the composite was extruded to form a tubular construct. The salt particles in the construct were then leached out leaving a conduit with an open-pore structure. PLGA was studied as a model polymer to analyze the effects of salt weight fraction, salt particle size, and processing temperature on porosity and pore size of the extruded conduits. The porosity and pore size were found to increase with increasing salt weight fraction. Increasing the salt particle size increased the pore diameter but did not affect the porosity. High extrusion temperatures decreased the pore diameter without altering the porosity. Greater decrease in molecular weight was observed for conduits manufactured at higher temperatures. The mechanical properties of both PLGA and PLLA conduits were tested after degradation in vitro for up to 8 weeks. The modulus and failure strength of PLLA conduits were approximately 10 times higher than those of PLGA conduits. Failure strain was similar for both conduits. After degradation for 8 weeks, the molecular weights of the PLGA and PLLA conduits decreased to 38% and 43% of the initial values, respectively. However, both conduits maintained their shape and did not collapse. The PLGA also remained amorphous throughout the time course, while the crystallinity of PLLA increased from 5.2% to 11.5%. The potential of seeding the conduits with cells for transplantation or with biodegradable polymer microparticles for drug delivery was also tested with dyed microspheres. These porous tubular structures hold great promise for the regeneration of tissues which require tubular scaffolds such as peripheral nerve, long bone, intestine, or blood vessel.

NASA Discipline Cell Biology↗