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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Quaternary and quinary modifications of the eutectic superalloy gamma/gamma prime-delta

Quaternary modifications and quinary additions from the elements Co, Ti, Mo, W, Re, B, Si, and Ta to the baseline quaternary alloy gamma/gamma prime-delta Ni-19.7 at.% Nb-6.0 at.% Cr-2.5 at.% Al are examined for various concentrations. From modification studies five alloys were chosen for detailed mechanical property characterization: Ni-19.7 Nb-6.0 Cr-2.5 Al-1.0 W; Ni-19.7 Nb-6.0 Cr-2.5 Al-1.0 Mo; Ni-18.6 Nb-6.0 Cr-2.5 Al-0.87 Ti; Ni-20.2 Nb-6.0 Cr-2.5 Al-2.0 Co; and Ni-17.9 Nb-6.0 Cr-2.5 Al-3.0 Ta. It is shown that extensive alloying of the baseline quaternary alloy is possible for elements exhibiting a wide solubility range in both phases, and that limited substitution of W, Mo, Re, Si, and B is possible for elements with restricted solid solubility especially in the delta phase. Improvement of creep rupture strength and cyclic oxidation resistance at 1100 C is discussed.

Lemkey, F. D.↗
NASA NTRS1985

Tertiary and Quaternary Research with Remote Sensing Methods

Problems encountered in mapping the Quaternary section of the Wind River Region using remote sensing methods are discussed. Analysis of the stratigraphic section is a fundamental aspect of the geologic study of sedimentary basins. Stratigraphic analysis of post-Cretaceous rocks in the Wind River Basin encounters problems of a distinctly different character from those involved in studying the pre-Cretaceous section. The interior of the basin is predominantly covered by Tertiary and Quaternary sediments. These rocks, except on the basin margin to the north, are mostly flat lying or gently dipping. The Tertiary section consists of sandstones, siltstones, and tuffaceous sediments, some variegated, but in general poorly bedded and of great lithologic similarity. The Quaternary sediments consist of terrace, fan, and debris tongue deposits, unconsolidated alluvium occupying the bottoms of modern watercourses, deposits of eolian origin and tufa. Terrace and fan deposits are compositionally diverse and reflect the lithologic diversity of the source terranes.

Conel, J. E.↗
NASA NTRS1992

Compression behavior of quaternary and higher order solid-solution L1(2) trialuminides

Results from preliminary studies undertaken to evaluate the existence of single-phase L1(2) solid solutions between pairs of ternary L1(2) trialuminides are presented. Two-kilogram ingots of selected quaternary compositions were cast, homogenized and forged into pancakes; compression specimens were machined from the forgings and tested as a function of temperature. The results are compared against existing data for the ternary alloys. The ternary L1(2) trialuminides Al66Ti25Mn9, Al67Ti25Cr8, and Al22Ti8Fe3 were found to exhibit continuous solubility in one another. The quaternary Cr-Mn composition does not indicate any strength advantage over its ternary counterparts. The continuous replacement of Mn with Fe enhances the strength of the quaternary compound over the ternary Al66Ti25 Mn9.

Kumar, K. S.↗
NASA NTRS1973

Evaluation of ERTS-1 imagery for mapping Quaternary deposits and landforms in the Great Plains and Midwest

The author has identified the following significant results. The main landform associations and larger landforms are readily identifiable on the better images and commonly the gross associations of surficial Quaternary deposits also can be differentiated, primarily by information on landforms and soils. Maps showing the Quaternary geologic-terrain units that can be differentiated from the ERTS-1 images are being prepared for 20-odd potential study areas in Illinois, Iowa, Missouri, Kansas, Nebraska, and South Dakota. Among the more distinct features are the major moraines and outwash channels of the last (Wisconsin) glaciation. Analysis of dissection/drainage patterns from the synoptic imagery is proving useful for detecting anomalies that may be caused by stream diversions and moraines of pre-Wisconsin glaciations, by variable loess deposition, by tectonism, and other factors. Numerous abandoned river valleys have been mapped. Trend-lines of several known pre-Wisconsin moraine systems have been identified in Iowa, Nebraska, and Kansas, and also several similar trend-lines, that may indicate previously unknown moraine systems of middle and possibly early Pleistocene age, have been found in Iowa and Missouri. The area inundated by a major flood in southwestern Iowa also has been delineated from ERTS-1 imagery.

Morrison, R. B.↗
NASA NTRS1973

Mapping quaternary landforms and deposits in the Midwest and Great Plains by means of ERTS-1 multispectral imagery

ERTS-1 multispectral images are proving effective for differentiating many kinds of Quaternary surficial deposits and landforms units in Illinois, Iowa, Missouri, Kansas, Nebraska, and South Dakota. Examples of features that have been distinguished are: (1) the more prominent end moraines of the last glaciation; (2) certain possible palimpsests of older moraines mantled by younger deposits; (3) various abandoned river valleys, including suspected ones deeply filled by deposits; (4) river terraces; and (5) some known faults and a few previously unmapped lineaments that may be faults. The ERTS images are being used for systematic mapping of Quaternary landforms and deposits in about 20 potential study areas. Some study areas, already well mapped, provide checks on the reliability of mapping from the images. For other study areas, previously mapped only partly or not at all, our maps will be the first comprehensive, synoptic ones, and should be useful for regional land-use planning and ground-water, engineering-geology, and other environmental applications.

Morrison, R. B.↗
NASA NTRS1973

Evaluation of ERTS-1 imagery for mapping Quaternary deposits and landforms in the Great Plains and Midwest

The author has identified the following significant results. The main landform associations and larger landforms are readily identifiable on the better images and commonly the gross associations of surficial Quaternary deposits also can be determined primarily by information on landforms and soils (obtained by analysis of stream dissection and drainage and stream-divide patterns, land use patterns, etc.). Maps showing the Quaternary geologic-terrain units that can be distinguished on the ERTS-1 images are being prepared for study areas in Illinois, Iowa, Missouri, Kansas, Nebraska, and South Dakota. Preliminary maps of 1:1,000,000 scale are included for three of the study areas: the Grand Island and Fremont, Nebraska, and the Davenport, Iowa-Illinois, 1 deg x 2 deg quadrangles. These maps exemplify the first phase of investigations, which consists of identifying and mapping landform and land use characteristics and geologic-surficial materials directly from the ERTS-1 images alone, with no additional information. These maps show that commonly the boundaries of geologic-terrain units can be delineated more accurately on ERTS-1 images than on topographic maps at 1:250,000 scale.

Morrison, R. B.↗
NASA NTRS1973

Evaluation of ERTS-1 imagery for mapping Quaternary deposits and landforms in the Great Plains and Midwest

The author has identified the following significant results. The main landform associations and larger landforms are readily identifiable on the better images and commonly the gross associations of surficial Quaternary deposits also can be differentiated, primarily by information on landforms and soils. Maps showing the Quaternary geologic-terrain units that can be differentiated from the ERTS-1 images are being prepared for study areas in Illinois, Iowa, Missouri, Kansas, Nebraska, and South Dakota. Preliminary maps at 1:1 million scale are given of two of the study areas, the Peoria and Decatur, Illinois, 1 deg x 2 quadrangles. These maps exemplify the first phase of investigations, which consists of identifying and mapping landform and land use characteristics and geologic-surficial materials directly from ERTS-1 images alone, without input of additional data. These maps shown that commonly the boundaries of geologic-terrain units can be identified more accurately on ERTS-1 images than on topographic maps of 1:250,000 scale. From analysis of drainage patterns, stream-divide relations, and tone and textural variations on the ERTS-1 images, the trends of numerous moraines of Wisconsinan and possibly some of Illinoian age were mapped. In the Peoria study area the trend of a buried valley of the Mississippi River is revealed.

Morrison, R. B.↗
NASA NTRS1975

Quaternary and quinary modifications of eutectic superalloys strengthened by delta Ni3Cb lamellae and gamma prime Ni3Al precipitates

By means of a compositional and heat treatment optimization program based on the quaternary gamma/gamma prime-delta, a tantalum modified gamma/gamma prime-delta alloy with improved shear and creep strength combined with better cyclic oxidation resistance was identified. Quinary additions, quaternary adjustments, and heat treatment were investigated. The tantalum modified gamma/gamma prime-delta alloy possessed a slightly higher liquidus temperature and exhibited rupture strength exceeding NASA VIA by approximately three and one-half Larson-Miller parameters (C = 20) above 1000 C. Although improvements in longitudinal mechanical properties were achieved, the shear and transverse strength property goals of the program were not met and present a continuing challenge to the alloy metallurgist.

Lemkey, F. D.↗
NASA NTRS1982

Studies of single-mode injection lasers and of quaternary materials. Volume 2: Measurement of electro-optic effects in InGaAsP junction waveguides

Both the linear electro-optic (Pockel's) effect and electroabsorption (Franz-Keldysh effect) in waveguiding junctions of InGaAsP were measured. The electro-optic coefficient is found to be 0.1-0.14x10 to the -12 power m/V at lambda = 1.54 - 1.65 micrometers. Possibly this is the first reported measurement of the electro-optic coefficient for InGaAsP. The value found for the electroabsorption is on the order of 7x10 to the -4 power cm to the -1 power/(V/cm) or approximately 100 cm/1 for fields of 200,000 V/cm at lambda 1.3 micrometers. All measurements were made on a quaternary film with a bandgap wavelength of 1.23 micrometers. Because of the rapid commercial introduction of quaternary lasers, LEDs, and detectors to take advantage of large optical fiber bandwidths and low losses in the 1.2- to 1.7- micrometer region, these measurements are significant in providing some of the basic physical constants needed to design modulators and switches capable of operating at microwave frequencies in this wavelength region.

Hammer, J. M.↗
NASA NTRS1985

Distribution and metabolism of quaternary amines in salt marshes

Quaternary amines such as glycine betaine (GBT) are common osmotically active solutes in much of the marine biota. GBT is accumulated by various bacteria, algae, higher plants, invertebrates, and vertebrates in response to salinity or water stresses; in some species, GBT occurs at tens to hundreds of millimolar concentrations and can account for a significant fraction of total nitrogen. Initial studies suggest that GBT is readily converted to two potential methane precursors, trimethylamine (TMA) and acetate, in anoxic sediments. TMA is apparently the most important methane precursor in surface sediments containing sulfate reducing bacteria. In salt marshes, the bulk of the methane formed may be due to the metabolism of TMA rather than other substrates. Current research is focussed on testing this hypothesis and on determining the role of quaternary amino osmoregulatory solutes in methane fluxes from marine environments. Preliminary studies have dealt with several problems: (1) determination of GBT concentrations in the dominant flora and fauna of salt marshes; (2) synthesis of radiolabelled GBT for metabolic studies; and (3) determination of fates of BGT in marine sediments using radiotracers. Both GC and HPLC techniques have been used to assay GBT concentrations in plant and animal tissues. S. alterniflora is probably the only significant source of GBT (and indirectly of methane) since the biomass and distribution of most other species is limited. Current estimates suggest that S. alterniflora GBT could account for most of the methane efflux from salt marshes.

King, Gary M.↗
NASA NTRS1948

Estimation of F-3 and F-4 knock-limited performance ratings for ternary and quaternary blends containing triptane or other high-antiknock aviation-fuel blending agents

Charts are presented that permit the estimation of F-3 and F-4 knock-limited performance ratings for certain ternary and quaternary fuel blends. Ratings for various ternary and quaternary blends estimated from these charts compare favorably with experimental F-3 and F-4 ratings. Because of the unusual behavior of some of the aromatic blends in the F-3 engine, the charts for aromatic-paraffinic blends are probably less accurate than the charts for purely paraffinic blends.

Barnett, Henry C↗
NASA NTRS1953

Survey of Portions of the Chromium-Cobalt-Nickel-Molybdenum Quaternary System at 1,200 Degrees C

A survey was made of portions of the chromium-cobalt-nickel-molybdenum quaternary system at 1,200 degrees c by means of microscopic and x-ray diffraction studies. Since the face-centered cubic (alpha) solid solutions form the matrix of almost all practically useful high-temperature alloys, the solid solubility limits of the quaternary alpha phase were determined up to 20 percent molybdenum. The component cobalt-nickel-molybdenum, chromium-cobalt-molybdenum, and chromium-nickel-molybdenum ternary systems were also studied. The survey of these systems was confined to the determination of the boundaries of the face-centered cubic (alpha) solid solutions and of the phases coexisting with alpha at 1,200 degrees c.

Rideout, Sheldon Paul↗
NASA NTRS1986

C.A.D. representation of ternary and quaternary phase diagrams

This work is concerned with the utilization of C.A.D. solid-modeling software for the computer representation of three-dimensional phase diagrams. The work was undertaken in two parts. First, the C.A.D. software (I-DEAS, by Structural Dynamics Research Corp.) was integrated with a variety of auxiliary Fortran 77 and I-DEAS language programs which were written specifically for the purpose of phase diagram representation. The capabilities of the resulting suite of software for three-dimensional phase diagram representation were developed and illustrated by the construction, display and manipulation of solid-model phase diagrams for a hypothetical quaternary eutectic system. The results of this work are discussed in some detail in the attached publication ('Solid-modeling: a C.A.D. Alternative for Three-dimensional Phase Diagram Representation'). Such a technique is of general applicability, having utility in both research and education. Secondly, using the C.A.D. technique, data from the literature (gleaned from some 70 separate publications), which represent experimentally determined phase boundaries, were combined to form solid-model representations of the CMS2-M2S-S ternary space diagram and the CMS2-CAS2-M2S-S quaternary liquidus projection (where C=CaO, M=MgO, A=Al2O3, and S=SiO2). These diagrams were utilized in a concurrent study of solidification in the CMAS system.

Delao, James D.↗
NASA NTRS2008

Effects of Palladium Content, Quaternary Alloying, and Thermomechanical Processing on the Behavior of Ni-Ti-Pd Shape Memory Alloys for Actuator Applications

The need for compact, solid-state actuation systems for use in the aerospace, automotive, and other transportation industries is currently driving research in high-temperature shape memory alloys (HTSMA) having transformation temperatures above 100 C. One of the basic high temperature systems under investigation to fill this need is NiTiPd. Prior work on this alloy system has focused on phase transformations and respective temperatures, no-load shape memory behavior (strain recovery), and tensile behavior for selected alloys. In addition, a few tests have been done to determine the effect of boron additions and thermomechanical treatment on the aforementioned properties. The main properties that affect the performance of a solid state actuator, namely work output, transformation strain, and permanent deformation during thermal cycling under load have mainly been neglected. There is also no consistent data representing the mechanical behavior of this alloy system over a broad range of compositions. For this thesis, ternary NiTiPd alloys containing 15 to 46 at.% palladium were processed and the transformation temperatures, basic tensile properties, and work characteristics determined. However, testing reveals that at higher levels of alloying addition, the benefit of increased transformation temperature begins to be offset by lowered work output and permanent deformation or "walking" of the alloy during thermal cycling under load. In response to this dilemma, NiTiPd alloys have been further alloyed with gold, platinum, and hafnium additions to solid solution strengthen the martensite and parent austenite phases in order to improve the thermomechanical behavior of these materials. The tensile properties, work behavior, and dimensional stability during repeated thermal cycling under load for the ternary and quaternary alloys were compared and discussed. In addition, the benefits of more advanced thermomechanical processing or training on the dimensional stability of these alloys during repeated actuation were investigated. Finally, the effect of quaternary alloying on the thermal stability of NiTiPdX alloys is determined via thermal cycling of the materials to increasing temperatures under load. It was found that solid solution additions of platinum and gold resulted in about a 30 C increase in upper use temperature compared to the baseline NiTiPd alloy, providing an added measure of over-temperature protection.

Bigelow, Glen↗
NASA NTRS2023

The Nature of Quaternary Climate Change

Dynamic interactions between atmosphere, hydrosphere, lithosphere, and biosphere, driven by solar energy and modulated by atmospheric greenhouse gasses, volcanism, and plate tectonics produce substantial variations in Earth's climate over geologic time. Major Quaternary drivers of climate change include variations in Earth's orbital cycles, global temperature, natural atmospheric greenhouse gasses, and continental ice mass. Multiple abrupt climate perturbations with onsets of a century to decades have also occurred. Since the 1970s, geologically unprecedented rising levels of anthropogenic greenhouse gasses from fossil fuel combustion, industry, and agriculture have become the dominant contributors to rising global temperature, glacier and ice sheet losses, and sea level rise.

Solar variability↗