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Results for “RH_Dry”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Impact of processing humidity on ionomer film structure and performance in hydroxide exchange membrane electrolyzers

Hydroxide exchange membrane electrolyzers (HEMELs) enable hydrogen production using low-cost, earth-abundant materials. Improving electrode fabrication is integral to enhancing device performance, and ionomer-responsible for transporting hydroxide and mechanically supporting the catalyst-is a major component. Here, we use experiments and computation to study the effects of relative humidity (RH) during the drying process of poly(aryl piperidinium) ionomer films on HEMEL electrodes. Broadly, the drying environments determine the physical structure and electrochemical traits of the ionomer network. High RH drying yields a highly porous network with excessive water uptake, structural defects, washout, and 64% reduction in hydroxide conductivity. Extremely low RH drying produces an overly compact pore network that hinders hydroxide mobility. In contrast, moderately low RH drying (9% RH) creates an ionomer film with well-balanced traits: excellent mechanical stability and connectivity needed for catalyst retention and hydroxide transport, which improves HEMEL performance by 40% at 1.8 V compared to suboptimal RHs. This research advances HEMEL manufacturing by providing a simple, scalable, and low-cost approach to optimize electrode ionomer films.

36 MATERIALS SCIENCE↗

Effects of spatial resolution on WRF v3.8.1 simulated meteorology over the central Himalaya

The sensitive ecosystem of the central Himalayan (CH) region, which is experiencing enhanced stress from anthropogenic forcing, requires adequate atmospheric observations and an improved representation of the Himalaya in the models. However, the accuracy of atmospheric models remains limited in this region due to highly complex mountainous topography. This article delineates the effects of spatial resolution on the modeled meteorology and dynamics over the CH by utilizing the Weather Research and Forecasting (WRF) model extensively evaluated against the Ganges Valley Aerosol Experiment (GVAX) observations during the summer monsoon. The WRF simulation is performed over a domain (d01) encompassing northern India at 15 km x 15 km resolution and two nests (d02 at 5 km x 5 km and d03 at 1 km x 1 km) centered over the CH, with boundary conditions from the respective parent domains. WRF simulations reveal higher variability in meteorology, e.g., relative humidity (RH = 70.3%-96.1%) and wind speed (WS = 1.1-4.2m s(-1)), compared to the ERA-Interim reanalysis (RH D 80.0%-85.0%, WS D 1.2-2.3m s(-1)) over northern India owing to the higher resolution. WRF-simulated temporal evolution of meteorological variables is found to agree with balloon-borne measurements, with stronger correlations aloft (r = 0.44-0.92) than those in the lower troposphere (r = 0.18-0.48). The model overestimates temperature (warm bias by 2.8 degrees C) and underestimates RH (dry bias by 6.4 %) at the surface in d01. Model results show a significant improvement in d03 (P = 827.6 hPa, T = 19.8 degrees C, RH = 92.3 %), closer to the GVAX observations (P = 801.4 hPa, T = 19.5 degrees C, RH = 94.7 %). Interpolating the output from the coarser domains (d01, d02) to the altitude of the station reduces the biases in pressure and temperature; however, it suppresses the diurnal variations, highlighting the importance of well-resolved terrain (d03). Temporal variations in near-surface P, T, and RH are also reproduced by WRF in d03 to an extent (r>0:5). A sensitivity simulation incorporating the feedback from the nested domain demonstrates the improvement in simulated P, T, and RH over the CH. Our study shows that the WRF model setup at finer spatial resolution can significantly reduce the biases in simulated meteorology, and such an improved representation of the CH can be adopted through domain feedback into regional-scale simulations. Interestingly, WRF simulates a dominant easterly wind component at 1 km x 1 km resolution (d03), which is missing in the coarse simulations; however, the frequency of southeasterlies remains underestimated. The model simulation implementing a highresolution (3 s) topography input (SRTM) improved the prediction of wind directions; nevertheless, further improvements are required to better reproduce the observed local-scale dynamics over the CH.

Singh, Jaydeep↗

TRACER-CAT-UCDAVIS Aerosol Optical Properties and Sizing - crdps

Aerosol size distribution and optical properties collected in La Port TX, during TRACER-CAT-UCDavis, July 2022. Speciated particle composition measurements are reported separately. All sampling was conducted with an identical aerosol inlet as the standard ARM-AOS systems. The TRacking Aerosol Convection interactions ExpeRiment Carbonaceous Aerosols Thrust by UC Davis (TRACER-CAT-UCDavis, July 2022) was designed to complement the larger ARM TRACER science goals to understand convective cloud lifecycles and aerosol-convection interactions. TRACER-CAT-UCDavis is focused on understanding the relationship between particle composition and light absorption and the influence of water uptake on this relationship. This aerosol data can be used to understand the relationship between particle composition and light absorption and the influence of water uptake on this relationship. Instruments include: UC Davis two-wavelength cavity ringdown-photoacoustic spectrometer (CRD-PAS); Brechtel scanning electrical mobility sizer (SEMS); modified humidified cavity attenuated phase shift spectrometer with single scatter albedo (H-CAPS-SSA)

54 ENVIRONMENTAL SCIENCES↗