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At least 19 records

The Rim Inertial Measuring System (RIMS)

The rim inertial measuring system (RIMS) is introduced and an approach for extracting angular rate and linear acceleration information from a RIMS unit is presented and discussed. The RIMS consists of one or more small annular momentum control devices (AMCDs), mounted in a strapped down configuration, which are used to measure angular rates and linear accelerations of a moving vehicle. An AMCD consists of a spinning rim, a set of noncontacting magnetic bearings for supporting the rim, and a noncontacting electromagnetic spin motor. The approach for extracting angular rate and linear acceleration information is for a single spacecraft mounted RIMS unit.

Groom, N. J.↗

Analysis of the Rim Inertial Measuring System (RIMS)

Nonlinear equations of motion are derived for the rim inertial measuring system, which is mounted in a strapped down configuration on a carrier vehicle. The measurement and equations derived from angular rates and linear accelerations were interfaced with the dynamic model of a user defined carried vehicle. Two methods are presented for rate measurement, and the results of the nonlinear computer simulation are presented.

Joshi, S. M.↗

Alteration and formation of rims on the CM parent body

All types of coarse-grained components in CM chondrites are surrounded by fine-grained dust coatings, but the origin of these rims is not yet clear. Although a strictly nebular origin seems likely for rims in the relatively unaltered type 3 chondrites, the rims in CM chondrites are dominated by secondary alteration phases. It has been argued that either the coarse-grained cores accreted altered rim materials while still in the nebula or that alteration of primary rim phases occurred on the CM parent body. To constrain the origin of alteration phases in rim material, we have analyzed the textures and mineral associations from 10 CM chondritic falls by optical and scanning electron microscopy. Our results indicate that the secondary phases in CM chondritic rims were produced by parent body fluid-rock interactions which redefined some primary rim textures and may have produced, in some cases, both coarse-grained components and the rims that surround them. Textural features demonstrate the interactive exchange of alteration fluids between rims, matrix, and chondrules on the CM parent body. For example, most matrix-rim contacts are gradational, suggesting the synchronous alteration of both components. Several observations suggest the possibility of in situ rim production. For example, tochilinite and phyllosilicates commonly form rims around matrix carbonates, which are generally believed to have precipitated from alteration fluids on the CM parent body. This suggests that the rims surrounding matrix carbonates may also have been produced by alteration processes. Partially replaced chondrule olivines bear a striking resemblance to many rimmed olivines in the matrix which suggests, by analogy, that site-specific precipitation of S-bearing phases may also be responsible for the occurrence of many tochilinite-rich rims around isolated matrix olivines. Non-silicate rims precipitate around olivines of any composition, but the process is most effective for fayalitic olivines. Most of the remaining olivines in CM chondrites are relatively Mg-rich, which suggests that the precipitation of S-bearing rims on olivines may not have been an important process in the aqueous alteration of CM chondrites. We conclude that: (1) precursor rim materials in CM chondrites were subjected to pervasive aqueous alteration on the CM parent body; and (2) textures and mineral associations observed in CM chondrites also suggest the possibility of in situ rim production.

Browning, Lauren B.↗

A FIB/TEM/Nanosims Study of a Wark-Lovering Rim on an Allende CAI

Ca- Al-rich inclusions (CAIs) are commonly surrounded by Wark-Lovering (WL) rims - thin (approx. 50 micrometers) multilayered sequences - whose mineralogy is dominated by high temperature minerals similar to those that occur in the cores of CAIs [1]. The origins of these WL rims involved high temperature events in the early nebula such as condensation, flashheating or reaction with a nebular reservoir, or combinations of these processes. These rims formed after CAI formation but prior to accretion into their parent bodies. We have undertaken a coordinated mineralogical and isotopic study of WL rims to determine the formation conditions of the individual layers and to constrain the isotopic reservoirs they interacted with during their history. We focus here on the spinel layer, the first-formed highest- temperature layer in the WL rim sequence. Results and Discussion: We have performed mineralogical, chemical and isotopic analyses of an unusual ultrarefractory inclusion from the Allende CV3 chondrite (SHAL) consisting of an approx. 500 micrometers long single crystal of hibonite and co-existing coarsegrained perovskite. SHAL is partially surrounded by WL rim. We previously reported on the mineralogy, isotopic compositions and trace elements in SHAL [2-4]. The spinel layer in the WL rim is present only on the hibonite and terminates abruptly at the contact with the coarse perovskite. This simple observation shows that the spinel layer is not a condensate in this case (otherwise spinel would have condensed on the perovskite as well). The spinel layer appears to have formed by gas-phase corrosion of the hibonite by Mg-rich vapors such that the spinel layer grew at the expense of the hibonite. We also found that the spinel layer has the same 16Orich composition as the hibonite. The spinel layer is polycrystalline and individual crystals do not show a crystallographic relationship with the hibonite. An Al-diopside layer overlies the spinel layer, and is present on both the hibonite and perovskite. While the spinel is 16O-rich, WL-rim perovskite and pyroxene are 16O-poor. This isotopic heterogeneity likely reflects O isotopic equilibration of WL-rim perovskite and pyroxene with a planetary O isotopic reservoir after the WL rim formation. The hibonite is zoned and contains wt.% levels of Ti, Mg and Fe in contact with the Fe-bearing spinel (Sp60Hc40) in the WL rim. The Fe enrichment in spinel is likely related to the Na-Fe metasomatism that is ubiquitous in Allende. Conclusions: The petrography and microstructure of the spinel layer in a WL rim sequence shows that it formed by gas phase reactions at high temperature in the nebula. The oxygen isotopic composition of the spinel indicates that this WL rim layer formed in the same (or similar) nebular gas reservoir as the host CAI.

Keller, L. P.↗

Influence of Vane Trailing Edge Flow on the Formation of Cavity Cells and Rim Sealing

Abstract Hot gas ingestion into the turbine rim seal cavity is an important concern for engine designers. To prevent ingestion, rim seals use high-pressure purge flow; however, the penalty is that excessive use of the purge flow decreases engine thermal efficiency. In this paper, a one-stage turbine operating at engine-representative conditions was used to study the effect of steady and time-resolved under-platform cavity temperatures and pressures across a range of coolant flowrates in the presence of vane trailing edge (VTE) flow. This study correlates time-resolved pressure with time-resolved temperature to identify primary frequencies driving ingestion. At certain flowrates, the time-resolved pressures are out of phase with the temperatures, indicating ingestion. Measurements from high-frequency response pressure sensors in the rim seal and vane platform were also used to determine rotational speed and quantity of large-scale structures (cells). In a parallel effort, a computational model using Unsteady Reynolds-averaged Navier–Stokes (URANS) was applied to determine swirl ratio in the rim seal cavity and time-resolved rim sealing effectiveness. The experimental results confirm that at low purge flowrates, the VTE flow influences the unsteady flow field by decreasing pressure unsteadiness in the rim seal cavity. Results show an increase in purge flow increases the number of unsteady large-scale structures in the rim seal and decreases their rotational speed. However, VTE flow was shown to not significantly change the cell speed and count in the rim seal. Simulations point to the importance of the large-scale cell structures in influencing rim sealing unsteadiness, which is not captured in current rim sealing predictive models.

Engineering↗

The contribution of vapor deposition to amorphous rims on lunar soil grains

Recent analysis analytical electron microscope study of lunar soils showed that the approximately 60-nm-wide amorphous rims surrounding many lunar soils grains exhibit distinct compositional differences from their hosts. On average, the amorphous rim compositions reflect the local bulk soil composition with the exceptions of Si and S, which are enriched relative to the bulk soil. These chemical trends led us to propose that the amorphous rims were in fact deposits of impact-generated vapors produced during regolith gardening, a hypothesis that runs contrary to the generally accepted view that the rims are produced through amorphization of the outer parts of mineral grains by interaction with the solar wind. Analytical data are reported for amorphous rims on individual minerals in lunar soils in order to show that the magnitude of the chemical differences between rim and host are so great that they require a major addition of foreign elements to the grain surfaces. The average composition of amorphous rims is listed as a function of host mineralogy as determined in microtone thin sections using energy-dispersive X-ray spectrometry in the transmission electron microscope. As the host mineral becomes chemically more complex, the chemical differences are not as clear. The average rim compositions are remarkably similar and are independent of the host grain mineralogy. Whether there are 'sputtering' or radiation effects superimposed on the vapor-deposited material can be debated. We do not explicitly exclude the effects of radiation damage as a contributing factor to the formation of amorphous rims; we are merely emphasizing the major role played by condensed vapors in the formation of amorphous rims on lunar soil grains.

Keller, L. P.↗

Trace Element Abundances Measured in Concentric and Texturally Distinct Fine-Grained Rims Surrounding Allende Chondrules

Layered rims of dust-sized material surround some chondrules and other early formed nebular particles, such as calcium aluminum inclusions in chondritic meteorites. In the Allende meteorite most chondrules(~85%) are un-rimmed and in direct contact with the host matrix material [1]. When present, rim thickness appears correlated to underlying particle size in both the Allende and Murchison chondrites [1,2]. This diverse behavior strongly argues for pre-parent body formation of rimmed particles as they traversed distinct (cooler and/or dustier) nebular environments [1]. Nebular rim formation involves accretion of unequilibrated dust to chondrule surfaces, recording evidence for the formation of at least two separate particle populations (chondrules and dust) that interacted in the nebula, and therefore potentially record distinct nebular reservoirs (e.g. [3-5]). Additionally, some particles exhibit textural evidence for multiple rim layers, (e.g., [1], further investigated herein). Herein, we evaluate the chemistry of concentrically and texturally distinct chondrule rim layers to investigate the possibility of discrete rim formation events recorded by individual chondrules (Fig. 1A,B). Using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) we measure major, minor, and trace elements of the rims and particles in Allende. Samples were characterized in detail previously by electron microanalysis for their mineralogy, textures, particle size, and rim thickness(es) [1].

Chondrites↗

Chondrule rims and interchondrule matrix in UOC

Opaque rims around chondrules and clasts were distinguished from opaque, interchondrule matrix apparently unrelated spatially to chondrules and clasts. Microprobe and electron microscope techniques were used. The mean chemical composition for dark rim and matrix in Bishunpur and Tieschitz are similar to the opaque matrix of Huss, et al. However, the mean dark rim compositions in Bishunpur have significantly higher Fe, and lower Na, K, Al and Si than opaque interchondrule matrix. The opaque matrix of Huss, et al, essentially lies between these compositions. In Tieschitz only rim material was observed. In Tieschitz the rims are Si-poor and dominated by normative olivine (Fo50). Again there is an Na, K, Al component but is often nepheline normative rather than albitic. It too is probably present as glass, Ashworth (pers.comm.). In Bishunpur rims as well as the silicate-FeS, FeNi layering described by Allen, et al, discontinuous layering was observed within the silicate portion. This is apparently due to variations in the proportions of the components, particularly in the glassy phase. In Bishunpur there is a strong genetic link between matrix and rims, although rims seem to have formed under different, possibly more oxidizing, conditions. Also the presence of the same component in rims, matrix chondrules, and clasts suggests a common source.

Alexander, C.↗

Two chondrule groups each with distinctive rims in Murchison recognized by cathodoluminescence

Two groups of chondrules in the Murchison CM chondrite, which have previously been identified on the basis of FeO in the chondrule grains, are readily identified from cathodoluminescence (CL) and belong to those of the ordinary chondrite group A and B chondrules of Sears et al. (1992a). All chondrules are surrounded by fine-grained rims containing forsterite with bright red CL, but on group A chondrules an outer thin rim grades into a much thicker rim, with a lower density of forsterite grains, which in turn grades into the central chondrule. Group B chondrules have only the thin outer rim with a high density of small forsterite grains. This is the first time an unequivocal correlation has been observed between chondrule rim thickness and the composition of the object on which the rim is located. We suggest that while all objects in the meteorite (group B chondrules, refractory inclusions, mineral and chondrule fragments, clasts) acquired a very thin rim during processing in a wet regolith, the thick rims on group A chondrules were formed by aqueous alteration of precursor metal- and sulfide-rich rims which are a characteristic of group A chondrules in ordinary chondrites.

Sears, Derek W. G.↗

Aqueous Alteration of Endeavour Crater Rim Apron Rocks

Mars Exploration Rover Opportunity is exploring Noachian age rocks of the rim of 22 km diameter Endeavour crater. Overlying the pre-impact lithologies and rim breccias is a thin apron of fine-grained sediments, the Grasberg fm, forming annuli on the lower slopes of rim segments. Hesperian Burns fm sandstones overly the Grasberg fm. Grasberg rocks have major element compositions that are distinct from Burns fm sandstones, especially when comparing interior compositions exposed by the Rock Abrasion Tool. Grasberg rocks are also different from Endeavour rim breccias, but have general compositional similarities to them. Grasberg sediments are plausibly fine-grained materials derived from the impact breccias. Veins of CaSO4 transect Grasberg fm rocks demonstrating post-formation aqueous alteration. Minor/trace elements show variations consistent with mobilization by aqueous fluids. Grasberg fm rocks have low Mn and high Fe/Mn ratios compared to the other lithologies. Manganese likely was mobilized and removed from the Grasberg host rock by redox reactions. We posit that Fe2+ from acidic solutions associated with formation of the Burns sulfate-rich sandstones acted as an electron donor to reduce more oxidized Mn to Mn2+. The Fe contents of Grasberg rocks are slightly higher than in other rocks suggesting precipitation of Fe phases in Grasberg materials. Pancam spectra show that Grasberg rocks have a higher fraction of ferric oxide minerals than other Endeavour rim rocks. Solutions transported Mn2+ into the Endeavour rim materials and oxidized and/or precipitated it in them. Grasberg has higher contents of the mobile elements K, Zn, Cl, and Br compared to the rim materials. Similar enrichments of mobile elements were measured by the Spirit APXS on West Spur and around Home Plate in Gusev crater. Enhancements in these elements are attributed to interactions of hydrothermal acidic fluids with the host rocks. Interactions of fluids with the Grasberg fm postdate the genesis of the Endeavour rim phyllosilicates. The aqueous alteration history of Endeavour rim rocks is complicated by different styles of alteration that have spanned the Noachian and Hesperian. Late stage acidic aqueous alteration of Grasberg fm materials is likely penecontemporaneous with the diagenesis of the sulfate-rich sediments of Meridiani Planum.

Mittlefehldt, David W.↗

Microstructural and Isotopic Constraints on WL Rim Formation

Coordinated microanalyses of Wark-Lovering (WL) rims are needed to best understand their origin and to decipher their subsequent evolution both in the nebular and parent body settings. Here we present the mineralogy, petrology, microstructures, O isotopic compositions, and Al-Mg systematics of a WL rim on a Type B CAI, ‘‘Big Guy”, from the reduced CV3 chondrite Vigarano [1]. Our SEM and TEM study reveals seven distinct mineral layers in the WL rim that include: (1) gehlenite with rare grossite, (2) hibonite, (3) spinel with minor hibonite and perovskite, (4) zoned melilite (Åk(sub ~0-10)), (5) anorthite, (6) zoned diopside grading outwards from Al,Ti-rich to Al,Tipoor, and (7) forsterite intergrown with diopside. We infer a two-stage history in which WL rim formation was initiated by flash melting and extensive evaporation of the original inclusion edge, followed by subsequent condensation under highly dynamic conditions. The outermost edge of the CAI mantle is mineralogically and texturally distinct compared to the underlying mantle that is composed of coarse, zoned melilite (Åk(sub ~10-60)) grains. The mantle edge contains finegrained gehlenite with hibonite and rare grossite that likely formed by rapid crystallization from a Ca,Al-rich melt produced during a flash vaporization event [2]. These gehlenite and hibonite layers are surrounded by successive layers of spinel, melilite, diopside, and forsterite, indicating their sequential gas-solid reactions onto hibonite. Anorthite occurs as a discontinuous layer that corrodes adjacent melilite and Al-diopside, and appears to have replaced them [3,4], probably even later than the forsterite layer formation. All the WL rim minerals analyzed using the JSC NanoSIMS 50L are 16O-rich (Δ17O ≈ −23‰), indicating their formation in an 16O-rich gas reservoir. Our data are in contrast with many CV CAIs that show heterogeneous Δ 17O values across their WL rims [5]. Our Al-Mg data obtained using the UCLA ims-1290 ion microprobe of the CAI interior and the WL rim define a well-correlated isochron with (26Al/27Al)(sub 0) = 4.94 × 10(exp −5), indicating their synchronous formation ≤5 × 10(exp 4) years after the canonical CAI value. In contrast, no 26Mg excesses are observed in the WL rim anorthite, which suggests its later formation or later isotopic resetting in an 16O-rich gas reservoir, after 26Al had decayed.

Han, J.↗

Formation Timescales of Amosphous Rims on Lunar Grains Derived from ARTEMIS Observations

The weathering of airless bodies exposed to space is a fundamental process in the formation and evolution of planetary surfaces. At the Moon, space weathering induces a variety of physical, chemical, and optical changes including the formation of nanometer-sized amorphous rims on individual lunar grains. These rims are formed by vapor redeposition from micrometeoroid impacts and ion irradiation-induced amorphization of the crystalline matrix. For ion irradiation-induced rims, however, laboratory experiments of the depth and formation timescales of these rims stand in stark disagreement with observations of lunar soil grains. We use observations by the Acceleration, Reconnection, Turbulence, and Electrodynamics of the Moon's Interaction with the Sun (ARTEMIS) spacecraft in orbit around the Moon to compute the mean ion flux to the lunar surface between 10 eV and 5 MeV and convolve this flux with ion irradiation-induced vacancy production rates as a function of depth calculated using the Stopping Range of Ions in Matter model. By combining these results with laboratory measurements of the critical fluence for charged-particle amorphization in olivine, we can predict the formation timescale of amorphous rims as a function of depth in olivinic grains. This analysis resolves two outstanding issues: (1) the provenance of >100 nm amorphous rims on lunar grains and (2) the nature of the depth-age relationship for amorphous rims on lunar grains.

Amorphous Rims↗

The origin of amorphous rims on lunar plagioclase grains: Solar wind damage or vapor condensates

A distinctive feature of micron sized plagioclase grains from mature lunar soils is a thin (20 to 100 nm) amorphous rim surrounding the grains. These rims were originally described from high voltage electron microscope observations of lunar plagioclase grains by Dran et al., who observed rims up to 100 nm thick on plagioclase grains from Apollo 11 and 12 soils. These rims are believed to be the product of solar wind damage. The amorphous rims were studied on micron sized plagioclase grains from a mature Apollo 16 soil using a JEOL 200FX transmission electron microscope equipped with an energy dispersive x ray spectrometer. It was found that the amorphous rims are compositionally distinct from the interior plagioclase and it is proposed that a major component of vapor condensates is present in the rims.

Keller, Lindsay P.↗

Cooling of Gas Turbines: Effectiveness of Rim Cooling of Blades - 2

An analysis is presented of rim cooling of gas-turbine blades; that is, reducing the temperature at the base of the blade (wheel rim), which cools the blade by conduction alone. Formulas for temperature and stress distributions along the blade are derived and, by the use of experimental stress-rupture data for a typical blade alloy, a relation is established between blade life (time for rupture), operating speed, and amount of rim cooling for several gas temperatures. The effect of blade parameter combining the effects of blade dimensions, blade thermal conductivity, and heat-transfer coefficient is determined. The effect of radiation on the results is approximated. The gas temperatures ranged from 1300F to 1900F and the rim temperature, from 0F to 1000F below the gas temperature. This report is concerned only with blades of uniform cross section, but the conclusions drawn are generally applicable to most modern turbine blades. For a typical rim-cooled blade, gas temperature increases are limited to about 200F for 500F of cooling of the blade base below gas temperature, and additional cooling brings progressively smaller increases. In order to obtain large increases in thermal conductivity or very large decreases in heat-transfer coefficient or blade length or necessary. The increases in gas temperature allowable with rim cooling are particularly small for turbines of large dimensions and high specific mass flows. For a given effective gas temperature, substantial increases in blade life, however, are possible with relatively small amounts of rim cooling.

Wolfenstein, Lincoln↗

Space Plasma Ion Processing of the Lunar Soil: Modeling of Radiation-Damaged Rim Widths on Lunar Grains

Chemically and microstructurally complex altered rims around grains in the finest size fraction (<20 micron) of the lunar regolith are the result of multi-stage processes involving both solar ion radiation damage and nanoscale deposition of impact or sputter-derived vapors. The formation of the rims is an important part of the space weathering process, and is closely linked to key changes in optical reflectance and other bulk properties of the lunar surface. Recent application of field-emission scanning transmission electron microscope techniques, including energy dispersive X-ray spectral imaging, is making it easier to unravel the "nano-stratigraphy" of grain rims, and to delineate the portions of rims that represent Radiation-Amorphized (RA) host grain from overlying amorphous material that represents vapor/sputter deposits. For the portion of rims formed by host grain amorphization (henceforth called RA rims), we have been investigating the feasibility of using Monte Carlo-type ion-atom collision models, combined with experimental ion irradiation data, to derive predictive numerical models linking the width of RA rims to the grain s integrated solar ion radiation exposure time.

Chamberlin, S.↗

FIB-NanoSIMS-TEM Coordinated Study of a Wark-Lovering Rim in a Vigarano Type A CAI

Wark-Lovering (WL) rims are thin multi layered mineral sequences that surround most Ca, Al-rich inclusions (CAIs). Unaltered WL rims are composed of the same primary high temperature minerals as CAIs, such as melilite, spinel, pyroxene, hibonite, perovskite, anorthite and olivine. It is still unclear whether the rim minerals represent a different generation formed by a separate event from their associated CAIs or are a byproduct of CAI formation. Several models have been proposed for the origins of WL rims including condensation, flashheating, reaction of a CAI with a Mg-Si-rich reservoir (nebular gas or solid); on the basis of mineralogy, abundances of trace elements, O and Mg isotopic studies. Detailed mineralogical characterizations of WL rims at micrometer to nanometer scales have been obtained by TEM observations, but so far no coordinated isotopic - mineralogical studies have been performed. Thus, we have applied an O isotopic imaging technique by NanoSIMS 50L to investigate heterogeneous distributions of O isotopic ratios in minerals within a cross section of a WL rim prepared using a focused ion beam (FIB) instrument. After the isotopic measurements, we determine the detailed mineralogy and microstructure of the same WL FIB section to gain insight into its petrogenesis. Here we present preliminary results from O isotopic and elemental maps by NanoSIMS and mineralogical analysis by FE-SEM of a FIB section of a WL rim in the Vigarano reduced CV3 chondrite.

Cai, A.↗

Multispectral Evidence of Alteration from Murray Ridge to Marathon Valley Observed by the Opportunity Pancam on the Rim of Endeavour Crater, Mars

The Mars Exploration Rover Opportunity has been traversing the rim of the Noachian‐aged, 22 km diameter Endeavour crater. Circa sol 3390 of its mission, Opportunity reached the northern tip of the rim segment known as Solander Point and has since been traversing the rim to the south to its current location at the break in the rim known as Marathon Valley. The rocks making up the rim are dominated by impact breccias consisting of clasts and a finer‐grained matrix. Several segments of the rim are transected by fractures as observed from orbital HiRISE imagery. Pancam multispectral observations of outcrop in these fracture regions, including part of the rim crest dubbed Murray Ridge, the Hueytown fracture, and Marathon Valley have been made. Over the range of 430 to 1010 nm there are changes in the multispectral reflectance signature of the breccia matrix with an increase in 535 nm and 904 nm band depth. This is attributed to oxidation and an increase in ferric oxides in these areas. In situ observations by the rover's APXS also indicate chemical differences associated with the matrix along these fractures, including increasing Fe/Mn southward from Solander Point to a region having an Al‐OH signature in CRISM spectra, and generally higher SO3 in the Hueytown fracture region and the area around Spirit of St. Louis. Overturned rocks observed on Murray Ridge were determined by the APXS to have elevated Mn and Pancam spectra of the high Mn spots have a characteristic red, featureless slope. This spectrum was also observed in association with some coatings on blocks of the sulfate‐rich Grasberg formation. Spectra resembling red hematite are observed in some zones in association with the craterform feature Spirit of St. Louis outside the mouth (to the west) of Marathon Valley. Marathon Valley itself has been observed from orbital hyperspectral observations by the CRISM sensor to host occurrences of Fe/Mg smectite minerals‐ indicating extensive aqueous alteration in this region. Pancam observations in Marathon Valley will play an important role in surveying outcrop and making VNIR spectral comparisons with clay bearing outcrop examined earlier in the mission at the Matijevic Hill region.

Farrand, W. H.↗