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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2022

GNSS-RO Deep Refraction Signals from Moist Marine Atmospheric Boundary Layer (MABL)

The marine atmospheric boundary layer (MABL) has a profound impact on sensible heat and moisture exchanges between the surface and the free troposphere. The goal of this study is to develop an alternative technique for retrieving MABL-specific humidity (q) using GNSS-RO data in deep-refracted signals. The GNSS-RO signal amplitude (i.e., signal-to-noise ratio or SNR) at the deep straight-line height (H(SL)) was been found to be strongly impacted by water vapor within the MABL. This study presents a statistical analysis to empirically relate the normalized SNR (S(RO)) at deep HSL to the MABL q at 950 hPa (~400 m). When compared to the ERA5 reanalysis data, a good linear q–S(RO) relationship is found with the deep H(SL) S(RO) data, but careful treatments of receiver noise, SNR normalization, and receiver orbital altitude are required. We attribute the good q–S(RO) correlation to the strong refraction from a uniform, horizontally stratiform and dynamically quiet MABL water vapor layer. Ducting and diffraction/interference by this layer help to enhance the S(RO) amplitude at deep H(SL). Potential MABL water vapor retrieval can be further developed to take advantage of a higher number of S(RO) measurements in the MABL compared to the Level-2 products. A better sampled diurnal variation of the MABL q is demonstrated with the S(RO) data over the Southeast Pacific (SEP) and the Northeast Pacific (NEP) regions, which appear to be consistent with the low cloud amount variations reported in previous studies.

diurnal variation↗
NASA NTRSDate not supplied

Impacts from Assimilating Large Volumes of GNSS Radio Occultation (RO) Observations during ROMEX in NASA’s Global Earth Observing System

The GNSS Radio Occultation (RO) Modeling Experiment (ROMEX) seeks to quantify the benefit of the increasing quantity of RO observations available for use in operational numerical weather prediction (NWP) systems and products. ROMEX includes participation from multiple operational NWP centers and NWP models, among them are NASA’s Global Earth Observing System (GEOS) model produced and run at the Global Modeling and Assimilation Office (GMAO). The design of the numerical experiments core to ROMEX include: 1) a control model run that includes all the RO observations currently used operationally with the sole exception of those from commercial sources and 2) a ROMEX model run that adds to the control over 25 thousand additional RO profiles per day from commercial RO providers, with both experiments run over the three-month period of September through November 2022. The ROMEX model run greatly augments the relatively small subset of the currently available commercial RO profiles which have been purchased for routine use in operational NWP by the various NWP centers. While this smaller subset of commercial RO profiles currently used in operations has been shown to have a positive impact on NWP forecasts, the additional impact from the ROMEX RO dataset has yet to be determined and is the focus of ROMEX. Results from GEOS are presented, including the impact on both analyses and forecasts over the study period and statistics using the forecast sensitivity-based observation impact (FSOI) method. The impact from varying the method of quality control and specifying the observation uncertainty for RO observations within the GEOS data assimilation system is also examined.

Michael J Murphy↗
DOE OSTI2025

A fully ro-vibrationally resolved corona model for the molecular hydrogen Fulcher-𝛼 system

A ro-vibrationally resolved corona model for the molecular hydrogen Fulcher-𝛼 transition based on the Yacora solver is introduced. The model couples 1365 ro-vibrational levels of the 𝑋 1 ⁢𝛴$^+_𝑔$, 𝑑 3⁢ 𝛱 𝑢 and 𝑎 3 ⁢𝛴$^+_𝑔$ states via electron impact excitation from the ground state into the 𝑑 3⁢ 𝛱 𝑢 state and subsequent spontaneous emission into the 𝑎 3 ⁢𝛴$+_𝑔$ state. For the process of electron impact excitation a set of 45260 fully ro-vibrationally resolved cross sections calculated with the molecular convergent close-coupling (MCCC) method in the adiabatic-nuclei formulation is applied. The MCCC cross sections are compared with results of a scaling method used in other works, demonstrating the need for dedicated ro-vibrationally resolved cross sections. By post-processing the model output, entire Fulcher spectra can be simulated. These spectra are benchmarked with measurements from an inductively coupled plasma discharge at a pressure between 1.1–10 Pa and a RF power of 700 W. The model results agree very well with the experiment both in relative shape and in absolute value. A non-ro-vibrationally resolved, purely electronically resolved collisional radiative model for molecular hydrogen (including further states and reaction channels) is applied to investigate the validity of the corona approximation for the benchmark plasmas and the relevance of possible process extensions of the corona model. Furthermore, the influence of collisional quenching, autoionization and predissociation is discussed.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS2022

Global GNSS-RO Electron Density in the Lower Ionosphere

Lack of instrument sensitivity to low electron density (Ne) concentration makes it difficult to measure sharp Ne vertical gradients (four orders of magnitude over 30 km) in the D/E-region. A robust algorithm is developed to retrieve global D/E-region Ne from the high-rate GNSS radio occultation (RO) data, to improve spatio-temporal coverage using recent SmallSat/CubeSat constellations.The new algorithm removes F-region contributions in the RO excess phase profile by fitting a linear function to the data below the D-region.The new GNSS-RO observations reveal many interesting features in the diurnal, seasonal, solar-cycle, and magnetic-field-dependent variations in the Ne morphology. While the D/E-region Ne is a function of solar zenith angle (c), it exhibits strong latitudinal variations for the same c with a distribution asymmetric about noon. In addition, large longitudinal variations are observed along the same magnetic field pitch angle. The summer-midlatitude Ne and sporadic-E(Es) show a distribution similar to each other. The distribution of auroral electron precipitation correlates better with the pitch angle from the magnetosphere than from one at100 km. Finally, anew TEC retrieval technique is developed for the high-rate RO data with a top reaching at least 120 km. For better characterization of the E-to-F transition in Ne and more accurate TEC retrievals, it is recommended to have all GNSS-RO acquisition routinely up to 220 km.

GNSS radio occultation↗
NASA NTRS2017

New Global Electron Density Observations from GPS-RO in the D- and E-Region Ionosphere

A novel retrieval technique is developed for electron density (N(sub e)) in the D- and E-region (80-120 km) using the high-quality 50-Hz GPS radio occultation (GPS-RO) phase measurements. The new algorithm assumes a slow, linear variation in the F-region background when the GPS-RO passes through the D- and E-region, and extracts the N(sub e) profiles at 80-130 km from the phase advance signal caused by N(sub e). Unlike the conventional Abel function, the new approach produces a sharp N(sub e) weighting function in the lower ionosphere, and the N(sub e) retrievals are in good agreement with the IRI (International Reference Ionosphere) model in terms of monthly maps, zonal means and diurnal variations. The daytime GPS-RO N(sub e) profiles can be well characterized by the alpha-Chapman function of three parameters (N(sub mE), h(sub mE) and H), showing that the bottom of E-region is deepening and sharpening towards the summer pole. At high latitudes the monthly GPS-RO N(sub e) maps at 80-120 km reveal clear enhancement in the auroral zones, more prominent at night, as a result of energetic electron precipitation (EEP) from the outer radiation belt. The D-/E-region auroral N(sub e) is strongly correlated with K(sub p) on a daily basis. The new N(sub e) data allow further comprehensive analyses of the sporadic E (E(sub s)) phenomena in connection with the background N(sub e) in the E-region. The layered (2-10 km) and fluctuated (less than 2 km) E(sub s) components, namely N(sub e_Layer) than N(sub e_Pert), are extracted with respect to the background N( sub e_Region) on a profile-by-profile basis. The N(sub e_Layer) component has a strong but highly-refined peak at approximately 105 km, with an amplitude smaller than N(sub e_Region) approximately by an order of magnitude. The N(sub e_Pert) component, which was studied extensively in the past, is approximately 2 orders of magnitude weaker than N(sub e_Layer). Both N(sub e_Layer) and N(sub e_Pert) are subject to significant diurnal and semidiurnal variations, showing downward progression with local time in amplitude. The 11-year solar cycle dominates the N(sub e) interannual variations, showing larger N(sub e_Region) and N(sub e_Layer) but smaller N(sub e_Pert) amplitudes in the solar maximum years. Enhanced Ne profiles are often observed in the polar winter, showing good correlation with solar proton events (SPEs) and geomagnetic activity. The new methodology offers great potential for retrieving low N(sub e) in the D-region, where radio propagation and communication blackouts can occur due to enhanced ionization. For space weather applications it is recommended for GPSRO operations to raise the top of high-rate data acquisition to approximately 140 km in the future.

GSP-R↗
NASA NTRS2020

Ionospheric S4 Scintillations From GNSS Radio Occultation (RO) at Slant Path

Ionospheric scintillation can significantly degrade the performance and the usability of space‐based communication and navigation signals. Characterization and prediction of ionospheric scintillation can be made from the Global Navigation Satellite System (GNSS) radio occultation (RO) technique using the measurement from a deep slant path where the RO tangent height (ht) is far below the ionospheric sources. In this study, the L–band S4 from the RO measurements at ht = 30 km is used to infer the amplitude scintillation on the ground. The analysis of global RO data at ht = 30 km shows that sporadic–E (Es), equatorial plasma bubbles (EPBs), and equatorial spread–F (ESF) produce most of the significant S4 enhancements, although the polar S4 is generally weak. The enhanced S4 is a strong function of local time and magnetic dip angle. The Es–induced daytime S4 tends to have a negative correlation with the solar cycle at low latitudes but a positive correlation at high latitudes. The nighttime S4 is dominated by a strong semiannual variation at low latitudes.

GPS radio occultation↗
NASA NTRS1973

Evaluation of RO modules for the SSP ETC/LSS.

During the past eight years the NASA Manned Spacecraft Center has supported the development of an Integrated Water and Waste Management System for use in the Space Station Prototype (SSP) Environmental Thermal Control/Life-Support System (ETC/LSS). This system includes the reverse osmosis (RO) process for recycling wash water and the compression distillation process for recovering useable water from urine, urinal flush water, humidity condensate, commode flush water and the wash water concentrated by RO. This paper summarizes the experimental work performed during the past four years to select the best commercially available RO module for this system and to also define which surfactants and germicides are most compatible with the selected module.

Jasionowski, W. J.↗
NASA NTRS2021

PBL Height from AIRS, GPS RO, and MERRA-2 Products in NASA GES DISC and Their 10 Year Seasonal Mean Intercomparison

Within the planetary boundary layer (PBL), surface forcing response, drag, turbulence, and vertical mixing are important processes and play a more critical role here than in the overlying “free atmosphere”. The PBL Height (PBLH) is an important parameter in climate models, weather forecasts, and air quality prediction. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) provides data processing, archiving, and distribution services for numerous Earth science products. PBLH is a parameter in three products served by GES DISC, which are from the Atmospheric Infrared Sounder (AIRS), the Global Positioning System (GPS) radio occultation (RO) experiment, and the NASA reanalysis product Modern-Era Retrospective analysis for Research and Applications – 2 (MERRA-2). These products have different spatial and temporal resolutions and coverages, and their PBLH definitions are also different. To better serve the PBL research community, we have summarized the specifications of these products. A ten-year seasonal mean intercomparison is also conducted to provide further guidance to users. The intercomparison results show that MERRA-2 has a much shallower PBL than AIRS and GPS RO. An experimental study indicates the different PBLH definition in MERRA-2 caused smaller values of PBLH. The improvement of the water vapor retrieval in AIRS version 7 over version 6 results in the version 7 PBLH agreeing better with GPS RO and MERRA-2 than version 6, especially near the equator and low latitudes.

Feng Ding↗
DOE OSTI2025

Electrocoagulation Combined with Ultrafiltration Membranes as Pretreatment for RO Desalination of Synthetic Cooling Tower Blowdown Water

Electrocoagulation (EC), an electrochemical water treatment process, is commonly used to remove particulate and colloidal matter from water. Here, in this study, we demonstrate that EC, when coupled with membrane filtration, is also capable of removing dissolved species, such as Ca + , Mg 2+ , and SiO x . The removal of such species is important for downstream membrane-based desalination treatment of the water that can suffer from reduced performance due to membrane scaling. Here, we describe how EC can be combined with a low-pressure membrane (LPM) system to offer efficient (and potentially universal) pretreatment for downstream membrane desalination. Synthetic water, simulating cooling tower blowdown (CTBD) with elevated concentrations of hardness and silicates (Ca: 418 ppm, Mg: 63 ppm, SiO 2 : 50 ppm) is treated using EC coupled to ultrafiltration (UF) to remove Mg up to 30 ± 1%, Ca up to 29 ± 1%, and silica up to 99 ± 1%. We evaluated the effectiveness of the EC-UF pretreatment system in reducing downstream RO scaling using thermodynamic modeling to predict the saturation index (SI) at the RO membrane/water interface. An SI value below zero (SI < 0) indicates under-saturated conditions (with respect to a particular mineral) where mineral scaling does not take place, which correlates with improved water recovery. Our findings suggest that the EC-UF pretreatment system was able to increase water recovery by up to 30%, compared to 0% recovery without pretreatment, under optimal conditions (feed solution pH of 7 and an EC charge loading of 1800 C/L). Finally, we conducted an economic analysis showing that implementing an EC-UF system for CTBD water could yield a cost benefit of up to $\$$14.13 per m 3 compared to direct brine disposal.

cooling tower blowdown↗
NASA NTRS1988

The determination of absolute ro-vibrational intensities for radical diatomic molecules

Ro-vibrational transition intensities of radical and/or chemically reactive molecular species are difficult to determine. A number of methods which might be used to provide information on matrix elements of the electric dipole moment function and the construction of the dipole moment function from the information these methods provide are discussed. The derived dipole moment function represents an optimum choice and allows a calculation (with estimable errors) of the line intensities for a large number of ro-vibrational transitions.

Chackerian, C., Jr.↗
NASA NTRS2005

Removal of organic contaminants by RO and NF membranes

Rejection characteristics of organic and inorganic compounds were examined for six reverse osmosis (RO) membranes and two nanofiltration (NF) membranes that are commercially available. A batch stirred-cell was employed to determine the membrane flux and the solute rejection for solutions at various concentrations and different pH conditions. The results show that for ionic solutes the degree of separation is influenced mainly by electrostatic exclusion, while for organic solutes the removal depends mainly upon the solute radius and molecular structure. In order to provide a better understanding of rejection mechanisms for the RO and NF membranes, the ratio of solute radius (r(i,s)) to effective membrane pore radius (r(p)) was employed to compare rejections. An empirical relation for the dependence of the rejection of organic compounds on the ratio r(i,s)/r(p) is presented. The rejection for organic compounds is over 75% when r(i,s)/r(p) is greater than 0.8. In addition, the rejection of organic compounds is examined using the extended Nernst-Planck equation coupled with a steric hindrance model. The transport of organic solutes is controlled mainly by diffusion for the compounds that have a high r(i,s)/r(p) ratio, while convection is dominant for compounds that have a small r(i,s)/r(p) ratio. c2005 Elsevier B.V. All rights reserved.

NASA Discipline Life Sciences Technologies↗
DOE OSTI2025

Techno-economic assessment of distributed wellhead RO water treatment for nitrate removal and salinity reduction: A field study in small disadvantaged communities

Techno-economic analysis of distributed wellhead water treatment and desalination (DWTD) systems was carried out based on a three-year field study in three small, disadvantaged communities (DACs) to evaluate the reliability and affordability of upgrading their impaired well water. The local water supplies of the three study DACs, located in Salinas Valley, California, were contaminated with nitrate at levels (~ 12–87 mg/L NO$^{-}_{3}$ - N) ) above the California maximum contaminant level (MCL) of 10 mg/L NO$^{-}_{3}$ - N , and had elevated water salinity (~600–1,600 mg/L total dissolved solids(TDS)) above its secondary MCL (SMCL) of 500 mg/L TDS. Well water nitrate removal and salinity reduction were accomplished via reverse osmosis (RO) based DWTD systems that operated autonomously, supported by remote monitoring and supervisory cyberinfrastructure. Reliable DWTD operation provided treated water quality, with respect to nitrate and salinity, in the range of 0.5–6.3 mg/L NO$^{-}_{3}$ - N and 57–161 mg/L TDS, respectively, which were well below the respective MCL and SMCL. The levelized cost of water treatment was in the range of ~$$2/m 3 - $$2.9/m 3 which aligns with typical residential water costs in California and in the study region, and monthly residential water costs (39 dollars-74 dollars/residential unit/month) were also within the range in California. The study showcased the DWTD approach as a viable and potentially scalable solution for upgrading impaired local potable water supply of communities lacking centralized water delivery infrastructure. However, streamlined permitting processes and standardized regulatory frameworks are critical to promoting wider adoption and maximizing the socio-economic benefits of the DWT approach. Moreover, DACs are likely to require government subsidies in order to cover the CapEx of DWTD systems in addition to upgrade of site infrastructure.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
NASA NTRS1995

A FFT Method for the Quasiclassical Selection of Initial Ro-Vibrational States of Triatomic Molecules

This paper describes the use of an exact fast Fourier transform (FFT) method to prepare specified vibrational-rotational states of triatomic molecules. The method determines the Fourier coefficients needed to describe the coordinates and momenta of a vibrating-rotating triatomic molecule. Once the Fourier coefficients of a particular state are determined, it is possible to easily generate as many random sets of initial cartesian coordinates and momenta as desired. All the members of each set will correspond to the particular vibrational-rotational state selected. For example, in the case of the ground vibrational state of a non-rotating water molecule, the calculated actions of 100 sets of initial conditions produced actions within 0.001 h(bar) of the specified quantization values and energies within 5 cm(sup -1) of the semiclassical eigenvalue. The numerical procedure is straightforward for states in which all the fundamental frequencies are independent. However for states for which the fundamental frequencies become commensurate (resonance states), there are additional complications. In these cases it is necessary to determine a new set of "fundamental" frequencies and to modify the quantization conditions. Once these adjustments are made, good results are obtained for resonance states. The major problems are in labelling the large number of Fourier coefficients and the presence of regions of chaotic motion. Results are presented for the vibrational states of H2O and HCN and the ro-vibrational states of H2O.

Eaker, Charles W.↗
NASA NTRS1995

Variational Calculations of Ro-Vibrational Energy Levels and Transition Intensities for Tetratomic Molecules

A description is given of an algorithm for computing ro-vibrational energy levels for tetratomic molecules. The expressions required for evaluating transition intensities are also given. The variational principle is used to determine the energy levels and the kinetic energy operator is simple and evaluated exactly. The computational procedure is split up into the determination of one dimensional radial basis functions, the computation of a contracted rotational-bending basis, followed by a final variational step coupling all degrees of freedom. An angular basis is proposed whereby the rotational-bending contraction takes place in three steps. Angular matrix elements of the potential are evaluated by expansion in terms of a suitable basis and the angular integrals are given in a factorized form which simplifies their evaluation. The basis functions in the final variational step have the full permutation symmetries of the identical particles. Sample results are given for HCCH and BH3.

Schwenke, David W.↗
NASA NTRS2004

Quantum Scattering Study of Ro-Vibrational Excitations in N+N(sub 2) Collisions under Re-entry Conditions

A three-dimensional time-dependent quantum dynamics approach using a recently developed ab initio potential energy surface is applied to study ro-vibrational excitation in N+N2 exchange scattering for collision energies in the range 2.1- 3.2 eV. State-to-state integral exchange cross sections are examined to determine the distribution of excited rotational states of N(sub 2). The results demonstrate that highly-excited rotational states are produced by exchange scattering and furthermore, that the maximum value of (Delta)j increases rapidly with increasing collision energies. Integral exchange cross sections and exchange rate constants for excitation to the lower (upsilon = 0-3) vibrational energy levels are presented as a function of the collision energy. Excited-vibrational-state distributions for temperatures at 2,000 K and 10,000 K are included.

Wang, Dunyou↗
DOE OSTI2024

Machine learning models of intermittent operation of RO wellhead water treatment for salinity reduction and nitrate removal

Machine learning models were developed for intermittent multi-mode operation of a wellhead reverse osmosis water purification and desalination system to predict salt passage, nitrate passage, and permeate flux. The models, based on long short-term memory (LSTM) recurrent neural network (RNN) architecture, included an attention mechanism to increase model performance in proximity of the regulatory limit for nitrate. Training and testing of the models for the Startup, Production, Shutdown and Flushing operational modes were based on operational data (consisting of 22 process variables per data sample) acquired every 2–5 s over a six-month period. The significant sets of model input attributes for the different operational modes were assessed via Spearman ranking correlation, Self-Organizing Map (SOM) analysis and feed forward feature selection (FFFS). Although the variability of nitrate passage, salt passage and permeate flux was significant over the four operational modes, prediction performance for the three outcomes were with R2 and Average Absolute Relative Error (AARE) of 0.78–0.95 and 2.96–6.16 %, respectively. Model updates post membrane elements replacement demonstrated similar levels of prediction accuracy. The study results suggest that there is merit in exploring the utility of multi-mode models for sensor fault detection, data imputation, and for potential use in model-predictive control.

Intermittent RO operation↗