Materials Data on RbAuO2 by Materials Project
RbAuO2 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Rb1+ is bonded in a 6-coordinate geometry to six equivalent O2- atoms. There are two shorter (2.85 Å) and four longer (3.07 Å) Rb–O bond lengths. Au3+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Au–O bond lengths are 2.04 Å. O2- is bonded to three equivalent Rb1+ and two equivalent Au3+ atoms to form a mixture of distorted corner, edge, and face-sharing ORb3Au2 trigonal bipyramids.
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