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Nodal fermions in the strongly spin-orbit coupled pyrochlore-lattice compound RbBi2

We explore the topological electronic band structure of the pyrochlore lattice in the strong spin-orbit coupling regime. Using angle-resolved photoemission spectroscopy, first-principles calculations, and symmetry analysis, we have investigated the bulk electronic structure of RbBi2, which has a Bi pyrochlore network. We observe the presence of 3D massless Dirac fermions enforced by nonsymmorphic symmetry, as well as a 3D quadratic band crossing protected by cubic crystalline symmetry. Furthermore, we identify an additional 3D linear Dirac dispersion associated with band inversion protected by threefold rotation symmetry. These observations reveal the rich band topology of itinerant pyrochlore lattice systems in the strong SOC limit and serve as a starting point to explore correlated topological phases in geometrically frustrated lattices.

Oh, Dongjin↗

Materials Data on RbBi2 by Materials Project

Bi2Rb is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Rb is bonded in a 12-coordinate geometry to twelve equivalent Bi atoms. All Rb–Bi bond lengths are 4.03 Å. Bi is bonded to six equivalent Rb and six equivalent Bi atoms to form a mixture of corner, edge, and face-sharing BiRb6Bi6 cuboctahedra. All Bi–Bi bond lengths are 3.43 Å.

36 MATERIALS SCIENCE↗