Materials Data on RbNO2 by Materials Project
RbNO2 crystallizes in the trigonal P3_121 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.98–3.36 Å. N3+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.27 Å. O2- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one N3+ atom.
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