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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Enhanced Groundwater Recharge Rates and Altered Recharge Sensitivity to Climate Variability Through Subsurface Heterogeneity

Our environment is heterogeneous. In hydrological sciences, the heterogeneity of subsurface properties, such as hydraulic conductivities or porosities, exerts an important control on water balance. This notably includes groundwater recharge, which is an important variable for efficient and sustainable groundwater resources management. Current large-scale hydrological models do not adequately consider this subsurface heterogeneity. Here we show that regions with strong subsurface heterogeneity have enhanced present and future recharge rates due to a different sensitivity of recharge to climate variability compared with regions with homogeneous subsurface properties. Our study domain comprises the carbonate rock regions of Europe, Northern Africa, and the Middle East, which cover 25 of the total land area. We compare the simulations of two large-scale hydrological models, one of them accounting for subsurface heterogeneity. Carbonate rock regions strongly exhibit karstification, which is known to produce particularly strong subsurface heterogeneity. Aquifers from these regions contribute up to half of the drinking water supply for some European countries. Our results suggest that water management for these regions cannot rely on most of the presently available projections of groundwater recharge because spatially variable storages and spatial concentration of recharge result in actual recharge rates that are up to four times larger for present conditions and changes up to five times larger for potential future conditions than previously estimated. These differences in recharge rates for strongly heterogeneous regions suggest a need for groundwater management strategies that are adapted to the fast transit of water from the surface to the aquifers.

water resources↗

Western Tennessee Water Resources: Leveraging High Resolution Remotely Sensed Data to Assess Water Availability and Vulnerability in the Memphis Aquifer Area in West Tennessee

The Memphis Aquifer (MA) is located in the Mississippi Embayment that extends 250,000 square kilometers across eight states. Fayette and Haywood counties in West Tennessee are situated within the recharge zone of the MA and include the forthcoming Ford “mega campus” named Blue Oval City (BOC), which will consist of a vehicle-production facility and battery assembly division. Increased water demand and land cover change resulting from urban development, such as BOC in the MA’s narrow recharge zone, threaten the aquifer’s groundwater storage and recharge rate. Groundwater recharge factors that influence the narrow recharge zone of the MA include precipitation, evapotranspiration, runoff, and land cover type. In partnership with Protect Our Aquifer (POA) and the Center for Applied Earth Science and Engineering Research (CAESAR) at the University of Memphis, the team used data from the ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS), Integrated Multi-Satellite Retrievals for Global Precipitation Measurement (GPM IMERG), and Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS). The team also used ancillary data from the National Land Cover Database (NLCD) and the North American Land Data Assimilation System (NLDAS) Noah Land Surface Model. These results identified “thriving” recharge locations, which are areas most conducive to aquifer recharge in Fayette County. The partners may use the results to prioritize specific areas in need of protection before they become susceptible to the effects of urbanization and industrialization.

precipitation↗

Photocured Gelled Electrolytes For Secondary Li Cells

Class of photocured polymers exhibiting lithium-ion conductivities greater than those of well-studied polymers based on polyethylene oxide (PEO) show promise as polymeric electrolytes in rechargeable lithium cells. Increase in conductivity occasioned by use of electrolytes, coupled with amenability of electrolytes to formation into uniform thin (less than 25 micrometers thick), wide films, expected to result in cells with power densities greater than 100 W h/kg and charge/discharge rates exceeding currents equal, in amperes, to ampere-hour ratings. All-solid-state lithium batteries containing these electrolytes used as high-power, high-rate rechargeable power sources in commercial and aerospace applications.

Nagasubramanian, Ganesan↗

Accelerated testing for synchronous orbits

Degradation of batteries during synchronous orbits is analyzed. Discharge and recharge rates are evaluated. The functional relationship between charge rate and degradation is mathematically determined.

Mcdermott, P.↗

Lithium Iron Phosphate Cell Performance Evaluations for Lunar Extravehicular Activities

Lithium-ion battery cells are being evaluated for their ability to provide primary power and energy storage for NASA s future Exploration missions. These missions include the Orion Crew Exploration Vehicle, the Ares Crew Launch Vehicle Upper Stage, Extravehicular Activities (EVA, the advanced space suit), the Lunar Surface Ascent Module (LSAM), and the Lunar Precursor and Robotic Program (LPRP), among others. Each of these missions will have different battery requirements. Some missions may require high specific energy and high energy density, while others may require high specific power, wide operating temperature ranges, or a combination of several of these attributes. EVA is one type of mission that presents particular challenges for today s existing power sources. The Portable Life Support System (PLSS) for the advanced Lunar surface suit will be carried on an astronaut s back during eight hour long sorties, requiring a lightweight power source. Lunar sorties are also expected to occur during varying environmental conditions, requiring a power source that can operate over a wide range of temperatures. Concepts for Lunar EVAs include a primary power source for the PLSS that can recharge rapidly. A power source that can charge quickly could enable a lighter weight system that can be recharged while an astronaut is taking a short break. Preliminary results of Al23 Ml 26650 lithium iron phosphate cell performance evaluations for an advanced Lunar surface space suit application are discussed in this paper. These cells exhibit excellent recharge rate capability, however, their specific energy and energy density is lower than typical lithium-ion cell chemistries. The cells were evaluated for their ability to provide primary power in a lightweight battery system while operating at multiple temperatures.

Reid, Concha↗

Comparing Potential Recharge Estimates From Three Land Surface Models Across the Western US

Groundwater is a major source of water in the western US. However, there are limited recharge estimates available in this region due to the complexity of recharge processes and the challenge of direct observations. Land surface Models (LSMs) could be a valuable tool for estimating current recharge and projecting changes due to future climate change. In this study, simulations of three LSMs (Noah, Mosaic and VIC) obtained from the North American Land Data Assimilation System (NLDAS-2) are used to estimate potential recharge in the western US Modeled recharge was compared with published recharge estimates for several aquifers in the region. Annual recharge to precipitation ratios across the study basins varied from 0.01-15% for Mosaic, 3.2-42% for Noah, and 6.7-31.8% for VIC simulations. Mosaic consistently underestimates recharge across all basins. Noah captures recharge reasonably well in wetter basins, but overestimates it in drier basins. VIC slightly overestimates recharge in drier basins and slightly underestimates it for wetter basins. While the average annual recharge values vary among the models, the models were consistent in identifying high and low recharge areas in the region. Models agree in seasonality of recharge occurring dominantly during the spring across the region. Overall, our results highlight that LSMs have the potential to capture the spatial and temporal patterns as well as seasonality of recharge at large scales. Therefore, LSMs (specifically VIC and Noah) can be used as a tool for estimating future recharge rates in data limited regions.

groundwater↗

Sustainable Use of Groundwater May Dramatically Reduce Irrigated Production of Maize, Soybean, and Wheat

Groundwater extraction in the United States (US) is unsustainable, making it essential to understand the impacts of limited water use on irrigated agriculture. To improve this understanding, we integrated a gridded crop model with satellite observations, recharge estimates, and water survey data to assess the effects of sustainable groundwater withdrawals on US irrigated agricultural production. The gridded crop model agrees with satellite-based estimates of evapotranspiration (R2 = 0.68), as well as survey data from the United States Department of Agriculture (R2 = 0.82–0.94 for county-level production and 0.37–0.54 for county-level yield). Using the optimistic assumption that groundwater extraction equals effective aquifer recharge rate, we find that sustainable groundwater use decreases US irrigated production of maize, soybean, and winter wheat by 20%, 6%, and 25%, respectively. Using a more conservative assumption of groundwater availability, US irrigated production of maize, soybean, and winter wheat decreases by 45%, 37%, and 36%, respectively. The wide range of simulated losses is driven by considerable uncertainty in surface water and groundwater interactions, as well as accounting for the many aspects of sustainability. Our results demonstrate the vulnerability of US irrigated agriculture to unsustainable groundwater pumping, highlighting the difficulty of expanding or even maintaining irrigated food production in the face of climate change, population growth, and shifting dietary demands. These findings are based on reducing pumping by fallowing irrigated farmland; however, alternate pumping reduction strategies or technological advances in crop genetics and irrigation could produce different results.

sustainability↗

Analysis of voltage data

The use of statistical analysis (regression analysis) to determine the data correlation between eight voltage parameters is discussed. The eight parameters correlated include: temperature, depth of discharge; charge rate; discharge rate; percent recharge; concentration of KOH; amount of KOH; and precharge. Graphs are presented which show: (1) starpoint/centerpoint cycles to failure vs. parameters; (2) cycles to failure vs. temperature; and (3) positive and negative plate thickness and weight vs. cycles. An empirical equation derived from cycles to failure vs. temperature graph for cells cycled at 1C charge, 2C discharge, and 14 percent recharge is also presented.

Mcdermott, P. P.↗

Lunar Equator Regenerative Fuel Cell System Efficiency Analysis

It is expected that future NASA mission energy storage requirements can be adequately met by regenerative fuel cells (RFCs). Aerospace RFCs are likely to package proton exchange membrane electrochemical conversion devices based on hydrogen, oxygen, and water. To optimize system designs and direct further development, the most useful system metric is round-trip efficiency (RTE). Improving RTE generally increases specific energy and reduces system mass. The following analysis models the impact of several factors on RTE for RFCs scaling from 0.1 to 50 kW. The analysis demonstrates that higher electrolyzer (EZ) operational pressure most negatively impacts both RFC RTE and specific energy. Reactant storage heating and power management losses are significant for RFCs of any scale, but solenoid valve power becomes a noticeable parasitic load for smaller RFCs. Spherical gas storage vessels benefit RTE by only 2 to 4 percentage points but increase specific energy by ~50 percent. Cryogenic reactant storage is shown to depress RTE to below 15 percent in all cases. For a given RFC scale, there is an RTE benefit to specifying larger EZs and recharging at higher rates—if the RFC can be coupled with a corresponding power source. Although fuel cell (FC) operation is less impactful on RTE than EZ factors, efficiency is maximized by sizing the FCs relatively large and keeping current density low. RFC design is a balance of many interrelated factors, but this analysis provides a starting point for difficult decisions that must be made when designing a lunar equator RFC.

regenerative fuel cell↗

Lunar South Pole Regenerative Fuel Cell System Efficiency Analysis

It is expected that future NASA mission energy storage needs can be adequately met by regenerative fuel cells (RFCs). Aerospace RFCs package proton exchange membrane (PEM) electrochemical conversion devices based on hydrogen, oxygen, and water. To optimize system designs and direct further development, the most useful system metric is round-trip efficiency (RTE). Improving RTE generally increases specific energy and reduces system mass. The following analysis models the impact of several factors on RTE for RFCs at the lunar south pole scaling from 0.1 kW to 50 kW. The analysis demonstrates that higher electrolyzer operational pressure most negatively impacts both RFC RTE and specific energy. Optimal electrolyzer membrane thickness is evaluated as a function of operational current density and pressure. Reactant storage heating and power management losses are significant for RFCs of any scale but are reduced in impact at the south pole compared to colder equator applications. Solenoid valve power remains a noticeable parasitic load for smaller RFCs. Larger electrolyzers enable higher peak theoretical efficiencies when recharging at higher rates, if the RFC can be coupled with a corresponding higher power source. RFC design is a compromise of many interrelated factors, but this analysis provides a starting point for difficult decisions that must be made when designing a lunar south pole RFC.

regenerative fuel cell↗

Characteristics of storage related capacity loss in Ni/H2 cells

The changes in the capacity, voltage and pressure profile of flight configuration Ni/H2 cells when they are stored for extended periods is examined. The Ni/H2 cells exhibit capacity fade phenomenon regardless of their design when they are stored at room temperature. Capacity loss also occurs if old cells (5 years old) are stored in a very low rate trickle charge (C/200 rate) condition. A periodic recharge technique leads to pressure rise in the cells. Conventional trickle charge (C/100 rate) helps in minimizing or eliminating the second plateau which is one of the characteristics of the capacity fade phenomenon.

Vaidyanathan, Hari↗

Phyllosilicate and Hydrated Sulfate Deposits in Meridiani

Several phyllosilicate and hydrated sulfate deposits in Meridiani have been mapped in detail with high resolution MRO CRISM [1] data. Previous studies have documented extensive exposures of outcrop in Meridiani (fig 1), or etched terrain (ET), that has been interpreted to be sedimentary in origin [e.g., 2,3]. These deposits have been mapped at a regional scale with OMEGA data and show enhanced hydration (1.9 m absorption) in several areas [4]. However, hydrated sulfate detections were restricted to valley exposures in northern Meridiani ET [5]. New high resolution CRISM images show that hydrated sulfates are present in several spatially isolated exposures throughout the ET (fig 1). The hydrated sulfate deposits in the valley are vertically heterogeneous with layers of mono and polyhydrated sulfates and are morphologically distinct from other areas of the ET. We are currently mapping the detailed spatial distribution of sulfates and searching for distinct geochemical horizons that may be traced back to differential ground water recharge and/or evaporative loss rates. The high resolution CRISM data has allowed us to map out several phyllosilicate deposits within the fluvially dissected Noachian cratered terrain (DCT) to the south and west of the hematite-bearing plains (Ph) and ET (fig 1). In Miyamoto crater, phyllosilicates are located within ~30km of the edge of Ph, which is presumably underlain by acid sulfate deposits similar to those explored by Opportunity. The deposits within this crater may record the transition from fluvial conditions which produced and/or preserved phyllosilicates deposits to a progressively acid sulfate dominated groundwater system in which large accumulations of sulfate-rich evaporites were deposited .

Wiseman, S. M.↗

NiH2 Battery Reconditioning for LEO Applications

This paper summarizes reasons for and benefits of reconditioning nickel-hydrogen (NiH2) batteries used for Low Earth Orbit (LEO) applications. NiH2 battery cells do not have the classic discharge voltage problems more commonly associated with nickel-cadmium (NiCd) cells. This is due, in part, to use of hydrogen electrodes in place of cadmium electrodes. The nickel electrode, however, does have a similar discharge voltage signature for both cell designs. This can have an impact on LEO applications where peak loads at higher relative depths of discharge can impact operations. Periodic reconditioning provides information which can be used for analyzing long term performance trends to predict usable capacity to a specified voltage level. The reconditioning process described herein involves discharging NiH2 batteries at C/20 rates or less, to an average cell voltage of 1.0 volts or less. Recharge is performed at nominal C/5 rates to specified voltage/temperature (V/T) charge levels selected to restore required capacity with minimal overcharge. Reconditioning is a process of restoring reserve capacity lost on cycling, which is commonly called the memory effect in NiCd cells. This effect is characterized by decreases in the discharge voltage curve with operational life and cycling. The end effect of reconditioning NiH2 cells may be hidden in the versatility, of that design over the NiCd cell design and its associated negative electrode fading problem. The process of deep discharge at lower rates by way of reconditioning tends to redistribute electrolyte and water in the NiH2 cell electrode stack, while improving utilization and charge efficiency. NiH2 battery reconditioning effects on life are considered beneficial and may, in fact. extend life based on NiCd experience. In any case, usable capacity data obtained from reconditioning is required for performance evaluation and trend analysis. Characterization and life tests have provided the historical data base used to determine the need for reconditioning in most battery applications. The following sections briefly describe the background of NiH2 battery reconditioning and testing at Lockheed Martin Missiles & Space (LMMS) and other aerospace companies.

Armantrout, J. D.↗

The Viking gas exchange experiment results from Chryse and Utopia surface samples

Immediate gas changes occurred when untreated Martian surface samples were humidified and/or wet by an aqueous nutrient medium in the Viking lander gas exchange experiment. The evolutions of N2, CO2, and Ar are mainly associated with soil surface desorption caused by water vapor, while O2 evolution is primarily associated with decomposition of superoxides inferred to be present on Mars. On recharges with fresh nutrient and test gas, only CO2 was given off, and its rate of evolution decreased with each recharge. This CO2 evolution is thought to come from the oxidation of organics present in the nutrient by gamma Fe2O3 in the surface samples. Atmospheric analyses were also performed at both sites. The mean atmospheric composition from four analyses is N2, 2.3%; O2, not greater than 0.15%; Ar, 1.5% and CO2, 96.2%.

Oyama, V. I.↗

Leveraging High Resolution Remotely Sensed Evapotranspiration Data to Assess Water Availability and Vulnerability in the Memphis Aquifer Area in West Tennessee

The Memphis aquifer is an indispensable source of water for municipal, agricultural, and industrial use across west Tennessee. The aquifer's water is thousands of years old and in pristine condition due to the natural geological filtering by the aquifer’s confining clay layers. To sustain the aquifer’s water supply, recharge must happen at a rate efficient enough to keep up with pumping from the aquifer. In partnership with Protect Our Aquifer and the University of Memphis Center for Applied Earth Science and Engineering Research, this project examined multiple factors to discover thriving areas of recharge in west Tennessee. The team used Integrated Multi-satellite Retrievals for GPM (IMERG) precipitation data, ECOsystem Spaceborne Thermal Radiometer on Space Station (ECOSTRESS) evapotranspiration data, Landsat 8 and National Land Cover Database (NLCD) to track landcover change, and the North American Land Data Assimilation System (NLDAS) Noah land surface model to estimate monthly runoff. These factors were averaged seasonally from 2019 to 2022 to understand seasonal relationships within the study area. Precipitation and evapotranspiration data were used to create water balance maps and with the evaporative stress index (ESI), landcover, and runoff maps, the team pinpointed locations that are most conducive to recharge. The team determined that areas where the water balance is low, ESI is high, and where there is sufficient pervious landcover are locations where recharge happens most effectively. Identification of effective recharge locations may be used by the partners to prioritize areas in need of protection before they become impacted by industrialization and urbanization.

Lauren Webster↗

Rechargeable nickel-zinc batteries

Device proves superiority in having two and one half to three times the energy content of popular lead-zinc or nickel-cadmium batteries. Application to electric utility vehicles improved acceleration rate and nearly doubled driving range between rechargings. Unit contributes substantially toward realization of practical urban electrical automobiles.

Soltis, D. G.↗

NWSC nickel cadmium spacecraft cell accelerated life test program data analysis

An analysis of the data leading to a proposed accelerated life test scheme to test a nickel cadmium cell under spacecraft usage conditions is described. The amount and concentration of electrolyte and the amount of precharge in the cell are discussed in relation to the design of the cell and the accelerated test design. A failure analysis of the cell is summarized. The analysis included such environmental test variables as the depth of discharge, the temperature, the amount of recharge and the charge and discharge rate.

Lander, J.↗