Materials Data on TiSiRh by Materials Project
TiRhSi crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ti is bonded in a 11-coordinate geometry to six equivalent Rh and five equivalent Si atoms. There are a spread of Ti–Rh bond distances ranging from 2.89–2.94 Å. There are three shorter (2.69 Å) and two longer (2.72 Å) Ti–Si bond lengths. Rh is bonded in a 4-coordinate geometry to six equivalent Ti and four equivalent Si atoms. There are a spread of Rh–Si bond distances ranging from 2.39–2.45 Å. Si is bonded in a 9-coordinate geometry to five equivalent Ti and four equivalent Rh atoms.
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