Materials Data on S2N3ClO6 by Materials Project
N2NCl(SO3)2 crystallizes in the orthorhombic Pbam space group. The structure is one-dimensional and consists of eight ammonia molecules; eight sulfur trioxide molecules; and four NCl ribbons oriented in the (1, 0, 0) direction. In each NCl ribbon, N3+ is bonded in a linear geometry to two equivalent Cl1- atoms. Both N–Cl bond lengths are 2.42 Å. Cl1- is bonded in a linear geometry to two equivalent N3+ atoms.
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