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AC Read-Out Circuits for Single Pixel Characterization of TES Microcalorimeters and Bolometers

SRON is developing Frequency Domain Multiplexing (FDM) for the read-out of transition edge sensor (TES) soft x-ray microcalorimeters for the XMS instrument of the International X-ray Observatory and far-infrared bolometers for the SAFARI instrument on the Japanese mission SPICA. In FDM the TESs are AC voltage biased at frequencies from 0.5 to 6 MHz in a superconducting LC resonant circuit and the signal is read-out by low noise and high dynamic range SQUIDs amplifiers. The TES works as an amplitude modulator. We report on several AC bias experiments performed on different detectors. In particular, we discuss the results on the characterization of Goddard Space Flight Center x-ray pixels and SRON bolometers. The paper focuses on the analysis of different read-out configurations developed to optimize the noise and the impedance matching between the detectors and the SQUID amplifier. A novel feedback network electronics has been developed to keep the SQUID in flux locked loop, when coupled to superconducting high Q circuits, and to optimally tune the resonant bias circuit. The achieved detector performances are discussed in view of the instrument requirement for the two space missions.

Gottardi, L.↗

Comparing Transition-Edge Sensor Response Times in a Modified Contact Scheme with Different Support Beams

We present measurements of the thermal conductance, G, and effective time constants, tau, of three transition-edge sensors (TESs) populated in arrays operated from 80-87mK with T(sub C) approximately 120mK. Our TES arrays include several variations of thermal architecture enabling determination of the architecture that demonstrates the minimum noise equivalent power (NEP), the lowest tau and the trade-offs among designs. The three TESs we report here have identical Mo/Cu bilayer thermistors and wiring structures, while the thermal architectures are: 1) a TES with straight support beams of 1mm length, 2) a TES with meander support beams of total length 2mm and with 2 phononfilter blocks per beam, and 3) a TES with meander support beams of total length 2mm and with 6 phonon-filter blocks per beam. Our wiring scheme aims to lower the thermistor normal state resistance R(sub N) and increase the sharpness of the transition alpha=dlogR/dlogT at the transition temperature T(sub C). We find an upper limit of given by (25+/-10), and G values of 200fW/K for 1), 15fW/K for 2), and 10fW/K for 3). The value of alpha can be improved by slightly increasing the length of our thermistors.

SAFARI instrument↗

Cloud Physics Lidar Measurements During the SAFARI-2000 Field Campaign

A new remote sensing instrument, the Cloud Physics Lidar (CPL) has been built for use on the ER-2 aircraft. The first deployment for CPL was the SAFARI-2000 field campaign during August-September 2000. The CPL is a three-wavelength lidar designed for studies of cirrus, subvisual cirrus, and boundary layer aerosols. The CPL utilizes a high repetition rate, low pulse energy laser with photon counting detectors. A brief description of the CPL instrument will be given, followed by examples of CPL data products. In particular, examples of aerosol backscatter, including boundary layer smoke and cirrus clouds will be shown. Resulting optical depth estimates derived from the aerosol measurements will be shown. Comparisons of the CPL optical depth and optical depth derived from microPulse Lidar and the AATS-14 sunphotomer will be shown.

McGill, Matthew↗

Urban and Rural Ozone Pollution Over Lusaka (Zambia, 15.5S, 25E) During SAFARI-2000 (September 2000)

In early September, throughout south central Africa, seasonal clearing of dry vegetation and the production of charcoal for cooking leads to intense smoke haze and ozone formation. Ozone soundings made over Lusaka during a six-day period in early September 2000 recorded layers of high ozone (greater than 125 ppbv at 5 km) during two stagnant periods, interspersed by a frontal passage that reduced boundary layer ozone by 30 percent. Smoke aerosol column variations aloft and total ozone were monitored by a sun photometer. During the 6-day measurement period, surface ozone concentrations ranged from 50-95 ppbv and integrated tropospheric ozone from the soundings was 39- 54 Dobson Units (note 1.3 km elevation at the launch site). High ozone concentrations above the mixed and inversion layers were advected from rural burning regions in western Zambia where SAFARI aircraft and ground-based instruments observed intense biomass fires and elevated aerosol and trace gas amounts. TOMS tropospheric ozone and smoke aerosols products show the distribution of biomass burning and associated pollution throughout southern Africa in September 2000. Animations of satellite images and trajectories confirm pollutant recirculation over south central African fires, exit of ozone from Mozambique and Tanzania to the Indian Ocean and the characteristic buildup of tropospheric ozone over the Atlantic from western African outflow.

Thompson, Anne M.↗

Lidar Observations of Tropospheric Aerosols Over Northeastern South Africa During the ARREX and SAFARI-2000 Dry Season Experiments

During the ARREX-1999 and SAFARI-2000 Dry Season experiments a micropulse lidar (523 nm) instrument was operated at the Skukuza Airport in northeastern South Africa. The Mar was collocated with a diverse array of passive radiometric equipment. For SAFARI-2000 the processed Mar data yields a daytime time-series of layer mean/derived aerosol optical properties, including extinction-to-backscatter ratios and vertical extinction cross-section profile. Combined with 523 run aerosol optical depth and spectral Angstrom exponent calculations from available CIMEL sun-photometer data and normalized broadband flux measurements the temporal evolution of the near surface aerosol layer optical properties is analyzed for climatological trends. For the densest smoke/haze events the extinction-to-backscatter ratio is found to be between 60-80/sr, and corresponding Angstrom exponent calculations near and above 1.75. The optical characteristics of an evolving smoke event from SAFARI-2000 are extensively detailed. The advecting smoke was embedded within two distinct stratified thermodynamic layers, causing the particulate mass to advect over the instrument array in an incoherent manner on the afternoon of its occurrence. Surface broadband flux forcing due to the smoke is calculated, as is the evolution in the vertical aerosol extinction profile as measured by the Han Finally, observations of persistent elevated aerosol during ARREX-1999 are presented and discussed. The lack of corroborating observations the following year makes these observation; both unique and noteworthy in the scope of regional aerosol transport over southern Africa.

Campbell, James R.↗

The Cloud Physics Lidar: Instrument Description and Initial Measurement Results

The new Cloud Physics Lidar (CPL) has been built for use on the NASA ER-2 high altitude aircraft. The purpose of the CPL is to provide multi-wavelength measurements of cirrus, subvisual cirrus, and aerosols with high temporal and spatial resolution. The CPL utilizes state-of-the-art technology with a high repetition rate, a low pulse energy laser, and photon-counting detection. The first deployment for the CPL was the SAFARI-2000 field campaign during August-September 2000. We provide here an overview of the instrument and initial data results to illustrate the measurement capability of the CPL.

McGill, Matthew↗

Radiative Properties of Smoke and Aerosol Over Land Surfaces

This talk discusses smoke and aerosol's radiative properties with particular attention to distinguishing the measurement over clear sky from clouds over land, sea, snow, etc. surfaces, using MODIS Airborne Simulator data from (Brazil, arctic sea ice and tundra and southern Africa, west Africa, and other ecosystems. This talk also discusses the surface bidirectional reflectance using Cloud Absorption Radiometer, BRDF measurements of Saudi Arabian desert, Persian Gulf, cerrado and rain forests in Brazil, sea ice, tundra, Atlantic Ocean, Great Dismal Swamp, Kuwait oil fire smoke. Recent upgrades to instrument (new TOMS UVA channels at 340 and 380 planned use in Africa (SAFARI 2000) and possibly for MEIDEX will also be discussed. This talk also plans to discuss the spectral variation of surface reflectance over land and the sensitivity of off-nadir view angles to correlation between visible near-infrared reflectance for use in remote sensing of aerosol over land.

King, Michael D.↗

A Climatology of Tropospheric CO over the Central and Southeastern United States and the Southwestern Pacific Ocean Derived from Space, Air, and Ground-based Infrared Interferometer Spectra

This final report summarizes all research activities and publications undertaken as part of NASA Atmospheric Chemistry and Modeling Analysis Program (ACMAP) Grant NAG-1-2022, 'A Climatology of Tropospheric CO over the Central and Southeastern United States and the Southwestern Pacific Ocean Derived from Space, Air, and Ground-based Infrared Interferometer Spectra'. Major project accomplishments include: (1) analysis of more than 300,000 AERI spectra from the ARM SGP site yielding a 5-year (1998-2002) timeseries of CO retrievals from the Lamont, OK AERI; (2) development of a prototype CO profile retrieval algorithm for AERI spectra; (3) validation and publication of the first CO retrievals from the Scanning High-resolution Interferometer Sounder (SHIS); and (4) development of a prototype AERI tropospheric O3 retrieval algorithm. Compilation and publication of the 5-year Lamont, OK timeseries is underway including a new collaboration with scientists at the Lawrence Berkeley National Laboratory. Public access to this data will be provided upon article submission. A comprehensive CO analysis of the archive of HIS spectra of remains as the only originally proposed activity with little progress. The greatest challenge faced in this project was motivating the University of Wisconsin Co-Investigators to deliver their archived HIS and AERIOO data along with the requisite temperature and water vapor profiles in a timely manner. Part of the supplied HIS dataset from ASHOE may be analyzed as part of a Master s Thesis under a separate project. Our success with the SAFARI 2000 SHIS CO analysis demonstrates the utility of such aircraft remote sensing data given the proper support from the instrument investigators. In addition to the PI and Co-I s, personnel involved in this CO climatology project include one Post Doctoral Fellow, one Research Scientist, two graduate students, and two undergraduate students. A total of fifteen presentations regarding research related to this project were delivered at eleven different scientific meetings. Thus far, three publications have resulted from this project with another five in preparation. No subject inventions resulted from this research project.

McMillian, W. Wallace↗

Optical and Microphysical Retrievals of Marine Stratocumulus Clouds off the Coast of Namibia from Satellite and Aircraft

Though the emphasis of the Southern Africa Regional Science Initiative 2000 (SAFARI-2000) dry season campaign was largely on emission sources and transport, the assemblage of aircraft (including the high altitude NASA ER-2 remote sensing platform and the University of Washington CV-580, UK MRF C-130, and South African Weather Bureau JRA in situ aircrafts) provided a unique opportunity for cloud studies. Therefore, as part of the SAFARI initiative, investigations were undertaken to assess regional aerosol-cloud interactions and cloud remote sensing algorithms. In particular, the latter part of the experiment concentrated on marine boundary layer stratocumulus clouds off the southwest coast of Africa. Associated with cold water upwelling along the Benguela current, the Namibian stratocumulus regime has received limited attention but appears to be unique for several reasons. During the dry season, outflow of continental fires and industrial pollution over this area can be extreme. From below, upwelling provides a rich nutrient source for phytoplankton (a source of atmospheric sulfur through DMS production as well as from decay processes). The impact of these natural and anthropogenic sources on the microphysical and optical properties of the stratocumulus is unknown. Continental and Indian Ocean cloud systems of opportunity were also studied during the campaign. SAFARI 2000 aircraft flights off the coast of Namibia were coordinated with NASA Terra Satellite overpasses for synergy with the Moderate Resolution Imaging Spectroradiometer (MODIS) and other Terra instruments. MODIS was developed by NASA and launched onboard the Terra spacecraft on December 18, 1999 (and Aqua spacecraft on May 4, 2002). Among the remote sensing algorithms developed and applied to this sensor are cloud optical and microphysical properties that include cloud thermodynamic phase, optical thickness, and effective particle radius of both liquid water and ice clouds. The archived products from these algorithms have applications in climate change studies, climate modeling, numerical weather prediction, and fundamental atmospheric research. The archived MODIS Collection 5 cloud products processing stream will be used to analyze low water cloud scenes off the Namibian and Angolan coasts during SAFARI 2000 time period, as well as other years. Pixel-level Terra and Aqua MODIS retrievals (l. km spatial resolution at nadir) and gridded (1' uniform grid) statistics of cloud optical thickness and effective particle radius will be presented, including joint probability distributions between the two quantities. In addition, perspectives from the MODIS Airborne Simulator, which flew on the ER-2 during SAFARI 2000 providing high spatial resolution retrievals (50 m at nadir), will be presented as appropriate. The H-SAF Program requires an experimental operational European-centric Satellite Precipitation Algorithm System (E-SPAS) that produces medium spatial resolution and high temporal resolution surface rainfall and snowfall estimates over the Greater European Region including the Greater Mediterranean Basin. Currently, there are various types of experimental operational algorithm methods of differing spatiotemporal resolutions that generate global precipitation estimates. This address will first assess the current status of these methods and then recommend a methodology for the H-SAF Program that deviates somewhat from the current approach under development but one that takes advantage of existing techniques and existing software developed for the TRMM Project and available through the public domain.

Platnick, Steven E.↗

Trace Gas Measurements in Nascent, Aged and Cloud-processed Smoke from Africa Savanna Fires by Airborne Fourier Transform Infrared Spectroscopy (AFTIR)

We measured stable and reactive trace gases with an airborne Fourier transform infrared spectrometer (AFTIR) on the University of Washington Convair-580 research aircraft in August/September 2000 during the SAFARI 2000 dry season campaign in Southern Africa. The measurements included vertical profiles of C02, CO, H20, and CH4 up to 5.5 km on six occasions above instrumented ground sites and below the TERRA satellite and ER-2 high-flying research aircraft. We also measured the trace gas emissions from 10 African savanna fires. Five of these fires featured extensive ground-based fuel characterization, and two were in the humid savanna ecosystem that accounts for most African biomass burning. The major constituents we detected in nascent CH3OOH, HCHO, CH30H, HCN, NH3, HCOOH, and C2H2. These are the first quantitative measurements of the initial emissions of oxygenated volatile organic compounds (OVOC), NH3, and HCN from African savanna fires. On average, we measured 5.3 g/kg of OVOC and 3.6 g/kg of hydrocarbons (including CH4) in the initial emissions from the fires. Thus, the OVOC will have profound, largely unexplored effects on tropical tropospheric chemistry. The HCN emission factor was only weakly dependent on fire type; the average value (0.53 g/kg) is about 20 times that of a previous recommendation. HCN may be useful as a tracer for savanna fires. Delta O3/Delta CO and Delta CH3COO/Delta CO increased to as much as 9% in <1 h of photochemical processing downwind of fires. Direct measurements showed that cloud processing of smoke greatly reduced CH30H, NH3, CH3COOH, SO2, and NO2 levels, but significantly increased HCHO and NO.

Yokelson, Robert J.↗

The SMART Ground-based Remote Sensing for Terra/MODIS Validation

A ground-based remote sensing system - SMART (Surface Measurements for Atmospheric Radiative Transfer) - was deployed during both the SAFARI-2000 and the ARREX-1999 dry season campaigns. The measurement site is the Skukuza airport. The operation period for 1999 is from August 16 to September 10. The main instruments include shortwave (approximately 0.28-2.8 micrometers) and longwave (approximately 4-50 micrometers) broadband radiometers, a shadow-band radiometer, a micro-pulse lidar, and a microwave radiometer. We also did some measurements of solar spectral flux by using an ASD spectrometer. The operation period for 2000 is from August 15 to September 22. This time we added a few new features to the SMART system: a solar tracker for direct and diffuse components of solar fluxes; the scanning capability to the microwave radiometer; a whole sky camera for documenting the sky conditions every minute; and a mini-weather station for atmospheric pressure, temperature, humidity, wind speed/direction. A surface SSFR (Solar Spectral Flux Radiometer) from NASA Ames also joined us for the measurements. This is a unique data set with reasonably long observational period and high accuracy. The data show good correlation with the local weather patterns. We also see diurnal change and some special events, such as fierce fires nearby. To quantify the surface radiative forcing of biomass burning aerosols, many pyranometers, pyrgeometers, and pyrheliometers measure the global, direct, and diffuse irradiance at the surface. These fluxes combining with the collocated optical thickness retrievals from sun photometer (or shadow-band radiometer), the solar radiative forcing, proportional to delta F/delta tau, can be investigated. Integrated with measurements of other instruments at the site, these data sets will serve as "ground truth" for the satellite measurements and modeling.

Tsay, Si-Chee↗

Shadow of a laser beam

Light, being massless, casts no shadow; under ordinary circumstances, photons pass right through each other unimpeded. Here, we demonstrate a laser beam acting like an object — the beam casts a shadow upon a surface when the beam is illuminated by another light source. We observe a regular shadow in the sense it can be seen by the naked eye, it follows the contours of the surface it falls on, and it follows the position and shape of the object (the laser beam). Specifically, we use a nonlinear optical process involving four atomic levels of ruby. We are able to control the intensity of a transmitted laser beam by applying another perpendicular laser beam. We experimentally measure the dependence of the contrast of the shadow on the power of the laser beam, finding a maximum of approximately 22%, similar to that of a shadow of a tree on a sunny day. We provide a theoretical model that predicts the contrast of the shadow. This work opens new possibilities for fabrication, imaging, and illumination.

47 OTHER INSTRUMENTATION↗

Cloud and Radiation Studies during SAFARI 2000

Though the emphasis of the Southern Africa Regional Science Initiative 2000 (SAFARI-2000) dry season campaign was largely on emission sources and transport, the assemblage of aircraft (including the high altitude NASA ER-2 remote sensing platform and the University of Washington CV-580, UK MRF C130, and South African Weather Bureau JRA in situ aircrafts) provided a unique opportunity for cloud studies. Therefore, as part of the SAFARI initiative, investigations were undertaken to assess regional aerosol-cloud interactions and cloud remote sensing algorithms. In particular, the latter part of the experiment concentrated on marine boundary layer stratocumulus clouds off the southwest coast of Africa. Associated with cold water upwelling along the Benguela current, the Namibian stratocumulus regime has received limited attention but appears to be unique for several reasons. During the dry season, outflow of continental fires and industrial pollution over this area can be extreme. From below, upwelling provides a rich nutrient source for phytoplankton (a source of atmospheric sulphur through DMS production as well as from decay processes). The impact of these natural and anthropogenic sources on the microphysical and optical properties of the stratocumulus is unknown. Continental and Indian Ocean cloud systems of opportunity were also studied during the campaign. Aircraft flights were coordinated with NASA Terra Satellite overpasses for synergy with the Moderate Resolution Imaging Spectroradiometer (MODIS) and other Terra instruments. An operational MODIS algorithm for the retrieval of cloud optical and physical properties (including optical thickness, effective particle radius, and water path) has been developed. Pixel-level MODIS retrievals (11 km spatial resolution at nadir) and gridded statistics of clouds in th SAFARI region will be presented. In addition, the MODIS Airborne Simulator flown on the ER-2 provided high spatial resolution retrievals (50 m at nadir). These retrievals will be discussed and compared with in situ observations.

Platnick, Steven↗

Tropospheric Carbon Monoxide Measurements from the Scanning High-resolution Interferometer Sounder on 7 September 2000 in Southern Africa during SAFARI 2000

Retrieved tropospheric carbon monoxide (CO) column densities are presented for more than 9000 spectra obtained by the University of Wisconsin-Madison (UWis) Scanning High-Resolution Interferometer Sounder (SHIS) during a flight on the NASA ER-2 on 7 September 2000 as part of the Southern African Regional Science Initiative (SAFARI 2000) dry season field campaign. Enhancements in tropospheric column CO were detected in the vicinity of a controlled biomass burn in the Timbavati Game Reserve in northeastern South Africa and over the edge of the river of smoke in south central Mozambique. Relatively clean air was observed over the far southern coast of Mozambique. Quantitative comparisons are presented with in situ measurements from five different instruments flying on two other aircraft: the University of Washington Convair-580 (CV) and the South African Aerocommander JRB in the vicinity of the Timbavati fire. Measured tropospheric CO columns (extrapolated from 337 to 100 mb) of 2.1 x 10(exp 18) per square centimeter in background air and up to 1.5 x 10(exp 19) per square centimeter in the smoke plume agree well with SHIS retrieved tropospheric CO columns of (2.3 plus or minus 0.25) x 10(exp 18) per square centimeter over background air near the fire and (1.5 plus or minus 0.35) x 10(exp 19) per square centimeter over the smoke plume. Qualitative comparisons are presented with three other in situ CO profiles obtained by the South African JRA aircraft over Mozambique and northern South Africa showing the influence of the river of smoke.

McMillan, W. W.↗

Visualizing Airborne and Satellite Imagery

Remote sensing is a process able to provide information about Earth to better understand Earth's processes and assist in monitoring Earth's resources. The Cloud Absorption Radiometer (CAR) is one remote sensing instrument dedicated to the cause of collecting data on anthropogenic influences on Earth as well as assisting scientists in understanding land-surface and atmospheric interactions. Landsat is a satellite program dedicated to collecting repetitive coverage of the continental Earth surfaces in seven regions of the electromagnetic spectrum. Combining these two aircraft and satellite remote sensing instruments will provide a detailed and comprehensive data collection able to provide influential information and improve predictions of changes in the future. This project acquired, interpreted, and created composite images from satellite data acquired from Landsat 4-5 Thematic Mapper (TM) and Landsat 7 Enhanced Thematic Mapper plus (ETM+). Landsat images were processed for areas covered by CAR during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCT AS), Cloud and Land Surface Interaction Campaign (CLASIC), Intercontinental Chemical Transport Experiment-Phase B (INTEXB), and Southern African Regional Science Initiative (SAFARI) 2000 missions. The acquisition of Landsat data will provide supplemental information to assist in visualizing and interpreting airborne and satellite imagery.

Bierwirth, Victoria A.↗

Ozone Pollution, Transport and Variability: Examples from Satellite and In-Situ Observations

Regional and intercontinental transport of ozone has been observed from satellite, aircraft and sounding data. Over the past several years, we have developed new tropospheric ozone retrieval techniques from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique uses Level 2 total ozone and was used to follow the 1997 fires in the wake of the El-Nino-related fires in southeast Asia and the Indonesian maritime continent. The TOMS-direct method ('TDOT' = TOMS Direct Ozone in the Troposphere) is a newer algorithm that uses TOMS radiances directly to extract tropospheric ozone. Ozonesonde data that have been taken in campaigns (e.g. TRACE-P) and more consistently in the SHADOZ (Southern Hemisphere Additional Ozonesondes) project, reveal layers of pollution traceable with trajectories. Examples will be shown of long-range transport and recirculation over Africa during SAFARI-2000.

Thompson, Anne↗

Airborne Sun photometry and Closure Studies in SAFARI-2000 Dry Season Campaign

From August 13 to September 25, the Southern African Regional Science Initiative's (SAFARI 2000) dry-season airborne campaign studied the complex interactions between the region's ecosystems, air pollution, atmospheric circulation, land-atmosphere interactions, and land use change. The field campaign was timed to coincide with the annual winter fire season in Southern Africa. This challenging campaign. which coordinated ground-based measurement teams, multiple research aircraft, and satellite overpasses across nine African nations, was head quartered at the Petersburg International Airport in South Africa's Northern Province. Among many others, unique coordinated observations were made of the evolution of massive, thick haze layers produced by industrial emissions, biomass burning, marine and biogenic sources. The NASA Ames Airborne Tracking 14-channel Sunphotometer (AATS-14) was operated successfully aboard the University of Washington CV-580 during 24 data flights. The AATS-14 instrument measures the transmission of the direct solar beam at 14 discrete wavelengths (3501558 nm) from which we derive spectral aerosol optical depths (AOD), columnar water vapor (CWV) and columnar ozone. Flying at different altitudes over a fixed location allows derivation of layer AOD and CWV. Data taken during feasible vertical profiles allows derivation of aerosol extinction and water vapor density. In the talk, we show comparisons with ground-based AERONET sun/sky photometer results, with ground based MPL-Net lidar data, and with measurements from a lidar aboard the high flying ER-2 aircraft. We will use measurements from the Ames Solar Spectral Flux Radiometer to derive estimates of solar spectral forcing as a function of aerosol thickness. Validations of TOMS and Terra satellite aerosol and water-vapor retrievals will also be discussed.

Schmid, B.↗

The 1998-2000 SHADOZ (Southern Hemisphere ADditional OZonesondes) Tropical Ozone Climatology: Ozonesonde Precision, Accuracy and Station-to-Station Variability

As part of the SAFARI-2000 campaign, additional launches of ozonesondes were made at Irene, South Africa and at Lusaka, Zambia. These represent campaign augmentations to the SHADOZ database described in this paper. This network of 10 southern hemisphere tropical and subtropical stations, designated the Southern Hemisphere ADditional OZonesondes (SHADOZ) project and established from operational sites, provided over 1000 profiles from ozonesondes and radiosondes during the period 1998-2000. (Since that time, two more stations, one in southern Africa, have joined SHADOZ). Archived data are available at: http://code9l6.gsfc.nasa.gov/Data-services/shadoz>. Uncertainties and accuracies within the SHADOZ ozone data set are evaluated by analyzing: (1) imprecisions in stratospheric ozone profiles and in methods of extrapolating ozone above balloon burst; (2) comparisons of column-integrated total ozone from sondes with total ozone from the Earth-Probe/TOMS (Total Ozone Mapping Spectrometer) satellite and ground-based instruments; (3) possible biases from station-to-station due to variations in ozonesonde characteristics. The key results are: (1) Ozonesonde precision is 5%; (2) Integrated total ozone column amounts from the sondes are in good agreement (2-10%) with independent measurements from ground-based instruments at five SHADOZ sites and with overpass measurements from the TOMS satellite (version 7 data). (3) Systematic variations in TOMS-sonde offsets and in groundbased-sonde offsets from station to station reflect biases in sonde technique as well as in satellite retrieval. Discrepancies are present in both stratospheric and tropospheric ozone. (4) There is evidence for a zonal wave-one pattern in total and tropospheric ozone, but not in stratospheric ozone.

Witte, J. C.↗