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At least 19 records

Numerical simulations of sand migration during gas production in hydrate-bearing sands interbedded with thin mud layers at site NGHP-02-16

The geomechanical behavior of gas hydrate-bearing sands during gas production is complex, involving changes in hydrate-dependent mechanical characteristics and also redistribution of stresses carried by the hydrate. When an interbedded mud layer is present, the complex response of the hydrate-bearing sediments is more pronounced because hydrate dissociation tends to occur preferentially in the sands adjacent to the hydrate-free mud layer, which can act as a heat source. This leads to non-uniform sediment deformation and potentially to shearing deformation along the sand/mud layers. In addition, since the hydrate-bearing sand permeability becomes far greater than the mud permeability with hydrate dissociation, a greater hydraulic gradient may exist along the interface between the sand/mud layers. These two behaviors may contribute to sand migration and thus a thorough study on the effect of a thin interbedded mud layer on the extent of sand migration is necessary. This paper presents numerical sand migration modeling of sand/mud interbedded hydrate-bearing sediments found at Site NGHP-02-16, one of 25 sites drilled as a part of National Gas Hydrate Program Expedition 02 (NGHP-02) in the offshore of India, subjected to depressurization. For a comparison and better understanding, simulation of homogeneous hydrate-bearing sediments is also conducted. It is found that greater sand migration occurs when the interbedded mud layer is present because of greater shearing deformation and greater pressure gradients at sand-mud interface.

58 GEOSCIENCES↗

Aerolian erosion, transport, and deposition of volcaniclastic sands among the shifting sand dunes, Christmas Lake Valley, Oregon: TIMS image analysis

Remote sensing is a tool that, in the context of aeolian studies, offers a synoptic view of a dune field, sand sea, or entire desert region. Blount et al. (1990) presented one of the first studies demonstrating the power of multispectral images for interpreting the dynamic history of an aeolian sand sea. Blount's work on the Gran Desierto of Mexico used a Landsat TM scene and a linear spectral mixing model to show where different sand populations occur and along what paths these sands may have traveled before becoming incorporated into dunes. Interpretation of sand transport paths and sources in the Gran Desierto led to an improved understanding of the origin and Holocene history of the dunes. With the anticipated advent of the EOS-A platform and ASTER thermal infrared capability in 1998, it will become possible to look at continental sand seas and map sand transport paths using 8-12 mu m bands that are well-suited to tracking silicate sediments. A logical extension of Blount's work is to attempt a similar study using thermal infrared images. One such study has already begun by looking at feldspar, quartz, magnetite, and clay distributions in the Kelso Dunes of southern California. This paper describes the geology and application of TIMS image analysis of a less-well known Holocene dune field in south central Oregon using TIMS data obtained in 1991.

Edgett, Kenneth S.↗

Three-Dimensional Evaluation of Sand Particle Fracture Using Discrete-Element Method and Synchrotron Microcomputed Tomography Images

Recent research showed that fracture of sand particles plays a significant role in determining the plastic bulk volumetric changes of granular materials under different loading conditions. One of the major tools used to better understand the influence of particle fracture on the behavior of granular materials is discrete-element modeling (DEM). This paper employed the bonded block model (BBM) to simulate the fracture behavior of sand. Each sand particle is modeled as an agglomerate of rigid blocks bonded at their contacts using the linear-parallel contact model, which can transmit both moment and force. DEM simulated particles closely matched the actual three-dimensional (3D) shape of sand particles acquired using high-resolution 3D synchrotron microcomputed tomography (SMT). Results from unconfined one-dimensional (1D) compression of a single synthetic silica cube were used to calibrate the model parameters. Particle fracture was investigated for specimens composed of three sand particles that were loaded under confined 1D compression. Breakage energy measured from DEM models matched well with that measured experimentally. The paper studied the effects of contact loading condition and particle interaction on the fracture mode of particles using BBM that can closely capture the 3D shape of real sand particles.

58 GEOSCIENCES↗

Role of mineral flotation technology in improving bitumen extraction from mined Athabasca oil sands—II. Flotation hydrodynamics of water‐based oil sand extraction

Abstract Bitumen flotation hydrodynamics in water‐based oil sand extraction is critically reviewed by comparing aeration of oil sand slurries with mineral flotation. The role of the two‐stage particle‐bubble attachment model in flotation is emphasized as a means to accelerate bitumen flotation recovery. It involves the generation of micro/nanobubbles and their frosting on hydrophobic bitumen droplets, followed by their attachment to a flotation‐size bubble via its coalescence with the nanobubbles frosted on the bitumen. Nanobubble generation by hydrodynamic cavitation demonstrates that the size of nanobubbles can be reduced, and the number of nanobubbles increased by fast liquid flow, intensified agitation, high dissolved gas content and surfactant concentration. The mechanism of pre‐existing gas nuclei in enhancing nanobubble generation by cavitation is utilized to produce a large volume of stabilized nanobubbles for practical flotation, by continuously recirculating the stream through a gas saturation tank or a cavitation tube. The aeration of oil sand slurries in hydrotransport pipelines is analyzed based on its similarity to dissolved air flotation. Bitumen extraction recovery increased significantly with the presence of nanobubbles in the system. The role of improved flotation hydrodynamics in bitumen recovery is briefly discussed in terms of the Suncor operation using flotation columns to process oil sand middling streams. Future research should be directed at understanding bitumen flotation kinetics, optimizing size ranges of nanobubbles for maximized flotation recovery, minimizing wearing of cavitation tubes in industrial operations, and intensifying the role of in‐situ nanobubble nucleation on hydrophobic particles/bitumen droplets in flotation, especially for bitumen extraction from underperforming oil sands.

Zhou, Joe Z.↗

Fractal breakage of porous carbonate sand particles: Microstructures and mechanisms

In situ, three-dimensional (3D) characterizations of particle breakage in porous carbonate sands are presented, for the first time, with synchrotron-based micro computed tomography. Evolution of grain-scale characteristics are identified and quantified via elaborate image processing and topology analyses. The sequential 3D images reveal distinctly different fracture mechanisms for carbonate sands from silica sands. The angular shape of carbonate sand particles facilitates bending fracture, and particles with a lower sphericity and a higher porosity are more prone to break. 3D crack networks extracted from fractured particles imply considerable cleavage along initial pores. The fractal dimension of crack networks increases with external loading due to crack branching via cleavage. The resultant fragment size distribution also appears fractal and the fractal feature is valid down to the breakage limit of calcium carbonate. Crack propagation along the initial pores reduces the energy barrier for particle breakage and thus fracture strength of particles

Carbonate sands↗

Spectral induced polarization of shaly sands: Influence of the electrical double layer

I developed a new model named POLARIS describing the complex conductivity of (pyrite‐free) shaly poorly sorted sands. This model is based on the solution given by the effective medium theory for grains coated by an electrical double layer and immersed in a background electrolyte. The electrical double layer comprises the Stern layer and the diffuse layer. Both layers play very distinct roles in the in‐phase and quadrature conductivities. The polarization of the shaly sands is mainly controlled by the polarization of the Stern layer (except at very high salinities) with a very small mobility of the counterions contained in this layer. The in‐phase component of the conductivity is controlled by the conductivity of the pore water with a contribution associated with the diffuse layer (the contribution of the Stern layer seems negligible). The fraction of counterions in the Stern layer is computed from a simple sorption isotherm and is used to infer the quadrature conductivity. The quadrature conductivity is assumed to be frequency independent, which is a reasonable approximation in clayey sands and sandstones, in agreement with observations. The polarization model is also based on the assumption that the Stern layer is discontinuous between grains, an assumption that is consistent with recent models of ionic transport in clayey sands. POLARIS explains the dependence of the quadrature conductivity on the salinity, cation exchange capacity, specific surface area (or specific surface per unit pore volume), and temperature. It can be used to predict the saturation and the permeability (inside 1 order of magnitude).

54 ENVIRONMENTAL SCIENCES↗

Source and distribution of naturally occurring arsenic in groundwater from Alberta’s Southern Oil Sands Regions

Arsenic (As) concentrations as high as 179 μg/L have been observed in shallow groundwater in the Alberta’s Southern Oil Sand Regions. The geology of this area of Alberta includes a thick cover (up to 200 m) of unconsolidated glacial deposits, with a number of regional interglacial sand and gravel aquifers, underlain by marine shale. Arsenic concentrations observed in 216 unconsolidated sediment samples ranged from 1 and 17 ppm. A survey of over 800 water wells sampled for As in the area found that 50% of the wells contained As concentrations exceeding drinking water guidelines of 10 μg/L. Higher As concentrations in groundwater were associated with reducing conditions. Measurements of As speciation from 175 groundwater samples indicate that As(III) was the dominant species in 74% of the wells. Speciation model calculations showed that the majority of groundwater samples were undersaturated with respect to ferrihydrite, suggesting that reductive dissolution of Fe-oxyhydroxides may be the source of some As in groundwater. Detailed mineralogical characterization of sediment samples collected from two formations revealed the presence of fresh framboidal pyrite in the deeper unoxidized sediments. Electron microprobe analysis employing wavelength dispersive spectrometry indicated that the framboidal pyrite had variable As content with an average As concentration of 530 ppm, reaching up to 1840 ppm. In contrast, the oxidized sediments did not contain framboidal pyrite, but exhibited spheroidal Fe-oxyhydroxide grains with elevated As concentrations. The habit and composition suggest that these Fe-oxyhydroxide grains in the oxidized sediment were an alteration product of former framboidal pyrite grains. X-ray absorption near edge spectroscopy (XANES) indicated that the oxidized sediments are dominated by As(V) species having spectral features similar to those of goethite or ferrihydrite with adsorbed As, suggesting that Fe-oxyhydroxides are the dominant As carriers. XANES spectra collected on unoxidized sediment samples, in contrast, indicated the presence of a reduced As species (As(-I)) characteristic of arsenopyrite and arsenian pyrite. The results of the mineralogical analyses indicate that the oxidation of framboidal pyrite during weathering may be the source of As released to shallow aquifers in this region.

58 GEOSCIENCES↗

Primary sedimentary structures and the internal architecture of a Martian sand body in search of evidence for sand transport and deposition

Lunar experiences show that unmanned sample return missions, despite limitations on sample size, can produce invaluable data to infer crustal processes, regolith processes, regolith-atmosphere/ionosphere interaction processes, etc. Drill cores provide a record of regolith evolution as well as a more complete sample of the regolith than small scoops and/or rakes. It is proposed that: (1) a hole be drilled in a sand body to obtain continuous oriented cores; a depth of about 10 m would be compatible with what we know of bed form hierarchy of terrestrial stream deposits; (2) two trenches, at right angles to each other and close to the drill-hole, be dug and the walls scraped lightly such that primary/internal sedimentary structures of the sand body become visible; (3) the walls of the trenches be made gravitationally stable by impregnation techniques; (4) acetate or other peels of a strip on each wall be taken; and (5) appropriately scaled photographs of the walls be taken at different sun-angles to ensure maximum ease of interpretation of sedimentary structures; and, to correlate these structural features with those in the core at different depth levels of the core.

Basu, Abhijit↗

Vertical Gradients in Fluidized Sand Columns

This study evaluated the influence of diameter and grain size on the initiation and continuation phase of piping erosion. Twelve tests were performed in a laboratory setting in which sand was fluidized in a controlled setting and hydraulic gradients within the sand, flow rates through the sand, and expansion of the sand columns were measured as the sand was fluidized. This study was conducted to improve the understanding of the resistance a vertical column of sand offers to piping erosion. From the fluidization tests conducted in two permeameters with different diameters, it cannot be concluded that permeameter diameter has a significant influence on a specimen’s resistance to piping erosion. Although one test conducted in the smaller diameter permeameter did record hydraulic gradients lower than those recorded in tests conducted in the larger diameter permeameter, this was not a consistent observation for all tests run in the smaller diameter permeameter. Further analysis ought to involve more tests run in each permeameter as well as incorporating additional permeameters with both larger and smaller diameters than those used in this study. From the fluidization tests conducted using the well-graded, coarse-, medium-, and fine-grained sands, it appears that resistance to piping is dependent on grain size and grain size distribution. The coarse-grained sand offered the most resistance to piping, the fine-grained sand offered the least, and the medium-grained and well-graded sands offered similar resistances between those of the coarse-grained and fine-grained sands. Gradients at which sand boils were observed, maximum gradients reached before the sand fluidized, and the minimum gradients reached at the conclusion of each test also appear to be influenced by grain size and grain size distribution. Tests conducted on the coarse-grained sand recorded the highest and most closely spaced sand boil, maximum, and minimum gradients, indicating that it offered the highest and most constant resistance to piping, while the fine-grained sand tests recorded the lowest sand boil, maximum, and minimum gradients, indicating that it offered the least resistance to piping and that resistance decreased as the tests progressed. The medium-grained sand tests recorded sand boil, maximum, and minimum gradients between those of the coarse-grained and fine-grained sands. The well-graded sand tests recorded the lowest sand boil gradient, which could be indicative of the occurrence of suffusion erosion occurring in conjunction with piping erosion, whereby the finer particles were washed out of the sand matrix at relatively low gradients, forming sand boils while the relatively coarser matrix remained resistant to piping. All tests recorded maximum gradients that were lower than the theoretical critical gradients calculated using Equation 4. This is likely due to the changes in the internal configuration of the sand as the piping process 33 initiates. In order to better understand the influence of gradation on resistance to piping, more sand gradations should be tested in future work. Measured hydraulic gradients in the lower portion of the fluidized sands were higher than those measured in higher portions. This could be explained if the density of the fluidized sand was not uniform, with more material near the base of the column than near the top, which is contrary to the findings of Sellmeijer. Furthermore, the tests were terminated when the maximum height of the upstream reservoir was reached but did not give any evidence that gradients had leveled off to a uniform “final gradient”. It is likely that gradients would have continued to dissipate had more hydraulic head been applied to the upstream reservoir. In order to better understand this, additional testing should be conducted using an upstream reservoir capable of simulating higher hydraulic heads.

13 HYDRO ENERGY↗