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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Rocketdyne - SE-7 and SE-8 Engines

The 70-pound SE-7 engine is very similar with its two valves, ablative material, a silicon carbide liner, a silicon carbide throat, and overall configuration. There were different wraps. One had a ninety-degree ablative material orientation. That is important because it caused problems with the SE-8, but not for this application. It was not overly stressed. It was a validation of the off-the-shelf application approach. There were two SE-7 engines located on the stage near the bottom. They had their own propellant tanks. That was the application. All it did was give a little bit of gravity by firing to push the propellants to the bottom of the tanks for start or restart. It was not a particularly complicated setup. (See Slides 6 and 7, Appendix F) What had we learned? This was a proven engine in a space environment. There weren't any development issues. Off-the-shelf seemed to work. There were no operational issues, which made the SE-7 very cost-effective. Besides NASA, the customer for this application was the Douglas Aircraft Company. Douglas decided the off-the-shelf idea was cost-effective. With the Gemini Program, the company was McDonnell Aircraft Corporation, which was part of the reason the off-the-shelf idea was applied to the Apollo. (See Slide 8, Appendix F) However, here are some differences between Apollo and Gemini vehicles. For one thing, the Apollo vehicle was really moving at high speed when it re-entered the atmosphere. Instead of a mere 17,000 miles per hour, it was going 24,000 miles per hour. That meant the heat load was four times as high on the Apollo vehicle as on the Gemini craft. Things were vibrating a little more. We had two redundant systems. Apollo was redundant where it could be as much as possible. That was really a keystone or maybe an anchor point for Apollo. We decided to pursue the off-the-shelf approach. However, the prime contractor was a different entity - the North American Space Division. They thought they ought to tune up this off-the-shelf setup. It was a similar off-the-shelf application, but at a higher speed. They wanted to improve it. What they wanted to improve was the material performance of silicon carbide. They were uncomfortable with the cracks they were seeing. They were uncomfortable with the cracks in the throat, and feeling that the environment was a little tougher, that maybe it was going to rattle, perhaps something would fall out, and they would have a problem. They wanted to eliminate the ceramic liner, and they wanted a different throat material. (See Slides 9 and 10, Appendix F) The Rocketdyne solutions were to replace silicon carbide material with a more forgiving ceramic material. Also, due to the multiple locations within the vehicle, the shape of the nozzles varied. Some nozzles were long, and some nozzles were short. We came up with a single engine design with variable nozzle extensions and configurations to fit particular vehicle locations. (See Slides 10 and 11, Appendix F)

Harmon, Tim↗

SE-FIT

The mathematical theory of capillary surfaces has developed steadily over the centuries, but it was not until the last few decades that new technologies have put a more urgent demand on a substantially more qualitative and quantitative understanding of phenomena relating to capillarity in general. So far, the new theory development successfully predicts the behavior of capillary surfaces for special cases. However, an efficient quantitative mathematical prediction of capillary phenomena related to the shape and stability of geometrically complex equilibrium capillary surfaces remains a significant challenge. As one of many numerical tools, the open-source Surface Evolver (SE) algorithm has played an important role over the last two decades. The current effort was undertaken to provide a front-end to enhance the accessibility of SE for the purposes of design and analysis. Like SE, the new code is open-source and will remain under development for the foreseeable future. The ultimate goal of the current Surface Evolver Fluid Interface Tool (SEFIT) development is to build a fully integrated front-end with a set of graphical user interface (GUI) elements. Such a front-end enables the access to functionalities that are developed along with the GUIs to deal with pre-processing, convergence computation operation, and post-processing. In other words, SE-FIT is not just a GUI front-end, but an integrated environment that can perform sophisticated computational tasks, e.g. importing industry standard file formats and employing parameter sweep functions, which are both lacking in SE, and require minimal interaction by the user. These functions are created using a mixture of Visual Basic and the SE script language. These form the foundation for a high-performance front-end that substantially simplifies use without sacrificing the proven capabilities of SE. The real power of SE-FIT lies in its automated pre-processing, pre-defined geometries, convergence computation operation, computational diagnostic tools, and crash-handling capabilities to sustain extensive computations. SE-FIT performance is enabled by its so-called file-layer mechanism. During the early stages of SE-FIT development, it became necessary to modify the original SE code to enable capabilities required for an enhanced and synchronized communication. To this end, a file-layer was created that serves as a command buffer to ensure a continuous and sequential execution of commands sent from the front-end to SE. It also establishes a proper means for handling crashes. The file layer logs input commands and SE output; it also supports user interruption requests, back and forward operation (i.e. undo and redo), and others. It especially enables the batch mode computation of a series of equilibrium surfaces and the searching of critical parameter values in studying the stability of capillary surfaces. In this way, the modified SE significantly extends the capabilities of the original SE.

Chen, Yongkang↗

Partial Pressures for Several In-Se Compositions from Optical Absorbance of the Vapor

The optical absorbance of the vapor phase over various In-Se compositions between 33.3-60.99 at.% Se and 673-1418 K was measured and used to obtain the partial pressures of Se2(g) and In2Se(g). The results are in agreement with silica Bourdon gauge measurements for compositions between 50-61 at.%, but significantly higher than those from Knudsen cell and simultaneous Knudsen-torsion cell measurements. It is found that 60.99 at.% Se lies outside the sesquiselenide homogeneity range and 59.98 at.% Se lies inside and is the congruently melting composition. The Gibbs energy of formation of the liquid from its pure liquid elements between 1000-1300 K is essentially independent of temperature and falls between -36 to -38 kJ per g atomic weight for 50 and 56% Se at 1200 and 1300 K.

Brebrick, R. F.↗

Mixed-Domain Charge Transport in the S-Se System from First Principles

Lithium-sulfur (Li-S) batteries are emerging systems heralded for the inexpensive cathode component (in S)and higher energy density than that of typical Li-ion batteries [1–5]. For the latter reason in particular, they are drawing high levels of interest for long-range electric air-craft applications where high gravimetric energy density is of utmost importance. Unfortunately, S by itself has a much too low electrical conductivity to be useful asa stand-alone cathode material. One effort to alleviate these shortcomings is to alloy sulfur with selenium [6–13],which is expected to improve the paltry conductivity of S as Se, depending on the phase, is 10∼30 times more conductive. This, however, comes at the cost of the heavier mass of Se that works against the gravimetric energy density. The charge transport behavior in the S1−xSex alloy system, not yet fully known or understood, is necessary for one to navigate the trade-offs between conductivity and other variables such as energy density en route to ultimately determining the optimum Se content, on demand. Charting carrier mobilities and conductivities in the S-Se system throughout the compositional spectrum from first principles at a predictive level is therefore critical.

Junsoo Park↗

Effect of process conditions and chemical composition on the microstructure and properties of chemically vapor deposited SiC, Si, ZnSe, ZnS and ZnS(x)Se(1-x)

Subatmospheric pressure CVD processes have been developed to produce theoretically dense, highly pure, void-free and large area bulk materials, SiC, Si, ZnSe, ZnS and ZnS(x)Se(1-x). These materials are used for optical elements, such as mirrors, lenses and windows, over a wide spectral range from the VUV to the IR. We discuss the effect of CVD process conditions on the microstructure and properties of these materials, with emphasis on optical performance. In addition, we discuss the effect of chemical composition on the properties of the composite material ZnS(x)Se(1-x). We first present a general overview of the bulk CVD process and the relationship between process conditions, such as temperature, pressure, reactant gas concentration and growth rate, and the microstructure, morphology and properties of CVD-grown materials. Then we discuss specific results for CVD-grown SiC, Si, ZnSe, ZnS and ZnS(x)Se(1-x).

Pickering, Michael A.↗

Partial Pressures of In-Se from Optical Absorbance of the Vapor

The optical absorbance of the vapor phase over various In-Se compositions between 33.3 and 61 atomic percent and 673 and 1418K has been measured and used to obtain the partial pressures of Se2(g) and In2Se(g). The results are in agreement with silica Bourdon gage measurements for compositions between 50 and 61 atomic percent but significantly higher than those from Knudsen cell and simultaneous Torsion-Knudsen cell measurements. The sequiselenide is found to sublime incongruently. Congruent vaporization occurs for the liquid above 1000 K between 50.08 and 56 at. percent Se. The Gibbs energy of formation of the liquid from its pure liquid elements between 1000 and 1300K is essentially independent of temperature and falls between -36 and -38 kJ per gram atomic weight for 50 and 56 percent Se at 1200 and 1300K.

Brebrick, R. F.↗

Overview of Extractive and Optical PM Measurements from the NASA SE-5 High Pressure Flame Diagnostics Laboratory

Soot emissions measurements of multiphase non-premixed flames are sparse in the literature due to the complexities of sampling in such environments. We present an overview from on-going work at the NASA SE-5 High Pressure Flame Diagnostics laboratory focusing on soot and gaseous emissions at elevated pressures. SE-5 is a gaseous and liquid fueled high pressure flame tube facility capable of operating at pressures up to 880 psia, cooling capacity of 4,000,000 BTU/hr, liquid fuel flow rates up to 2 GPH, and an equivalence ratio range of 0.2 (fuel lean) to 4 (fuel rich). SE-5 provides optical access via four UV-grade fused silica optical windows of the primary reaction zone enabling non-intrusive optical diagnostics of the flame.

Soot↗

Growth and characterization of Hg(1-x)Cd(x)Se alloys

A detailed evaluation of the influence of growth conditions on the radial and axial compositional variations in directionally solidified Hg(1-x)Cd(x)Se alloys was performed. The measured axial compositional profiles were fitted to theoretical profiles to determine the effective solute (CdSe) diffusion coefficient (D) for the Hg(1-x)Cd(x)Se system. The value for D was estimated to be 3.0 + or - 0.5 x 10 to the -5th sq cm/s and did not appear to be significantly affected by the rate of crystal growth. The axial crystal uniformity was shown to be highly growth-rate dependent, with the faster growth rates producing crystals of more uniform composition in the axial direction. The magnitude of the radial variations was also shown to be highly growth-rate dependent, with the slower growth rates producing crystals of greater radial uniformity. This translation rate dependence of the radial uniformity is discussed in terms of lateral solute diffusion and convective interfacial fluid flows.

Andrews, R. N.↗

Purification, growth, and characterization of Zn(x)Cd(1-x)Se crystals

The purification of starting materials which were used in the growth of Zn(x)Cd(1-x)Se (x = 0.2) single crystals using the traveling solution method (TSM) is reported. Up to 13 cm long single crystals and as grown resistivities of 6 x 10(exp 12) ohm/cm could be achieved. Infrared and Raman spectra of Zn(0.2)Cd(0.8)Se are also presented and discussed.

Silberman, E.↗

Characterization of directionally solidified Hg(1-x)Zn(x)Se semiconducting alloys

Hg(1-x)Zn(x)Se alloys with composition between x = 0.08 and 0.115 were synthesized from elemental constituents and were resolidified using a Bridgman-Stockbarger growth technique. By performing precision mass-density measurements on selected wafers cut perpendicular to the growth axis, it was shown that the axial compositional profiles fit a numerical solution to the 1D diffusion equation which takes into account the variation of interface velocity with time. Infrared transmission-edge measurements performed on selected transverse slices from each ingot showed that the relative radial variations in composition decreased with decreasing growth rate. Van der Pauw measurements on selected wafers showed that the 10 exp 18/cu cm electron concentration, typical of as-grown crystals, could be reduced by approximately an order of magnitude by annealing in Se vapor.

Cobb, S. D.↗

Microstructural Development of Directionally Solidified Hg(1-x)Zn(x)Se Alloys

Hg(1-x)Zn(x)Se alloys have been studied as an alternative to HgCdTe for the detection of electromagnetic radiation, because the shorter ZnSe and HgSe bonds were predicted to improve lattice stability. Previous studies showed that optical properties were stable with time and that the microhardness was higher than for HgTe based alloys. However, for this material to be commercially viable, compositional variations must be reduced, and the distribution of defects induced by the growth process must be understood. The basic structural properties of bulk materials were characterized, and dislocation etch pit densities were measured to determine whether the addition of Zn to the HgSe lattice reduced the potential for dislocation formation. Hg(0.9)Zn(0.1)Se alloys were directionally solidified using a modified Bridgman-Stockbarger method and in an applied magnetic field. Radial compositional variations were greatly reduced when solidification occurred in an applied magnetic field. The combination of a convex liquid-solid interface shape and a method for reduced wetting produced boules that were a single crystal after reaching full diameter. Observed surface features indicated ampoule wetting could be eliminated using a graphite getter. Microstructural characteristics were greatly improved over HgCdTe alloys, In six boules, a total of only one twin was observed, and no inclusions were found. A method for polishing and producing dislocation etch pits was developed for these alloys, revealing dislocation etch pit densities one to two orders of magnitude less than HgTe based alloys. A kink in the thermal profile during processing of one boule generated more dislocations than did lattice mismatch due to compositional variations. The results of this investigation indicate this alloy has improved microstructural properties and resistance to dislocation formation compared with similar II-VI alloys, and should be further investigated for the detection of electromagnetic radiation.

Cobb, S. D.↗

BOREAS RSS-3 Reflectance Measured from a Helicopter-Mounted SE-590

The BOREAS RSS-3 team collected multiple remotely sensed data sets from the NASA UH-1 helicopter. This data set includes helicopter-based radiometric measurements of forested sites acquired during BOREAS made with an SE-590 processed to reflectance factors. The data used in this analysis were collected in 1994 during the three BOREAS IFCs at numerous tower and auxiliary sites in both the NSA and the SSA. The 15-degree FOV of the SE-590 yielded a ground resolution of approximately 79 m at the 300-m nominal altitude. The data are provided in tabular ASCII files.

Hall, Forrest G.↗

Exposing Hidden Parts of the SE Process: MBSE Patterns and Tools for Tracking and Traceability

An interesting benefit of applying Model-Based Systems Engineering (MBSE) is that the rigor and coordination intrinsic to MBSE forces us to apply Systems Engineering to our own traditional activities, processes, and products, which results in richer, more expressive models, more powerful reasoning, and a clearer and more effective Systems Engineering (SE) process. Our MBSE frameworks and languages contain semantic richness sufficient to describe our systems at any particular point in time, often with an emphasis on the description of the system at major milestones. This is unarguably a real asset. However, when we apply MBSE in service of missions that are in development, rapidly evolving, of a larger scale, and where interpersonal communication is a critical part of the design process, we discover that our frameworks and languages are still not quite rich enough to enable us to ask the kinds of questions and get the kinds of answers we want in order to address the concerns of day to day work. This paper will discuss some patterns and tools we have developed to help address some of the not-always-explicit SE concerns that we have identified through our MBSE work. Particularly, this paper will discuss flexible yet practical methods for defining and capturing maturity, workflow, and agreement traceability within our system models, extensible ways to perform and track model audits, and ways to report and interact with this knowledge in the context of MBSE applied to support NASA’s Europa Project.

Jackson, Maddalena↗

Exposing Hidden Parts of the SE Process: MBSE Patterns and Tools for Tracking and Traceability

An interesting benefit of applying Model-Based Systems Engineering (MBSE) is that the rigor and coordination intrinsic to MBSE forces us to apply Systems Engineering to our own traditional activities, processes, and products, which results in richer, more expressive models, more powerful reasoning, and a clearer and more effective Systems Engineering (SE) process. Our MBSE frameworks and languages contain semantic richness sufficient to describe our systems at any particular point in time, often with an emphasis on the description of the system at major milestones. This is unarguably a real asset. However, when we apply MBSE in service of missions that are in development, rapidly evolving, of a larger scale, and where interpersonal communication is a critical part of the design process, we discover that our frameworks and languages are still not quite rich enough to enable us to ask the kinds of questions and get the kinds of answers we want in order to address the concerns of day to day work. This paper will discuss some patterns and tools we have developed to help address some of the not-always-explicit SE concerns that we have identified through our MBSE work. Particularly, this paper will discuss flexible yet practical methods for defining and capturing maturity, workflow, and agreement traceability within our system models, extensible ways to perform and track model audits, and ways to report and interact with this knowledge in the context of MBSE applied to support NASA’s Europa Project

Jackson, Maddalena↗

Hexavalent Chrome Free Coatings for Electronics: Electromagnetic Interference (EMI) Shielding Effectiveness (SE)

Determine the suitability of trivalent chromium conversion coatings that meet the requirements of MIL-DTL-5541, Type II, for use in applications where high-frequency electrical performance is important. Evaluate the ability of hexavalent chrome free pretreated aluminum to form adequate EMI seals, and maintain that seal while being subjected to harsh environmental conditions. Assess the performance of trivalent chromium pretreatments against a known control hexavalent chrome pretreatment before and after they have been exposed to a set of environmental conditions. It is known that environmental testing causes a decrease in shielding effectiveness when hexavalent chrome pretreatments are used (Alodine 1200s). Need to determine how shielding effectiveness will be affected with the use of hexavalent chrome free pretreatments. Performance will be assessed by evaluating shielding effectiveness (SE) test data from a variety of test samples comprised of different aluminum types and/or conversion coatings. The formation of corrosion will be evaluated between the mating surfaces and gasket to assess the corrosion resistant properties of the pretreatments, comparing the hexavalent control to the hexavalent chrome free pretreatments.

hexavalent chrome free↗

Autonomous Control for Arbitrary Thruster Configurations and Mass Properties in Special Euclidean Group SE(3)

Most current methods for determining maneuvers and thrust firing sequences depend on explicit and predetermined commands generated by a combination of on-board systems and ground-based human-in-the-loop methods. For spacecraft and space structures with changing mass properties and thruster configurations, such as the Deep Space Gateway as it changes configurations throughout its lifetime, determining these commands can be time-consuming and computationally intensive. However, recent work within the Lie group SE(3) has offered ways of autonomously determining the location, power, precision, and capabilities of thrusters in any arbitrary position. Furthermore, a method for determining thruster firing sequences based on an arbitrary control input (both translational and rotational in a coupled, 6-element vector) and arbitrary thruster configurations has also recently been developed. When combining these methods, any spacecraft with any mass properties and thruster configurations can be understood in terms of controllability limits and thruster firing sequences can be generated quickly and with low computational load, thus extending the autonomous capabilities of deep space missions. In this work, this method is presented and explored in terms of convergence time to the desired pose. The capabilities of this method are also examined in the case of the Deep Space Gateway both in fully controllable configurations and uncontrollable configurations.

SE(3)↗