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At least 19 records

Additively Reinforced Thermoformable PETG Composite Sheets for Improved Structural Efficiency

Thermoforming of short-fiber reinforced thermoplastic sheets offers a viable pathway for producing lightweight composite components; however, inherent anisotropy in fiber-reinforced sheets can limit structural performance under multidirectional loading. In this work, short carbon fiber, glass fiber, and hybrid fiber–reinforced PETG sheets were evaluated as candidate feedstock materials for thermoforming, with flexural and tensile testing performed both along the primary fiber direction and in the off-axis orientation to establish baseline stiffness, strength, and anisotropy. As expected, short carbon fiber PETG exhibited the highest stiffness and strength in the primary fiber direction, while all systems showed reduced performance in the off-axis direction. This off-axis performance reduction provides clear justification for the use of additive reinforcement when such thermoformed sheets are intended for structural applications. The intended manufacturing sequence involves thermoforming the reinforced sheet first, followed by the application of additively manufactured lattice reinforcement; therefore, the reinforcement strategy does not impose limitations on sheet formability during thermoforming. Post-forming lattice reinforcement significantly reduced load-normalized displacement by approximately 95–99% relative to non-reinforced sheets and improved weight-normalized stiffness by ~70%. These findings demonstrate that geometry-driven additive reinforcement can effectively compensate for off-axis property reductions in thermoformed PETG composites, enabling enhanced multidirectional structural performance without compromising manufacturability.

Talabi, Isaac [ORNL] (ORCID:0000000340215594)↗

Methods of sheet metal production and sheet metal products produced thereby

Processes for producing sheet metal products by machining a solid metal body with a cutting tool in a single step to continuously produce a continuous bulk form from material obtained from the solid metal body, and without performing a hot rolling operation thereon, cold rolling the continuous bulk form to produce a sheet metal product. The machining step is a large-strain machining process capable of being directly performed on an as-cast ingot or other solid body to produce a continuous intermediate product that can be directly cold rolled without any intervening hot rolling operation, and optionally without homogenization or annealing.

Trumble, Kevin Paul↗

Damage evolution and ductile fracture of commercially-pure titanium sheets subjected to simple tension and cyclic bending under tension

This paper describes a study into the evolution of damage in commercial-purity titanium (CP–Ti) sheets subjected to cyclic bending under tension (CBT) and uniaxial tension (simple tension, ST). Sections were taken from sheets that were strained to various levels under both methods and were imaged using X-ray computed tomography (XCT) to reveal insights into the size, density, and distribution of microvoids in the sheets. Digital image correlation (DIC) was also used to observe the surface strain of CBT and ST sheets during testing. These results showed that elongation to failure (ETF) for CBT deformation is about 2.5× higher than for ST, local longitudinal strains in the bulk of the CBT sample are around 1.3× higher than the peak strain in the ST necked region, and 1.7× higher in the localized region of CBT failure. It was found that the volume-density of voids in both sheets followed a similar exponential increase with strain, reaching nearly 45× higher in the CBT than the ST sheets before the onset of failure, mainly due to the higher strain levels achieved. A higher volume density of voids developed in the center of sheets at high levels of strain, for both processes, with the density in the sheet center becoming approximately double that found near the edges. Scanning electron microscopy (SEM) was used to examine the fracture surface of CBT and ST sheets after failure. The observations are presented and discussed highlighting the CBT process as effective to delay ductile fracture of the CP-Ti sheets.

Commercially pure titanium↗

A planar-sheet nongraphitic zero-bandgap sp 2 carbon phase made by the low-temperature reaction of γ-graphyne

The highest sheet symmetry form of graphyne, with one triple bond between each neighboring hexagon in graphene, irreversibly transforms exothermically at ambient pressure and low temperatures into a nongraphitic, planar-sheet, zero-bandgap phase consisting of intrasheet-bonded sp 2 carbons. The synthesis of this sp 2 carbon phase is demonstrated, and other carbon phases are described for possible future synthesis from graphyne without breaking graphyne bonds. While measurements and theory indicate that the reacting graphyne becomes nonplanar because of sheet wrinkling produced by dimensional mismatch between reacted and nonreacted sheet regions, sheet planarity is regained when the reaction is complete. Although the observed elimination of triple bonds to make parallel planar sp 2 carbon sheets likely requires ordered transformation within each sheet, diffraction data for reacted multisheet stacks indicate that the relative lateral positions of neighboring sheets are disordered, as predicted, since no crystalline diffraction peak (other than for the intersheet spacing) is observed.

Aliev, Ali E. (ORCID:0000000300349707)↗

Optimizing Bendability and Hardness of Age-Hardenable Aluminum Sheets through Local Thermo-Mechanical Processing

This paper introduces a novel thermo-mechanical process to modify the local mechanical properties of 6xxx aluminum (Al-Mg-Si-Cu) alloy sheets. In this process, two pairs of rollers travel along the length of a sheet while locally bending and unbending it so that the final shape and thickness of the sheet remains unchanged. Room temperature bending/unbending (B/U) produces a deformation gradient through thickness and local hardening in both T4 and T6 sheets (with 41% and 18% greater Vickers hardness, respectively). High temperature bending/unbending performed at ~ 500°C via induction heating, produces significant improvements in local formability as measured by bend testing. Formability levels equivalent to the as-received T4 temper are achieved within the processed zones of T6 sheets with bend angles of ~ 150°, without disturbing the T6 temper in the remainder of the sheet. Finite element simulations and characterization explained the mechanical property improvements and the heterogenous microstructure with weakened Cube texture. Due to its similarity with the roller hemming process, and its compact dimensions, the apparatus developed for B/U has the potential for seamless integration with roller hemming robots to selectively process high strength aluminum sheet materials within mass-production settings.

Efe, Mert [BATTELLE (PACIFIC NW LAB)]↗

The Nonlinear and Distinct Responses of Ocean Heat Content and Anthropogenic Carbon to Ice Sheet Freshwater Discharge in a Warming Climate

Anthropogenic climate change will drive extensive mass loss across both the Antarctic (AIS) and Greenland Ice Sheets (GrIS), with the potential for global climate system feedbacks, especially in polar regions. Historically, the high-latitude North Atlantic and Southern Ocean have been critical regions for anthropogenic heat and carbon uptake, but our understanding of how this uptake will be altered by future freshwater discharge is incomplete. We assess each ice sheet's impact on global ocean anthropogenic heat and carbon storage for a high-emission scenario over the 21 st -century using a coupled Earth system model. We explore the impact of contemporaneous mass loss from both ice sheets on anthropogenic heat and carbon storage and quantify their linear and nonlinear contributions. Notably, added freshwater reduces ocean heat and carbon storage by 2,100, and the sum of individual freshwater effects differ from those induced by simultaneous freshwater discharge from both ice sheets. Combined AIS and GrIS freshwater engenders distinct anthropogenic storage anomalies—particularly in the high-latitude Southern Ocean and North Atlantic. From 2080 to 2100, GrIS freshwater exerts primary control on the temporal evolution of global ocean heat storage, while global ocean carbon storage is modulated by the linear AIS and GrIS freshwater impacts. Nonlinear impacts of simultaneous ice sheet discharge have a non-negligible contribution to the evolution of global ocean heat storage. Further, anthropogenic heat changes are realized more quickly in response to ice sheet discharge than anthropogenic carbon. Our results highlight the need to incorporate both ice sheets actively in climate models to accurately project future global climate.

Gorte, Tessa↗

East Antarctic Ice Sheet variability in the central Transantarctic Mountains since the mid Miocene

The response of the East Antarctic Ice Sheet to warmer-than-present climate conditions has direct implications for projections of future sea level, ocean circulation, and global radiative forcing. Nonetheless, it remains uncertain whether the ice sheet is likely to undergo net loss due to amplified melting coupled with dynamic instabilities or whether such losses will be balanced, or even offset, by enhanced accumulation under a higher-precipitation regime. The glacial depositional record from the central Transantarctic Mountains (TAM) provides a robust geologic means to reconstruct the past behaviour of the East Antarctic Ice Sheet, including during periods thought to have been warmer than today, such as the mid-Pliocene Warm Period (~3.3–3.0 Ma). This study describes a new surface-exposure-dated moraine record from Otway Massif in the central TAM spanning the last ~9 Myr and synthesises these data in the context of previously published moraine chronologies constrained with cosmogenic nuclides. The resulting record, although fragmentary, represents the majority of direct and unambiguous terrestrial evidence for the existence and size of the East Antarctic Ice Sheet during the last 14 Myr, and it thus provides new insight into the long-term relationship between the ice sheet and global climate. At face value, the existing TAM moraine record does not exhibit a clear signature of the mid-Pliocene Warm Period, thus precluding a definitive verdict on the East Antarctic Ice Sheet's response to this event. In contrast, an apparent hiatus in moraine deposition both at Otway Massif and the neighbouring Roberts Massif suggests that the ice sheet surface in the central TAM was potentially lower than present during the late Miocene and earliest Pliocene.

58 GEOSCIENCES↗

ISMIP6-based Antarctic projections to 2100: simulations with the BISICLES ice sheet model

The contribution of the Antarctic Ice Sheet is one of the most uncertain components of sea level rise to 2100. Ice sheet models are the primary tool for projecting future sea level contribution from continental ice sheets. The Ice Sheet Model Intercomparison for the Coupled Model Intercomparison Phase 6 (ISMIP6) provided projections of the ice sheet contribution to sea level over the 21st century, quantifying uncertainty due to ice sheet model, climate model, emission scenario, and uncertain parameters. We present simulations following the ISMIP6 framework with the BISICLES ice sheet model and new experiments extending the ISMIP6 protocol to more comprehensively sample uncertainties in future climate, ice shelf sensitivity to ocean melting, and their interactions. These results contributed to the land ice projections of Edwards et al. (2021), which formed the basis of sea level projections for the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (AR6). Our experiments show the important interplay between surface mass balance processes and ocean-driven melt in determining Antarctic sea level contribution. Under higher-warming scenarios, high accumulation offsets more ocean-driven mass loss when sensitivity to ocean-driven melt is low. Conversely, we show that when sensitivity to ocean warming is high, ocean melting drives increased mass loss despite high accumulation. Overall, we simulate a sea level contribution range across our experiments from 2 to 178 mm. Finally, we show that collapse of ice shelves due to surface warming increases sea level contribution by 25 mm relative to the no-collapse experiments, for both moderate and high sensitivity of ice shelf melting to ocean forcing.

54 ENVIRONMENTAL SCIENCES↗

Förster Resonance Energy Transfer and Enhanced Emission in Cs 4 PbBr 6 Nanocrystals Encapsulated in Silicon Nano-Sheets for Perovskite Light Emitting Diode Applications

Encapsulating Cs 4 PbBr 6 quantum dots in silicon nano-sheets not only stabilizes the halide perovskite, but also takes advantage of the nano-sheet for a compatible integration with the traditional silicon semiconductor. Here, we report the preparation of un-passivated Cs 4 PbBr 6 ellipsoidal nanocrystals and pseudo-spherical quantum dots in silicon nano-sheets and their enhanced photoluminescence (PL). For a sample with low concentrations of quantum dots in silicon nano-sheets, the emission from Cs 4 PbBr 6 pseudo-spherical quantum dots is quenched and is dominated with Pb 2+ ion/silicene emission, which is very stable during the whole measurement period. For a high concentration of Cs 4 PbBr 6 ellipsoidal nanocrystals in silicon nano-sheets, we have observed Förster resonance energy transfer with up to 87% efficiency through the oscillation of two PL peaks when UV excitation switches between on and off, using recorded video and PL lifetime measurements. In an area of a non-uniform sample containing both ellipsoidal nanocrystals and pseudo-spherical quantum dots, where Pb 2+ ion/silicene emissions, broadband emissions from quantum dots, and bandgap edge emissions (515 nm) appear, the 515 nm peak intensity increases five times over 30 min of UV excitation, probably due to a photon recycling effect. This irradiated sample has been stable for one year of ambient storage. Cs 4 PbBr 6 quantum dots encapsulated in silicon nano-sheets can lead to applications of halide perovskite light emitting diodes (PeLEDs) and integration with traditional semiconductor materials.

36 MATERIALS SCIENCE↗

Hierarchical domain structures in buckled ferroelectric free sheets

Flat elastic sheets tend to display wrinkles and folds. From pieces of clothing down to two-dimensional crystals, these corrugations appear in response to strain generated by sheet compression or stretching, thermal or mechanical mismatch with other elastic layers, or surface tension. Extensively studied in metals, polymers and, — more recently — in van der Waals exfoliated layers, with the advent of thin single crystal freestanding films of complex oxides, researchers are now paying attention to novel microstructural effects induced by bending ferroelectric-ferroelastics, where polarization is strongly coupled to lattice deformation. Here we show that wrinkle undulations in BaTiO3 sheets bonded to a viscoelastic substrate transform into a buckle delamination geometry when transferred onto a rigid substrate. Using spatially resolved techniques at different scales (Raman, scanning probe and electron microscopy), we show how these delaminations in the free BaTiO3 sheets display a self-organization of ferroelastic domains along the buckle profile that strongly differs from the more studied sinusoidal wrinkle geometry. Moreover, we disclose the hierarchical distribution of a secondary set of domains induced by the misalignment of these folding structures from the preferred in-plane crystallographic orientations. Our results disclose the relevance of the morphology and orientation of buckling instabilities in ferroelectric free sheets, for the stabilization of different domain structures, pointing to new routes for domain engineering of ferroelectrics in flexible oxide sheets.

36 MATERIALS SCIENCE↗

Beta-dependent Properties of Solar Wind Current Sheets at 1 au

We utilize plasma turbulence in interplanetary coronal mass ejections as a natural laboratory to analyze more than 4600 current sheets observed over a broad range of electron and proton beta values, 10 −2 ≲ β e ≲ 10 and 10 −3 ≲ β p ≲ 10. The analysis shows that the shear angle Δθ and the thickness λ CS of the current sheets depend on both electron and proton beta. Specifically, the dependencies on electron beta are Δθ ≈ 12.6° $β^{0.41}_{e}$ and, λ CS /λ p ≈ 1.9 $β^{0.26}_{e}$ where λ p is the local proton inertial length. We argue that the beta dependence of the shear angle is an intrinsic feature of solar wind turbulence arising from the natural correlation between turbulence intensity and plasma beta. In contrast, the beta dependence of current sheet scales is likely a general characteristic of plasma turbulence. According to recent theory, current sheets formed in turbulence are disrupted by the electron tearing instability once their thickness is smaller than a critical scale. We demonstrate that normalizing the thickness of current sheets by this critical scale eliminates the dependence on beta across the entire range of plasma beta. This observation not only supports the theory suggesting that current sheets mediate the transition from the inertial to the kinetic cascade through the electron tearing instability, but also demonstrates the plausibility of similar processes in astrophysical plasma. The presented results also indicate that the theory may be applicable beyond its formal limits, m e /m i ≪ β ≪ 1.

79 ASTRONOMY AND ASTROPHYSICS↗

Experimental design for the Marine Ice Sheet–Ocean Model Intercomparison Project – phase 2 (MISOMIP2)

The Marine Ice Sheet–Ocean Model Intercomparison Project – phase 2 (MISOMIP2) is a natural progression of previous and ongoing model intercomparison exercises that have focused on the simulation of ice-sheet and ocean processes in Antarctica. The previous exercises motivate the move towards realistic configurations, as well as more diverse model parameters and resolutions. The main objective of MISOMIP2 is to investigate the performance of existing ocean and coupled ice-sheet–ocean models in a range of Antarctic environments through comparisons to observational data. We will assess the status of ice-sheet–ocean modelling as a community and identify common characteristics of models that are best able to capture observed features. As models are highly tuned based on present-day data, we will also compare their sensitivity to prescribed abrupt atmospheric perturbations leading to either very warm or slightly warmer ocean conditions compared to the present day. The approach of MISOMIP2 is to welcome contributions of models as they are, including global and regional configurations, but we request standardized variables and common grids for the outputs. We target the analysis at two specific regions, the Amundsen Sea and the Weddell Sea, since they describe two different ocean environments and have been relatively well observed compared to other areas of Antarctica. An observational “MIPkit” synthesizing existing ocean and ice-sheet observations for a common period is provided to evaluate ocean and ice-sheet models in these two regions.

58 GEOSCIENCES↗

Solid face sheets enable lattice metamaterials to withstand high-amplitude impulsive loading without yielding

Owing to their ability to provide tunable mechanical responses, lattice materials are frequently studied to elucidate their response to static and dynamic loads. However, these roles are typically in opposition: static loads must be supported sufficiently far away from the onset of buckling or yielding, whereas dynamic loads are typically ameliorated by crushing of the lattice, which provides excellent energy-absorption due to the large plastic deformation accompanying densification. In contrast, this work considers the octet truss as an exemplar topology, in a structural role where it must simultaneously support static loads while enduring high-amplitude impulsive loads. This study focuses on the ability to withstand impulsive loads without yielding, an essential prerequisite to enduring dual loading. Computational studies using the ALE3D hydrocode were performed to examine the response of the octet truss under a short temporal width impulse shape associated with laser-driven shocks. A key finding was that covering the lattice with a solid face sheet and treating this face sheet thickness as a design variable allows the Taylor-like pulse to be attenuated prior to entering the weaker lattice, at the cost of added mass up front. Experimental validation was accomplished by laser-driven shock testing, using octet trusses printed out of Ti-5Al-5V-5Mo-3Cr. The results show that for a given quantity of mass, the attenuation is maximized when as much mass as possible is moved into the face sheet, leaving a more slender lattice structure. The effect of placing mass in the face sheet rather than lattice beams dominates the effect of relative density, to the point where a low-mass structure with most of the mass concentrated in the face sheet can outperform a high-mass structure with most of the mass in the lattice. Finally, by further understanding the propagation of short pulse width waves within under-dense structures, this study expand the domain of applicability of such structures, including lattice materials, to challenging dual-loading regimes spanning decades of strain rates.

36 MATERIALS SCIENCE↗

Antarctic ice sheet model comparison with uncurated geological constraints shows that higher spatial resolution improves deglacial reconstructions

Accurately reconstructing past changes to the shape and volume of the Antarctic ice sheet relies on the use of physically based and thus internally consistent ice sheet modeling, benchmarked against spatially limited geologic data. The challenge in model benchmarking against geologic data is diagnosing whether model-data misfits are the result of an inadequate model, inherently noisy or biased geologic data, and/or incorrect association between modeled quantities and geologic observations. In this work we address this challenge by (i) the development and use of a new model-data evaluation framework applied to an uncurated data set of geologic constraints, and (ii) nested high-spatial-resolution modeling designed to test the hypothesis that model resolution is an important limitation in matching geologic data. While previous approaches to model benchmarking employed highly curated datasets, our approach applies an automated screening and quality control algorithm to an uncurated public dataset of geochronological observations (specifically, cosmogenic-nuclide exposure-age measurements from glacial deposits in ice-free areas). This optimizes data utilization by including more geological constraints, reduces potential interpretive bias, and allows unsupervised assimilation of new data as they are collected. We also incorporate a nested model framework in which high-resolution domains are downscaled from a continent-wide ice sheet model. We highlight the application of this framework by applying these methods to a small ensemble of deglacial ice-sheet model simulations, and demonstrate that the nested approach improves the ability of model simulations to match exposure age data collected from areas of complex topography and ice flow. We develop a range of diagnostic model-data comparison metrics to provide more insight into model performance than possible from a single-valued misfit statistic, showing that different metrics capture different aspects of ice sheet deflation.

Geosciences↗

Improved Understanding of Multicentury Greenland Ice Sheet Response to Strong Warming in the Coupled CESM2‐CISM2 With Regional Grid Refinement

The simulation of ice sheet‐climate interactions, such as surface mass balance fluxes, is sensitive to model grid resolution. Here we simulate the multi‐century evolution of the Greenland Ice Sheet (GrIS) and its interaction with the climate using the Community Earth System Model version 2.2 (CESM2.2) including an interactive GrIS component (the Community Ice Sheet Model v2.1 [CISM2.1]) under an idealized warming scenario (atmospheric CO 2 increases by 1% yr -1 until quadrupling the pre‐industrial level and then is held fixed). A variable‐resolution (VR) grid with 1/4° regional refinement over the broader Arctic and 1° resolution elsewhere is applied to the atmosphere and land components, and the results are compared with conventional 1° lat‐lon grid simulations to investigate the impact of grid refinement. Compared with the 1° runs, the VR run features a slower rate of surface melt, especially over the western and northern GrIS, where the ice surface slopes gently toward the periphery. This difference pattern originates primarily from higher snow albedo and, thus, weaker albedo feedback in the VR run. The VR grid better captures the CISM ice sheet topography by reducing elevation discrepancies between CAM and CISM and is, therefore, less reliant on the downscaling algorithm, which is known to underestimate albedo gradients. The sea level rise contribution from the GrIS in the VR run is 53 mm by year 150 and 831 mm by year 350, approximately 40% and 20% less than that of the 1° runs, respectively.

Earth System Model↗

Improving Projections of Antarctic Ice Sheet Contribution to Sea‐Level Change Through 2300 by Capturing Gravitational, Rotational, and Deformational Effects

Ice-mass change induces regionally varying patterns of sea-level change due to gravitational, rotational, and deformational (GRD) effects, which in turn influence marine-based ice stability in Antarctica. For improved projection of the Antarctic Ice Sheet (AIS), there is a need for including GRD effects in modeling and improving understanding of basin-by-basin sensitivity of ice evolution to GRD effects under a range of climate scenarios. We couple a high-resolution, higher-order ice-sheet model with a 1D global sea-level model that fully captures GRD effects, and simulate ice evolution in Antarctica under the Ice Sheet Model Intercomparison Project for CMIP6 experiments. We perform two sets of coupled simulations incorporating 1D Maxwell solid Earth structure suitable for West and East Antarctica and show that the Amundsen Sea Embayment (ASE) in West Antarctica has the highest sensitivity to GRD effects—in high-emission scenarios, grounding-line retreat accelerates by hundreds of kilometers by 2300 without GRD effects, but GRD effects delay this retreat on a timescale of decades. However, we find that delay times do not show a clear relationship to the strength of climate forcing alone. Furthermore, GRD effects can influence ice-sheet dynamics more than the choice of climate model for a given emissions scenario. In contrast, East Antarctica exhibits minimal sensitivity to GRD effects throughout the study period. These findings underscore the critical role of GRD effects in shaping future West AIS evolution, highlighting the importance of constraining the regional 3D Earth structure and bed topography in West Antarctica, particularly the ASE.

58 GEOSCIENCES↗

Self‐Propelling Macroscale Sheets Powered by Enzyme Pumps

Nanoscale enzymes anchored to surfaces act as chemical pumps by converting chemical energy released from enzymatic reactions into spontaneous fluid flow that propels entrained nano‐ and microparticles. Enzymatic pumps are biocompatible, highly selective, and display unique substrate specificity. Utilizing these pumps to trigger self‐propelled motion on the macroscale has, however, constituted a significant challenge and thus prevented their adaptation in macroscopic fluidic devices and soft robotics. Using experiments and simulations, we herein show that enzymatic pumps can drive centimeter‐scale polymer sheets along directed linear paths and rotational trajectories. In these studies, the sheets are confined to the air/water interface. With the addition of appropriate substrate, the asymmetric enzymatic coating on the sheets induces chemically driven, buoyancy flows that controllably propel the sheet's motion on the air/water interface. The directionality and speed of the motion can be tailored by changing the pattern of the enzymatic coating, type of enzyme, and nature and concentration of the substrate. This work highlights the utility of biocompatible enzymes for generating motion in macroscale fluidic devices and robotics and indicates their potential utility for in vivo applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗