Materials Data on SOF2 by Materials Project
SOF2 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight thionyl fluoride molecules. S4+ is bonded in a trigonal non-coplanar geometry to one O2- and two F1- atoms. The S–O bond length is 1.44 Å. Both S–F bond lengths are 1.63 Å. O2- is bonded in a single-bond geometry to one S4+ atom. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one S4+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one S4+ atom.
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