Soup to Nuts: MOFs for Production Transport and Storage of Fuels.
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We propose physically reasonable systems capable of avoiding ergodicity at infinite time in the thermodynamic limit, even with generic perturbations and when coupled to a heat bath. In two dimensions, the rainbow loop soup has (stretched) exponentially numerous absolutely stable nonergodic states with diverging energy but vanishing energy density. In three dimensions the rainbow membrane soup has (stretched) exponentially numerous nonergodic states with diverging energy barriers, leading to infinite-time robust ergodicity breaking that even survives coupling to a nonzero temperature heat bath. We describe our results in the language of exact emergent symmetries and demonstrate how the systems avoid common instabilities. Furthermore, our construction naturally connects to quantum dimer models, topologically ordered systems, the group word construction, and Hamiltonians whose low-energy eigenstates exhibit anomalous entanglement entropy.
This work reviews the advancements and prospects of liquid cell transmission electron microscopy (TEM) imaging and analysis methods in understanding the nucleation, growth, etching, and assembly dynamics of nanocrystals. The bonding of atoms into nanoscale crystallites produces materials with nonadditive properties unique to their size and geometry. The recent application of in situ liquid cell TEM to nanocrystal development has initiated a paradigm shift, (1) from trial-and-error synthesis to a mechanistic understanding of the “synthetic reactions” responsible for the emergence of crystallites from a disordered soup of reactive species (e.g., ions, atoms, molecules) and shape-defined growth or etching; and (2) from post-processing characterization of the nanocrystals’ superlattice assemblies to in situ imaging and mapping of the fundamental interactions and energy landscape governing their collective phase behaviors. Imaging nanocrystal formation and assembly processes on the single-particle level in solution immediately impacts many existing fields, including materials science, nanochemistry, colloidal science, biology, environmental science, electrochemistry, mineralization, soft condensed-matter physics, and device fabrication.
Third Lab Director Harold Agnew’s barbecue sauce. Applesauce meatballs from the wife of Nobel laureate Frederick Reines. Two different recipes for chopped liver. And dozens more for soups, salads, meats, breads, desserts, drinks – plus a big taste of the past. What’s Cooking was published in Los Alamos in 1955 and recently discovered in a used bookstore in Santa Fe by Lab physicist Roseanne Cheng. “It was buried and on a forgotten shelf,” Cheng said. “I started flipping through it and I couldn’t believe all the (recognizable) names inside.” The wives of Lab staff, including prominent scientists, and Los Alamos community members had submitted recipes to the Los Alamos Chapter of Hadassah, which compiled them and printed the book.
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