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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Solid‐State Prealkylation of Electrode Architectures (SPEAR): Direct Control of Prelithiation Levels in Silicon Anodes and Electrochemical Cycling

The Solid-state Prealkylation of Electrode ARchitectures (SPEAR) is different than traditional electrochemical prealkylation processes. Through SPEAR, alkylation is driven by solid-state diffusion without the simultaneous SEI formation concomitant with polarization. Here, we investigate the prelithiation of 80 wt. % Si-based anodes to varying amounts (up to Li 1.38 Si) to understand the trade-off between improved Li capacity and expansion-induced stress. Through dilatometry, we found that solid-state lithiation led to filling of the electrode pores through silicon expansion. This swelling changed the SEI formation process and accessibility of the silicon compared to an electrochemically lithiated electrode. Indeed, optimal prelithiation to Li 0.82 Si increases the initial C/3 cycling capacity post-SEI formation up to 43%, consistent with deeper Si activation through the electrode bulk. Prelithiation and cycling cells prelithiated beyond Li 0.82 Si results in a state of charge (SOC) close to 100% which facilitates parasitic degradation mechanisms and volume expansion of the Si electrode. The results demonstrate a pathway to modify silicon activation/SEI formation to enable high-energy electrodes.

Musgrove, Amanda L. [Oak Ridge National Laboratory↗

Omen: identifying potential spear-phishing targets before the email is sent.

We present the results of a two year project focused on a common social engineering attack method called "spear phishing". In a spear phishing attack, the user receives an email with information specifically focused on the user. This email contains either a malware-laced attachment or a link to download the malware that has been disguised as a useful program. Spear phishing attacks have been one of the most effective avenues for attackers to gain initial entry into a target network. This project focused on a proactive approach to spear phishing. To create an effective, user-specific spear phishing email, the attacker must research the intended recipient. We believe that much of the information used by the attacker is provided by the target organization's own external website. Thus when researching potential targets, the attacker leaves signs of his research in the webserver's logs. We created tools and visualizations to improve cybersecurity analysts' abilities to quickly understand a visitor's visit patterns and interests. Given these suspicious visitors and log-parsing tools, analysts can more quickly identify truly suspicious visitors, search for potential spear-phishing targeted users, and improve security around those users before the spear phishing email is sent.

Wendt, Jeremy Daniel.↗

An Introduction to SPEARS (Spectrum Education Awareness)

This presentation provides an overview of the SPectrum Education AwaRenesS (SPEARS) initiative developed by the NASA Spectrum Office under HEO/SCaN. SPEARS is a strategic initiative that is comprised of fourteen (14) activities/tasks targeted for various stakeholders within and external to NASA and from the spectrum and non-spectrum communities. These activities will also facilitate fostering partnerships and enhance the regulatory and policy understanding with international spectrum regulators and other space agencies. Further, SPEARS will institute several activities geared to promote spectrum management and to gain the interest of the next and future generations of spectrum managers, through Science, Technology, Engineering, and Mathematics (STEM) outreach.

spectrum training↗

SPEARS: A Database-Invariant Spectral modeling API

The Spectral Physics Environment for Advanced Remote Sensing (SPEARS) application programming interface (API) is a Python-based, line-by-line, local thermal equilibrium (LTE) spectral modeling code which is optimized for simultaneously synthesizing optical spectra from any combination of fundamental spectroscopic databases. In this article, we contribute two novel spectral modeling techniques to the scientific literature. First we describe how SPEARS integrates a physics-based collisional model for calculating pressure broadening in the absence of available broadening coefficients. With this collisional model implementation, a generalized approach to fundamental spectroscopic databases can be achieved across multiple databases. We also detail our adaptive grid mesh algorithm developed to make the code scalable for simulating large spectral bandwidths at high spectral fidelity using intuitive grid parameters. Here, we present comparisons to other modeling tools, experiments, and provide a discussion on the SPEARS user interface.

47 OTHER INSTRUMENTATION↗

Non Linear Beam Dynamics Studies at SPEAR

The frequency map analysis of a Hamiltonian system recently introduced to accelerators physics in combination with turn-by-turn phase space measurements opens new experimental opportunities for studying non linear dynamic in storage rings. In this paper we report on the experimental program at SPEAR having the goal of measuring the frequency map of the machine. In this paper we discuss the accuracy of the instantaneous tune extraction from experimental data and demonstrate the possibility of the frequency map measurement. The instantaneous tune extraction technique can be applied to experimental tracking data with reasonable accuracy. Frequency map can be experimentally determined using the existing turn-by-turn phase space measurement techniques and NAFF instantaneous tune extraction.

43 PARTICLE ACCELERATORS↗

Parasitic Cavities Losses in SPEAR-2

In PEP the large number of particles in a bunch, together with the small bunch length, may cause grievous energy loss from the beam to parasitic modes in the accelerating cavities. I have recently tried to estimate the parasitic cavity in PEP, based on a paper of Keil and I have obtained the result that the loss to parasitic modes will be about 10 MeV per particle per revolution for a bunch length of about 10 cm. In this note, I bring together some of the considerations that might bear on an experimental investigation of the loss using SPEAR-2.

43 PARTICLE ACCELERATORS↗

Study of the Power Supply Ripple Effect on teh Dynamics at SPEAR

For long term stability analysis time variation of tunes is important. We have proposed and tested a technique for measuring the magnitude of this variation. This was made possible by using tune extraction algorithms that require small number of turns thus giving an instantaneous tune of the machine. In this paper we demonstrate the measured effect of the tune modulation with 60 Hz power supplies ripple, power line interference from SLAC linac operating at 30 Hz repetition rate, and nonperiodic variation.

43 PARTICLE ACCELERATORS↗

Spaceborne Earth Applications Ranging system (SPEAR)

A technique is discussed for the accurate (i.e. to within fractions of cm/yr) detection of earth surface motions utilizing the latest space technology. It is shown that over a six day period and assuming a 50% cloud cover (as experienced over the last few years of laser operation) utilizing spaceborne precision ranging systems, intersite distances on the order of 5 to 15 km can be determined in the vertical and horizontal components with errors in the 0.5 to 1.5 cm range. These errors are almost independent of ground survey errors up to 0.25 meters and orbit errors up to 200 meters. A spaceborne laser ranging system is assumed to range simultaneously to two or more ground emplaced retroreflectors. The fundamental advantage derived from simultaneous ranging is the elimination to first order of errors due to the system. This means elimination of bias errors in the ranging system, errors due to propagation effects, and errors associated with the spacecraft's motion in its orbit.

Vonbun, F. O.↗

SPEAR-1: An experiment to measure current collection in the ionosphere by high voltage biased conductors

An experiment is described in which a high electrical potential difference, up to 45 kV, was applied between deployed conducting spheres and a sounding rocket in the ionosphere. Measurements were made of the applied voltage and the resulting currents for each of 24 applications of different high potentials. In addition, diagnostic measurements of optical emissions in the vicinity of the spheres, energetic particle flow to the sounding rocket, dc electric field and wave data were made. The ambient plasma and neutral environments were measured by a Langmuir probe and a cold cathode neutral ionization gauge, respectively. The payload is described and examples of the measured current and voltage characteristics are presented. The characteristics of the measured currents are discussed in terms of the diagnostic measurements and the in-situ measurements of the vehicle environment. In general, it was found that the currents observed were at a level typical of magnetically limited currents from the ionospheric plasma for potentials less than 12 kV, and slightly higher for larger potentials. However, due to the failure to expose the plasma contactor, the vehicle sheath modified the sphere sheaths and made comparisons with the analytic models of Langmuir-Blodgett and Parker-Murphy less meaningful. Examples of localized enhancements of ambient gas density resulting from the operation of the attitude control system thrusters (cold nitrogen) were obtained. Current measurements and optical data indicated localized discharges due to enhanced gas density that reduced the vehicle-ionosphere impedance.

Raitt, W. John↗