Determination of nitrogen, oxygen, and hydrogen by spark-source mass spectrography.
Nitrogen, oxygen and hydrogen determined by spark-source mass spectrography, noting reduction of instrument blank levels
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Nitrogen, oxygen and hydrogen determined by spark-source mass spectrography, noting reduction of instrument blank levels
High resolution mass spectrography using AgBr photographic plates as ion detectors for organic chemical problems
The use of a Kron electrographic detector for wide-field, narrow-band imagery of faint emission nebulosity in the near-UV and visual (3100-6000 A) wavelength interval is described. As an example of the photometric quality of the imagery and of the sensitivity of the instrumentation to diffuse, low-contrast objects, imagery of the Cygnus Loop supernova remnant in the high excitation forbidden line of Ne V 3426 A is presented. In addition, a program to develop electrographic detectors which use cesium telluride photocathodes for broad-band imagery and spectrography in the middle-UV (1650-3100 A) wavelength range is described.
The latest results in the NRL program of far-UV electrographic camera development, and application of these cameras to astrophysical and upper-atmospheric investigations, are presented. A new large electrographic Schmidt camera, of 15 cm aperture and f/2 focal ratio, has been successfully used in two sounding rocket flights, one for direct imagery in the 1230-2000 A wavelength range and the second for objective spectrography in the 950-2000 A range, of stars and nebulae in the Cygnus region of the sky. The camera has an 11 deg field of view and better than 30 arcsec resolution (2 A spectral resolution with 600 line/mm objective grating). A nebular spectrograph, based on a microchannel-intensified electrographic Schmidt camera, is the payload of a May 1979 rocket flight. It will reach emission line features as faint as 5 Rayleighs in 100 second exposures in the 1050-2000 A range, with 5 A spectral resolution.
Emission spectrographic method determines trace amounts of inorganic impurities in potable water. The capability of this innovation should arouse considerable interest among plant biologists, chemists working in organic synthesis, and pathologists.
The flash photolysis of hydrogen iodide in the presence of nitrous oxide, carbon dioxide, and water has been investigated by kinetic spectroscopy. Although the fraction of hydrogen iodide dissociated was very large, the only observable intermediate was imidogen. It was demonstrated that the rapid removal of imidogen and the apparent absence of hydroxyl radicals in each case is a result of the following two reactions, respectively: (1) NH + HI yields NH2 + I; and (2) OH + HI yields H2O + I.
Single-crystalline thin films of copper were oxidized at an isothermal temperature of 425 C and at an oxygen partial pressure of .005 Torr in situ in a high-resolution electron microscope. The specimens were prepared by epitaxial vapor deposition onto polished 100 and 110 faces of rocksalt and mounted in a hot stage inside an ultra-high-vacuum specimen chamber of the microscope. Large amounts of sulfur, carbon, and oxygen were detected by Auger electron spectroscopy on the surface of the as-received films and were removed in situ by ion-sputter etching immediately prior to the oxidation. The nucleation and growth characteristics of Cu2O on Cu were studied. Results show that neither stacking faults nor dislocations are associated with the Cu2O nucleation sites. The growth of Cu2O nuclei is linear with time. The experimental findings, including results from oxygen dissolution experiments and from repetitive oxidation-reduction-oxidation sequences, fit well into the framework of an oxidation process involving (a) the formation of a surface-charge layer, (b) oxygen saturation in the metal and (c) nucleation, followed by surface diffusion of oxygen and bulk diffusion of copper for lateral and vertical oxide growth, respectively.
Ion acceleration transverse to the magnetic field in the topside ionosphere was investigated. Transverse acceleration is believed to be responsible for the upward-moving conical ion distributions commonly observed along auroral field lines at altitudes from several hundred to several thousand kilometers. Of primary concern in this investigation is the extent of these conic events in space and time. Theoretical predictions indicate very rapid initial heating rates, depending on the ion species. These same theories predict that the events will occur within a narrow vertical region of only a few hundred kilometers. Thus an instrument with very high spatial and temporal resolution was required; further, since different heating rates were predicted for different ions, it was necessary to obtain composition as well as velocity space distributions. The fast ion mass spectrometer (FIMS) was designed to meet these criteria. This instrument and its operation is discussed.
X-ray collectors and detectors evaluated for use as spectrography experiment in Orbiting Astronomical Observatory /OAO/
Spectrography of gegenschein and indications that earth has gaseous emanation of matter similar to comets
Impurity analysis of nonconductors and gases by spark-source mass spectrography techniques
Noncircular motions of ionized gas in M51 and NGC 5195 spiral galaxies, using spectrography
Powdered or densified nonconductive ceramic materials analyzed by spark source mass spectrography based on use of conducting probe
Mass spectrometer, spectrography, and other electronic instrumentation development
Lunar ground data for interpretation of AES ORBITAL experiments such as electromagnetic radiation monitoring, photographic data evaluation, spectrography, etc
IR spectrography applied to Mars biological studies, discussing organic IR radiation absorption and emission mechanisms
High vacuum UV reflectance of opaque iridium overcoated with thin aluminum film, noting possible application in satellite spectrography