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At least 19 records

Spectrophotometry of comets at optical wavelengths

Techniques for spectrophotometry of comets are discussed, and results are reviewed for line and continuum spectrophotometry of comets at optical wavelengths. The techniques considered include photographic spectroscopy and spectrophotometry, photoelectric spectrophotometry, and methods based on the use of image dissector scanners, Fourier-transform instruments, and Fabry-Perot spectrometers. Results are summarized for the study of cometary emission features due to C2, CN, CH, OH, NH, C3, NH2, O, H, CO(plus), and H2O(plus). Relative abundances of various species in comets are examined, along with continuum spectrophotometry of the nuclei, comas, and tails of comets.

Ahearn, M. F.

Optical spectrophotometry of comet Tempel 2 far from the sun

With the advent of mission planning for spacecraft encounters with comets in the 1980s, the lack of basic data on cometary nuclei has become quite apparent and a real problem. More effort is needed on all comets, with special attention given to probable space flight targets such as Tempel 2. The paper presents medium-spectral-resolution spectrophotometry of P/Tempel 2, made at heliocentric distances of 2.66 and 3.02 AU on two dates in 1978. It is shown that optical spectrophotometry of comet Tempel 2 near 3 AU heliocentric distance places strict limits on its activity, the modeled CN production rate having an upper limit of 6 times 10 to the 21st molecules per sec. The observations of P/Tempel 2 are compatible with a bare nucleus of 1.6 km radius (geometric albedo = 0.15) and somewhat redder than the sun.

Spinrad, H.

Airborne stellar spectrophotometry from 1.2 to 5.5 microns - Absolute calibration and spectra of stars earlier than M3

Airborne infrared spectrophotometry (1.2-5.5 microns, 1.5% resolution) is presented for 13 stars which have been extensively used as infrared calibration objects: alpha Lyr, alpha CMA, alpha UMi, beta Dra, and mu Her; the K giants beta Gem, alpha UMa, alpha Boo, gamma-1 And, and alpha Tau; and the M giants beta And, beta Peg, and alpha Cet. These spectra, obtained using NASA's Kuiper Airborne Observatory and Lear Jet Observatory, are virtually free of the interfering effects of terrestrial absorptions. Absolute calibration of the spectrophotometry was based on the theoretical model of alpha Lyr by Schild, Peterson, and Oke (1971), which fits photometric measurements at shorter wavelengths. The resulting flux densities are compared with previous ground-based photometry.

Strecker, D. W.

Preparation of Ion Exchange Films for Solid-Phase Spectrophotometry and Solid-Phase Fluorometry

Atomic spectroscopy has dominated the field of trace inorganic analysis because of its high sensitivity and selectivity. The advantages gained by the atomic spectroscopies come with the disadvantage of expensive and often complicated instrumentation. Solid-phase spectroscopy, in which the analyte is preconcentrated on a solid medium followed by conventional spectrophotometry or fluorometry, requires less expensive instrumentation and has considerable sensitivity and selectivity. The sensitivity gains come from preconcentration and the use of chromophore (or fluorophore) developers and the selectivity is achieved by use of ion exchange conditions that favor the analyte in combination with speciative chromophores. Little work has been done to optimize the ion exchange medium (IEM) associated with these techniques. In this report we present a method for making ion exchange polymer films, which considerably simplify the solid-phase spectroscopic techniques. The polymer consists of formaldehyde-crosslinked polyvinyl alcohol with polyacrylic acid entrapped therein. The films are a carboxylate weak cation exchanger in the calcium form. They are mechanically sturdy and optically transparent in the ultraviolet and visible portion of the spectrum, which makes them suitable for spectrophotometry and fluorometry.

Hill, Carol M.