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Uncovering surface plasmon optical resonances in nanohole arrays through interferometric photoemission electron microscopy
In this work, the role of surface plasmon polaritons (SPPs) in nanohole array optical extinction spectra is explored using a time-resolved technique capable of isolating the air/metal interfacial SPP contribution to the typical Fano profile in optical transmission curves. A pair of interferometrically locked broad-band femtosecond pulses is used to launch SPPs from lithographically patterned plasmonic nanohole arrays. SPPs launched in the co- and counter-propagating directions are probed using a third probe pulse in a photoemission electron microscope. Using this approach, we record interferometric SPP–SPP linear autocorrelations that selectively report on the resonances of SPPs launched from arrays of varying pitches and hole diameters. Aside from advancing an approach to selective SPP spectroscopy, we illustrate that resonant coupling in the counter-propagating direction may be exploited to control the spatial, temporal, and spectral characteristics of SPPs. For the counter-propagating direction, we show that tuning the array pitch near the fundamental plasmon resonance generates color-tuned (~770–820 nm), narrow bandwidth SPPs, and the bandwidth may be controlled by changing the ratio of pitch to hole diameter. The SPP resonances we recover through Fourier transforms of the interferometric autocorrelations shed light on the classical problem of Fano interference in nanohole array extinction spectra.
Ultra-High Temperature Thermal Barrier Coating Development and Validation
The most effective method to improve industrial gas turbine power is to increase firing temperature. To maintain component durability at these higher temperatures, thermal barrier coatings (TBC’s) are playing an increasing role in protecting turbine hardware. TBC’s have been successfully used on Solar Turbines’ combustor liners and turbine airfoils, but there is a need for TBC’s that can operate at higher temperatures. Based on recent, favorable rig testing experience, Solar recognized that yttrium aluminum garnet (YAG) TBC’s made by the Solution Precursor Plasma Spray Process (SPPS) has great potential for higher turbine temperatures. This testing verified the thermal cycle durability of the SPPS YAG TBC’s, as well as demonstrated that the temperature drop through the SPPS YAG TBC was twice that measured across a companion APS YSZ TBC. The SPPS YAG TBC with the potential for a 200°C improvement in temperature capability represents a materials breakthrough. The SPPS process also produces a number of unique microstructural features that confer superior properties. SPPC TBC’s have ultra-fine splats that increase toughness and erosion resistance, and the process can be tailored to produce through-thickness cracks for strain-tolerance and control porosity for lower thermal conductivity and increase coating abradability. This proposal would include further development of SPPS YAG density-graded coatings, optimization of the application process, and validation of higher temperature capability and durability through rig and engine testing of coated combustion liners and turbine outer air seals. The technology would be advanced from a TRL 3 to a proposed TRL 6 by overcoming processing concerns on efficiency, application distance and optimization of a graded coating without impacting coating durability by demonstrating the coating performance on components in rig and development gas turbine engine testing.
Surface plasmon polariton pulse shaping via two-dimensional Bragg grating pairs
Abstract We demonstrate control over the spatial and temporal properties of surface plasmon polaritons (SPPs) launched from nanohole arrays in silver. The arrays provide wave vector matching to allow the conversion of free-space photons into counter-propagating SPPs. SPPs launched from multiple arrays interfere at well-defined spatial positions, and the interference fringes form an all-SPP periodic nano-optical grating which evolves in space and time as the SPPs propagate. The spatio-temporal characteristics of the optical grating can be tuned through various nanohole array parameters such as tilt angle, separation, and array width. In addition, we examine multiperiodic arrays (MPAs) consisting of arrays with different pitches placed adjacent to one another. This platform allows the temporal interference of SPPs with different central wavelengths to be tailored through the MPA geometric and structural parameters. The temporal interference serves as an encoded signal, whereby the frequency components can be controlled by the array properties.
Robustness of Gridded Precipitation Products for Vietnam Basins using the Comprehensive Assessment Framework of Rainfall
The use of satellite–based precipitation products (SPPs) have become increasingly prevalent as key inputs to provide regional rainfall for improving hydrological simulations in data–spare regions. This study introduces a new approach – Comprehensive Assessment Framework of Rainfall (CAFR) to evaluate six satellite–based precipitation products (SPPs) for eleven basins with different sizes across Vietnam (2007–2015). These SPPs include the Global Precipitation Mission (GPM) Integrated Multi-satellitE Retrievals for Global Precipitation Measurement Final run Version 6 (GPM IMERGF V6), Multi–Source Weighted–Ensemble Precipitation (MSWEP) V2.2, Soil Moisture to Rain (SM2RAIN) – Advanced SCATterometer (ASCAT) V1.5, Asian Precipitation–Highly–Resolved Observational Data Integration Towards Evaluation (APHRODITE) V1901, Climate Hazards group Infrared Precipitation with Stations (CHIRPS) V2.0, and Precipitation Estimation from Remotely Sensed Information using Artificial Neural Networks (PERSIANN) – Climate Data Record (CDR) V1.0. With the proposed CAFR: (1) IMERGF is suggested to have the best performance overall, especially when simulating flood peaks; (2) SM2RAIN–ASCAT demonstrates the best skills in metrics related to the dry season; (3) For streamflow simulations, SPPs' performance is sensitive to basin size, with larger basins showing better performance skills. In this study, we demonstrate the capability of our proposed framework to better understand SPP applications in hydrological modeling.
Charge Transfer Plasmonics in Bespoke Graphene/α-RuCl 3 Cavities
Surface plasmon polaritons (SPPs) provide a window into the nano-optical, electrodynamic response of their host material and its dielectric environment. Graphene/α-RuCl 3 serves as an ideal model system for imaging SPPs since the large work function difference between these two layers facilitates charge transfer that hole dopes graphene with n ~ 10 13 cm –2 free carriers. In this work, we study the emergent THz response of graphene/α-RuCl 3 heterostructures using our home-built cryogenic scanning near-field optical microscope. Using phase-resolved imaging, we clearly observe long wavelength, heavily damped THz SPPs in a series of variable-size graphene cavities. From this, we extract the plasmonic wavelength and scattering rate in the graphene/α-RuCl 3 heterostructures. We determine that the measured plasmon wavelength and electronic scattering rate match our heterostructures’ theoretically predicted values. Here, our results demonstrate that shaping graphene into bespoke cavity structures enables observation and quantification of SPPs in heavily doped graphene that are largely not addressable with other experimental techniques. Moreover, the manifest lack of metallicity observed in the adjacent doped α-RuCl 3 layer provides significant constraints on the nature of the interfacial charge transfer in this 2D heterostructure.
Probing Surface Plasmon Dynamics in Periodic Nanostructures through Ultrafast Electron Microscopy
Surface plasmon polaritons (SPPs) can be manipulated to localize and guide light in subwavelength distances, enabling them to find applications in a wide range of areas, from sensing to quantum computing. Among several methods of SPP excitation, periodic arrays of nano- and microstructures are of particular interest, as they enable engineering SPP properties through structural parameters. Here, in this study, using the photon-induced near-field electron microscopy (PINEM) technique, we investigated the mode formation, coupling, interference, and decay of SPPs in square and hexagonal arrays of circular nanoholes under both visible and near-infrared excitation. Polarization-resolved analysis revealed the key factors governing SPP localization and interference patterns, showing that the periodicity and symmetry of the array primarily determine the SPP interference patterns and their orientation, while pump polarization mainly modulates their intensity. Time-resolved PINEM measurements demonstrated the spatial dependence of the SPP temporal characteristics. In addition, cathodoluminescence (CL) spectroscopy was employed to examine the intrinsic plasmonic characteristics of the structure. Finite difference time domain (FDTD) simulations showed strong agreement with both PINEM and CL measurements on the spatial and spectral behavior of SPPs. Understanding the spatiotemporal dynamics of SPPs on nanostructures beyond the diffraction limit is crucial for optimizing plasmonic structures for advanced photonic and quantum technologies.
Effects of Pollen on Hydrometeors and Precipitation in a Convective System
Anemophilous (wind-driven) pollen is one type of primary biological aerosol particle, which can rupture under high humidity conditions and form smaller sub-pollen particles (SPPs). Both pollen and SPPs can reach the upper troposphere under convective conditions, acting as cloud condensation nuclei (CCN) and ice nucleating particles (INPs), thus influencing cloud formation and precipitation. However, the impacts of these biological aerosols on cold cloud formation and local climate remain unclear as there are large uncertainties on their emission flux and ice nucleating abilities. Here, we incorporate pollen emission and rupture processes in the Weather Research and Forecasting Model with Chemistry (WRF-Chem) simulations and update the Morrison microphysics scheme within WRF-Chem using aerosol-aware INP parameterizations to account for pollen in addition to other anthropogenic and biogenic aerosol. INP parameterizations for pollen and SPP are derived from laboratory experiments. When including pollen rupture rates as observed in a series of chamber studies, SPP concentrations increase, leading to an increase of cloud ice and water by up to 50% and potentially extending the duration of the convective system. Among all simulated hydrometeors, graupel and raindrops exhibit the largest enhancements from the inclusion of SPPs, with intensifying precipitation at the backside of the convective system and a greater spatial extent. Sensitivity simulations indicate that SPPs have a greater effect on cloud microphysical processes than whole pollen grains, and further observational evidence is needed to constrain these processes.
Engineering anisotropic electrodynamics at the graphene/CrSBr interface
Abstract Graphene is a privileged 2D platform for hosting confined light-matter excitations known as surface plasmon polaritons (SPPs), as it possesses low intrinsic losses and a high degree of optical confinement. However, the isotropic nature of graphene limits its ability to guide and focus SPPs, making it less suitable than anisotropic elliptical and hyperbolic materials for polaritonic lensing and canalization. Here, we present graphene/CrSBr as an engineered 2D interface that hosts highly anisotropic SPP propagation across mid-infrared and terahertz energies. Using scanning tunneling microscopy, scattering-type scanning near-field optical microscopy, and first-principles calculations, we demonstrate mutual doping in excess of 10 13 cm –2 holes/electrons between the interfacial layers of graphene/CrSBr. SPPs in graphene activated by charge transfer interact with charge-induced electronic anisotropy in the interfacial doped CrSBr, leading to preferential SPP propagation along the quasi-1D chains that compose each CrSBr layer. This multifaceted proximity effect both creates SPPs and endows them with anisotropic propagation lengths that differ by an order-of-magnitude between the in-plane crystallographic axes of CrSBr.
Real-space simulations of the hyperbolic plasmon polaritons in 1T′ tungsten ditelluride
Recent discoveries of hyperbolic surface plasmon polaritons (SPPs) in 1T′ WTe 2 have garnered significant attention in 2D materials and nanophotonics. In this study, we employ finite-element simulations to investigate the real-space characteristics of hyperbolic SPPs in thin WTe 2 flakes. Our results show that the SPPs exhibit a pronounced sensitivity to excitation energy and sample thickness. By analyzing the plasmonic field patterns, we extract key plasmonic parameters including plasmon wavelengths, hyperbolic angles, and plasmonic figures of merit. In addition, we examine SPP modes in stacked WTe 2 flakes with varying twist angles, demonstrating that the plasmonic field patterns can be effectively tuned by adjusting the twist angle. Notably, as the twist angle increases, the SPPs undergo a topological transition from open hyperbolic modes to closed elliptic modes. This twist-engineering capability offers promising potential for the development of tunable plasmonic devices based on WTe 2 .
Enhanced Light Outcoupling from OLEDs Fabricated on Novel Low-Cost Patterned Plastic Substrates of Varying Periodicity
OLEDs continue to make strides in display applications, but their commercial utilization in solid-state lighting (SSL) is lagging. An ongoing challenge, in particular for manufacturing, is the need for enhanced efficiency and hence the necessity to increase in an inexpensive approach the extraction of the light generated inside the OLED into the forward (viewing) hemisphere. In conventional OLEDs fabricated on a transparent flat anode coated on glass, the external quantum efficiency (EQE) is only ~20%. About 50% of the light is lost to internal waveguiding in the high refractive index (RI) organic + ITO anode layers and to surface plasmon polaritons (SPPs) at the organic/metal cathode interface. Another ~30% of the light is externally waveguided in the substrate to its edges. While extraction of the externally waveguided light is commonly addressed by adding a microlens array (MLA) or a scattering layer at the substrate’s air-side, light outcoupling increases by only ~1.6-1.7x (vs up to 2.5x in improving from ~20% to ~50%). The use of a hemispherical lens or an index matching fluid (IMF) at the substrate/photodetector (PD) interface increases the outcoupling by at least 2x; these approaches however, are not viable industrially, and even a MLA is sometimes undesirable due to its non-planar, scattering structure. In multi-stack tandem OLEDs, where the metal cathode is far from the emitting zone(s), the impact of photons loss to SPPs decreases. Our project addressed the ~50% loss to the internally waveguided light and SPPs. We evaluated OLEDs fabricated on patterned or planarized plastic substrates manufactured in a cost-effective approach compatible with a roll-to-roll (R2R) process. The OLEDs were either (i) patterned to various degrees depending on the pitch a and height or depth h of the pattern features or (ii) planar, with a pattern buried under a flat high RI planarization layer. We demonstrated that the outcoupling from green patterned OLEDs reaches ~50% by mitigating plasmon–related loss and internal waveguiding, even without the addition of a MLA, a hemispherical lens, or IMF. Simulations conducted in parallel with the experimental effort demonstrated how diffraction by conformally corrugated OLEDs increases the outcoupling to >60%. Structures with varying pitch values were also simulated indicating that combining domains of varying pitch could increase outcoupling to 55-60%. Experimentally, we additionally assessed the role a and h in determining not only the OLED efficiencies, but also their structural properties, i.e., the uniformity and conformality throughout the OLED stack. As planar OLEDs are preferred over corrugated devices, we studied different patterns in plastic substrates that were planarized by a high RI formulation. Planar green OLEDs on such structures showed enhanced efficiencies with EQEs larger than 60% with the addition of an IMF (to extract the substrate mode) at the substrate/Si PD interface. White OLEDs showed EQEs of 45.5%. Plastic substrates are currently less attractive than glass substrates due to drawbacks such as permeability to water vapor and oxygen, and in some cases thermal instability. Plastic substrates however, are flexible and easy to handle unlike thin flexible glass, and once transparent thin barrier films are available, they will become more attractive; they are already of interest in medical applications. Importantly, as it is easy to generate various patterns in different plastic materials, they provide excellent means for assessing and optimizing enhancing extracting structures. Such structures can also be transferred to glass substrates with some process modifications. The technical effectiveness and economic feasibility of the project lie in the patterning of the extracting plastic substrates in an approach that is scalable to R2R manufacturing. R2R processes are of drastically lower-cost than batch or single-unit fabrication. The patterned plastic can be a part of an integrated substrate either plastic or glass, which includes also a MLA or a planar layer with embedded scattering particles, as well as a conductive metal mesh/electrode design. SSL is environmentally-friendly and as OLED SSL becomes more efficient it will reduce electricity consumption, and hence lighting cost, as well as produce less expensive attractive lighting fixtures. Our university-industry collaboration is hence of major benefit to the public as it demonstrates the feasibility of manufacturing optimized extracting substrates for highly efficient OLEDs for SSL in a future R2R process, which would drastically reduce the manufacturing cost and increase production in the USA. Moreover, newly developed methods by our team allow low-cost roll manufactured substrates to be transferred to flexible or rigid glass substrates, which solves the plastic substrate barrier issues, and when combined with device encapsulation will increase the OLEDs’ environmental stability.
Laterally Modulating Carrier Concentration by Ion Irradiation in CdO Thin Films for Mid‐IR Plasmonics
This report demonstrates tunable carrier densities in CdO thin films through local ion irradiation, providing lateral control of mid‐IR optical properties. Ion‐solid interactions produce donor‐like defects that boost electron concentrations from the practical minimum of 2.5 × 10 19 cm −3 to a maximum of 2.5 × 10 20 cm −3 by metered ion exposure. This range is achieved using He, N, Ar, or Au ions at 1–2.8 MeV; when normalized by displacements per atom, all ion species produce comparable results. Since CdO is well‐described by the Drude model, irradiation‐tuned carrier densities directly alter the infrared dielectric function, and in turn, mid‐infrared optical properties. Further, it is demonstrated that by combining irradiation with traditional lithography, CdO films expose to ions in the presence of 3‐µm thick, patterned photoresist exhibit lateral carrier density profiles with ≈400‐nm resolution. Scanning near‐field optical microscopy reveals sharp optical interfaces with almost no companion contrast in surface morphology, microstructure, or crystallinity. Finally, CdO lateral homostructures supporting surface plasmon polaritons (SPPs) are demonstrated whose dispersion relation can be tuned through periodic patterning in a monolithic platform by simple nanofabrication. Numerical simulations show these polaritons result from strong coupling between excitations at CdO plasma frequencies and SPPs supported by the platinum substrate.
Emulation of neutron damage with proton irradiation and its effects on microstructure and microchemistry of Zircaloy-4
This work assesses the potential of proton irradiation to simulate the neutron damage to the matrix and laves phase Zr(Fe,Cr) 2 precipitates in Zircaloy-4. Isothermal proton irradiation has been performed on Zircaloy-4 samples at irradiation temperatures ranging from 250 to 350 °C. Two-step proton irradiation was also performed to enhance the amorphization of and iron loss from the laves phase Zr(Fe,Cr) 2 precipitates. The irradiated microstructures, including dislocation loops and rafts near SPPs, were observed in proton irradiated Zircaloy-4, which are consistent with neutron irradiated material at a similar damage level. The amount of irradiation-induced hardening after proton irradiation was similar to post neutron irradiated data. The significant amorphization of the SPPs and concurrent Fe redistribution observed on neutron irradiated materials can be effectively emulated using a two-step proton irradiation on Zircaloy-4. Hence, the neutron irradiation effect on Zircaloy-4 can be mostly captured using the two-step proton irradiation described in this study.
Spatiotemporal imaging and manipulation of surface plasmons
Abstract Surface plasmon polaritons (SPPs) are travelling surface waves that have shown promise for applications in nanophotonics as they provide a direct route toward photon-mediated electrical signal generation – a central paradigm for speeding up and scaling down photonic elements. SPP waves have also generated fundamental interest due to their high-field strength and sub-wavelength confinement, properties that have enabled the surface-enhanced Raman effect. Over the last decade, photoemission electron microscopy (PEEM) has emerged as a pioneering technique for imaging surface electric fields through ultrashort laser pulse mediated electron emission and has therefore become an indispensable tool for characterizing plasmonic phenomena at interfaces in a variety of materials. PEEM offers nanometer spatial resolution and femtosecond temporal resolution, allowing SPPs to be prepared, monitored, and manipulated on the nanometer-femtosecond scale. Through a brief review of recent reports, we aim to introduce PEEM-based SPP imaging and manipulation modalities and highlight their utility in the context of emerging nanoscale and quantum materials science advancements.
High Temperature Thermal Barrier Coating Evaluation of Yttrium Aluminum Garnet for Gas Turbine Applications
The Solution Precursor Spray Process (SPPS) process has been shown to overcome the durability and property challenges of applying yttrium aluminum garnet (YAG) coating for high temperature thermal barrier coating (TBC) applications (1200°C+) but only limited testing has been performed in representative application environments. In this study, YAG coatings were developed to optimize microstructure and tailor properties for combustion components in an industrial gas turbine. Thermal conductivity, erosion resistance and furnace cycling durability were used to validate YAG properties against the standard yttria-stabilized zirconia coating (YSZ). Graded and multi-layered microstructures were applied to enhance performance while maintaining durability. Further YAG process development was required to replicate coating properties and optimize deposition on more complex fuel injector nozzle and combustion liner components. Rig testing of both components was performed and compared against the baseline YSZ coating validating the high temperature capability and lower thermal conductivity of the SPPS YAG coating. The components in both tests were cycled for a minimum of ten cycles with the fuel injector test targeting a higher operating temperature while the combustor liner operated at standard conditions. A development engine test is planned to further validate performance in a gas turbine engine of this promising material.
A cosmic ray super high energy multicore family event. 2: Structure and fragmentation characteristics of the jets
Quarks and gluons are not directly observable, but may be displayed through fragmentation in the form of hadronic jets, the evidence of which was first revealed in cosmic ray interactions before the advent of the modern theory of strong interactions. Experimental results from ISR and SPPS collider rendered the jet phenomena more confident and definite. All the properties of jets observed up to now at ISR and SPPS collider are in agreement with the predictions of QCD. In order to make further test of QCD in still higher energy regions, detailed study of super high energy jet events in cosmic rays is very desirable. The event KO E19 observed in the Mt. Kambala emulsion chamber is an interesting event for such study. The general features of KO E19 is described. Its total visible energy is sigma E sub gamma = 1537 TeV(E sub min = 1.5 TeV) and production height H=(70 + or - 30)m, with a hadron as its primary particle. Besides about forty small clusters, there are five super high energy cores or jets, one lying near the center of the event while the other four surrounding it, having incident directions making small angles with that of the primary particle. Detailed analysis is done on the emulsion plates inserted in the chamber, making full use of their fine granularity, superior in detecting and analyzing jet events, specially their substructures.
The Solar Probe Plus Mission: Humanity's First Visit to Our Star
Solar Probe Plus (SPP) will be the first spacecraft to fly into the low solar corona. SPPs main science goal is to determine the structure and dynamics of the Suns coronal magnetic field, understand how the solar corona and wind are heated and accelerated, and determine what processes accelerate energetic particles. Understanding these fundamental phenomena has been a top-priority science goal for over five decades, dating back to the 1958 Simpson Committee Report. The scale and concept of such a mission has been revised at intervals since that time, yet the core has always been a close encounter with the Sun. The mission design and the technology and engineering developments enable SPP to meet its science objectives to: (1) Trace the flow of energy that heats and accelerates the solar corona and solar wind; (2) Determine the structure and dynamics of the plasma and magnetic fields at the sources of the solar wind; and (3) Explore mechanisms that accelerate and transport energetic particles. The SPP mission was confirmed in March 2014 and is under development as a part of NASAs Living with a Star (LWS) Program. SPP is scheduled for launch in mid-2018, and will perform 24 orbits over a 7-year nominal mission duration. Seven Venus gravity assists gradually reduce SPPs perihelion from 35 solar radii (RS) for the first orbit to less than 10 RS for the final three orbits. In this paper we present the science, mission concept and the baseline vehicle for SPP, and examine how the mission will address the key science questions.