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At least 19 records

Processing Techniques for ODS Stainless Steels

Oxide dispersion-strengthened (ODS) alloys have been studied extensively, in part as a response to the need to develop the high-temperature materials that are required for energy efficient systems. ODS stainless steels, in particular, are of technological interest because of their high ductility and high strength at elevated temperatures, which when combined with their resistance to corrosion, render them ideal for many applications that require extreme performance quality. Survey of the published literature reveals that efforts have been devoted to incorporate specific strengthening mechanisms in order to meet demanding performance criteria for ODS alloys. As a result, a number of novel processing approaches have been developed in an effort to design distinct microstructures that can enhance the performance of ODS alloys. In the current paper, various techniques used to manufacture ODS stainless steel alloys are compared and summarized on the basis of a literature search, and results are contrasted with selected experimental data obtained by the authors. In particular, cryomilling, water-atomization, and melt-spinning processes are described in detail as three novel approaches that can be effectively used to distribute nanometric oxides in 316L stainless steel matrix. The microstructural features, mechanical properties, and sintering behavior of the fabricated materials are described and discussed. The critical processing parameters for each processing technique are discussed with reference to the properties of the material. The versatility and potential challenges of the individual techniques are also described and contrasted.

36 MATERIALS SCIENCE↗

Numerical Analysis of Molten Pool Behavior and Spatter Formation with Evaporation During Selective Laser Melting of 316L Stainless Steel

During the selective laser-melting process, material evaporation and resultant spatter are common phenomena that bring about many defects. However, the underlying physical phenomena such as molten pool behavior and spatter formation, as evaporation occurred, are sparsely understood and difficult to observe during the process. Thus, a three–dimensional powder-scale model was established to investigate the thermal and flow behavior of the molten pool, the morphology evolution of the molten pool and keyhole, and the spatter formation with evaporation in the selective laser-melting processing of 316L stainless steel. Phase transitions and variations in interfacial force were taken into account in this model. The modified phase-field method was applied to trace the melt–gas interface. The results showed that keyhole formed in molten pool under recoil pressure, and that there were some differences in the temperature distribution and flow behavior inside and outside the keyhole. In addition, the dimension and surface morphology of the molten pool and keyhole depth altered and gradually stabilized during the process. Moreover, droplet spatter formation at rear of molten pool proceeded roughly as follows: the backward ejection of melt vapor would induce a depression in molten pool and a bump on the molten pool surface, the bump moved backward and subsequently a liquid column formed, then the liquid column formed a neck and gradually pinched off, resulting in the droplet spatter. Furthermore, the characteristic morphology of the scan track and dimension of the molten pool were obtained through experiments, which showed good agreement with the simulation results.

36 MATERIALS SCIENCE↗

Corrosion Behavior of Candidate Materials Used for Urea Hydrolysis Equipment in Coal-Fired Selective Catalytic Reduction Units

Corrosion tests were performed in the laboratory in order to assess the corrosion resistance of candidate materials used in urea hydrolysis equipment. The materials to be evaluated were exposed at 145 °C for 1000 h. Alloys 316L, 316L Mod., HR3C, Inconel 718, and TC4 were evaluated. Additionally, aluminide and chromate coatings applied to a 316L substrate were examined. After exposure, the mass changes in the test samples were measured by a discontinuous weighing method, and the morphologies, compositions, and phases of the corrosion products were analyzed using scanning electron microscopy, energy-dispersive spectroscopy, and x-ray diffraction. Results indicated that continuous pitting and dissolution corrosion were the main failure modes for 316L stainless steel. 316L Mod. and HR3C alloy showed better corrosion resistance than 316L due to their relatively high Cr contents, but HR3C exhibited a strong tendency toward intergranular corrosion. Inconel 718, TC4, and aluminide and chromate coating samples showed similar corrosion processes: only depositions formed by hydrothermal reactions were observed. Based on these results, a possible corrosion process in the urea hydrolysis environment was discussed for these candidate materials and questions to be clarified were proposed.

36 MATERIALS SCIENCE↗

Effect of Thermal Aging and Test Temperatures on Fracture Toughness of SS 316(N) Welds

The effect of thermal aging and test temperatures on fracture toughness (J{sub 0.2}) of SS 316(N) weld material has been studied based on J-R curve evaluations. The aging of the welds was carried out at temperatures 370, 475 and 550 °C and for durations varying from 1000 to 20,000 h. The fracture toughness (J-R curve) tests were carried out at 380 and 550 °C for specimens after all aging conditions, including as-weld condition. The initiation fracture toughness (J{sub 0.2}) of the SS 316(N) weld material has shown degradation after 20,000-h aging durations and is reflected in all the test temperatures and aging temperatures. The fracture toughness after different aging conditions and test temperatures, including as-weld condition, was higher than the minimum specified value for this class of welds.

36 MATERIALS SCIENCE↗

Analyses of Small Punch Creep Deformation Behavior of 316LN Stainless Steel Having Different Nitrogen Contents

The small punch creep (SPC) behavior of 316LN stainless steel (SS) containing 0.07, 0.11 and 0.14 wt.% nitrogen has been investigated at 923 K. The transient and tertiary SPC deformation of 316LN SS with various nitrogen contents have been analyzed according to the equation proposed for SPC deflection, δ=δ{sub 0}+δ{sub T}(1−e{sup −κt})+ δ-dot {sub s}t+δ{sub 3}e{sup [φ(t−t{sub r})]}. The relationships among the rate of exhaustion of transient creep (κ), steady-state deflection rate ( δ-dot {sub s}) and the rate of acceleration of tertiary creep (φ) revealed the interrelationships among the three stages of SPC curve. The first-order reaction rate theory was found to be applicable to SPC deformation throughout the transient as well as tertiary region, in all the investigated steels. The initial and final creep deflection rates were decreased, whereas time to attain steady-state deflection rate increased with the increase in nitrogen content. By increasing the nitrogen content in 316LN SS from 0.07 to 0.14 wt.%, each stage of SPC was prolonged, and consequently, the values of κ, δ-dot {sub s} and φ were lowered. Using the above parameters, the master curves for both transient and tertiary SPC deflections were constructed for 316LN SS containing different nitrogen contents.

36 MATERIALS SCIENCE↗

Friction and Wear Properties of CrSiCN/SiC Tribopairs in Water Lubrication

CrSiCN coatings (3.4 at.% Si) were prepared on 316L stainless steels using unbalanced magnetron sputtering. According to the analysis results of x-ray diffractometer and x-ray photoelectrons spectroscopy, silicon in CrSiCN coatings mainly presented in the amorphous forms of a-SiN, a-SiCN and a-SiC. The hardness and Young’s modulus of CrSiN coatings were 19.4 ± 0.6 and 306.1 ± 5.9 GPa, respectively. In addition, the ball-on-disk sliding tests of CrSiCN/SiC tribopairs were performed in distilled water at varying velocities (0.1-0.5 m/s) and loads (2-12 N). The friction coefficient of tribopairs presented a decreasing trend with respect to velocity at low applied loads (≤ 4 N). To be specific, the low friction coefficient of 0.05-0.14 accompanied with polished wear scar was obtained at high velocities and low loads. Finally, the wear mechanism map of CrSiCN/SiC tribopairs was proposed based on a combination of friction coefficient, wear scar morphology and wear rates of tribopairs.

36 MATERIALS SCIENCE↗

Corrosion Behavior of 316L Stainless Steel Fabricated by Selective Laser Melting Under Different Scanning Speeds

This work discussed the effects of different scanning speeds (800, 1083, 1200 and 1400 mm/s) on the microstructure of 316L stainless steel manufactured by selective laser melting (SLM) and the related corrosion behavior. Results showed that there were more voids with faster scanning speeds, and there were oxide powder and non-melt silicon inside the defects. The SLM 316L exhibited a full gamma austenite phase filled with sub-grains, and the average grain size of SLM-1083 mm/s 316L was approximately 42 μm, three times larger than that of the quenched 316L. The pitting potentials for the SLM 316L were all approximately 300 mV higher than that of the quenched due to the modification of inclusions in SLM, but the corrosion rate for the SLM 316L was faster, which was attributed to the voids and unstable passive film. The number of pitting sites increased with the scanning speed, and the pits occurred preferentially at the voids in SLM 316L.

36 MATERIALS SCIENCE↗

Effects of Rolling Temperature on the Microstructure and Properties of 2Cr13/316L/9Cr18MoV Stainless Steel Composite Plate Fabricated by Hot-Rolling Bonding Process

A 15-layer composite plate was developed. The microstructure and mechanical properties were characterized by scanning electron microscopy, Vickers microhardness, tensile, and bending tests. Particularly, the effects of hot-rolling at different rolling temperatures of 1130, 1180, 1250, and 1300 °C on the microstructure and mechanical properties of the 2Cr13/316L/9Cr18MoV composite plates were investigated in detail. The results indicated that, with the increase in the rolling temperature, the tensile strength was first decreased and then slightly increased by the coarsening of grains and the increase in the ferrite content in the 2Cr13 layers. The highest tensile elongation of 12.5% and tensile strength of 958.1 MPa were obtained for the composite plate manufactured with the rolling temperature of 1180 °C. The 2Cr13/316L/9Cr18MoV composite plates with rolling temperatures of 1130 and 1180 °C obtained by hot-rolling processes withstood larger bending deformations, showing only local cracks after the bending process because of their strong combined interfaces. However, during the bending to 130° of specimens fabricated with the rolling temperature of 1250 and 1300 °C, the specimens experienced direct fracture at very low bending displacements.

36 MATERIALS SCIENCE↗

3D Gel-Printing of TiC-Reinforced 316L Stainless Steel: Influence of the Printing Parameters

In this paper, the composite composed of TiC (35 wt.%) reinforced 316L stainless steel matrix was successfully prepared using a 3D gel-printing (3DGP) process. The “step effect” of 3D printing can be reduced using reasonable parameter settings. The properties of TiC/316L slurry for 3DGP and the influence of the different printing parameters on the surface quality of the samples, such as the extrusion overlaps and printing speed, were researched. The microstructure and fracture morphology of the sintered sample were revealed using scanning electron microscopy. The surface roughness, density, and mechanical properties were also measured. When the internal diameter of the nozzle was 0.50 mm, the result showed that the proper extrusion overlap parameter was 0.08 mm and the maximum printing speed was 20 mm/s. Furthermore, the minimum surface roughness value was 10 μm. After sintering, the mechanical performances were similar to those obtained using a conventional powder metallurgy process.

36 MATERIALS SCIENCE↗

Computational Simulation of an Additively Manufactured Marine Component

Early work in finite-element analysis of additive manufacturing (AM) components was not able to include distortion and residual stress of the entire build, yielding uncertainty in the computational model predictions. To address this, current versions of recently developed computational tools are being used to understand their role in validation at the Naval Surface Warfare Center, Carderock Division, for laser powder-bed fusion (L-PBF) AM. A 316L stainless steel L-PBF build containing multiple parts, which exhibited the same local part failure over multiple AM fabrication runs, was selected for computational analysis. Single-part simulations analyzed optimization of computational speed and prediction accuracy. Full-build simulations exposed the smallest re-coater tolerances early in part fabrication as a result of part shrinkage and subsequent cupping. This cupping was predicted to change the powder spreading and result in the non-consolidation of the support structures, which paralleled the failures seen in the physical builds. Part redesign of the conventionally produced part to align with AM fabrication requirements was recommended to alleviate the build failures. This project is part of a larger program focused on validation of the computational tools to determine best practices for insertion of AM simulation into the greater Naval enterprise.

36 MATERIALS SCIENCE↗

Effect of Boron Content on Hot Ductility and Hot Cracking Susceptibility in 316L Austenitic Stainless Steel for Welding Components

Liquation cracking may occur in the heat-affected zone during welding. Two factors influence this phenomenon: the tensile stresses generated during welding and the potential loss of ductility due to the presence of a liquid film at grain boundaries depending on their chemical composition. Gleeble hot ductility tests have been used to study the combined effect of boron content and holding time on ductility drop in the liquation temperature range of a 316L type austenitic stainless steel. It is shown that high boron contents and short holding times promote the loss of ductility in this temperature range. Secondary ion mass spectrometry has been used to correlate mechanical results to boron distribution either at grain boundaries or in the bulk. Other welding tests have been performed to confirm the influence of boron content on hot cracking sensitivity of AISI 316L stainless steels. Results indicate that cracks appear on all specimens but at different strain levels. The higher the boron content is, the more the specimen exhibits tendency to hot cracking.

36 MATERIALS SCIENCE↗

In Situ Quality Monitoring in AM Using Acoustic Emission: A Reinforcement Learning Approach

Additive manufacturing (AM) has attracted considerable attention in recent years. This technology overcomes the geometrical limits of workpieces produced with the traditional subtractive methods and so gives the opportunity to manufacture highly complex shapes. Unfortunately, the repeatability of the manufacturing process and the monitoring of quality are not reliable enough to be utilized in mass production. The quality monitoring of AM processes in commercial equipment has been largely based on temperature measurements of the process zone or high-resolution imaging of the layers. However, both techniques lack information about the physical phenomena taking place in the depth of the materials medium and this limits their reliability in real-life applications. To overcome those restrictions, we propose to combine acoustic emission and reinforcement learning. The former captures the information about the subsurface dynamics of the process. The latter is a branch of machine learning that allows interpreting the received data in terms of quality. The combination of both is an original method for in situ and real-time quality monitoring. Acoustic data were collected during a real process using a commercial AM machine. The process parameters were selected to achieve three levels of quality in terms of porosity concentration while manufacturing a stainless steel 316L cuboid shape. Using our method, we demonstrated that each level of quality produced unique acoustic signatures during the build that were recognized by the classifier. The classification accuracy reached in this work proves that the proposed method has high potential to be used as in situ and real-time monitoring of AM quality.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Fabrication and Characterization of Core–Shell Density-Graded 316L Stainless Steel Porous Structure

In the present work, cylindrical shape 316 L cellular structure with different densities in its core and outer layer (shell) is fabricated by using carbamide as a space holder, via powder metallurgy route and layer-by-layer technique. The arrangement of the created pore is the same as face-centered cubic atomic structure, and different densities are created in two regions by using carbamide particles having two different sizes in the range of 1.7-2 and 2-2.4 mm. The effect of creating a structure with higher porosity (64.5%) in the core and lower porosity (53.8%) in the shell and vice versa and also change in the ratio of the core to the cylinder cross-sectional areas, on the mechanical properties and compaction load bearing of the fabricated foam samples were investigated. In leaching process of the carbamide particles, as an important step of porous structure’s fabrication, it is shown that discontinuous leaching process is more favorable than continuous, by which it would be possible to remove more carbamide particles (around 20%) at the same time. Furthermore, the deformation of the density-graded foam shows the parallel mechanism in the core and shell sections, and the contribution of each part depends on its density and thickness. The energy absorption behavior of the fabricated specimens is evaluated optimally in terms of the energy absorption value associated with the ideal adsorption behavior. The maximum ideal energy absorption efficiency for the samples with more porosity in the shell was approximately equal to 0.91, while for the sample includes the lower amount of porosity in the shell, this value was in the range of 0.85 and 0.89.

36 MATERIALS SCIENCE↗

Effects of CeO{sub 2} on the Microstructure and Properties of Laser Cladding 316L Coating

Laser cladding was used to distribute a CeO{sub 2}-modified 316L powder coating onto a 316L stainless steel surface. The cladding layer phase composition was evaluated through x-ray diffraction. An analysis of the microstructure was conducted using an optical microscope and scanning electron microscope, while the micro-hardness was measured using a tester. The coating corrosion behavior in response to 3.5% NaCl solution was analyzed by polarization curves and electrochemical impedance spectroscopy. Finally, the overall performance of coatings with different CeO{sub 2} concentrations, 1, 2, and 3%, was compared. Results showed that adding CeO{sub 2} significantly refined the grains, reduced the coating porosity, and effectively limited the appearance of local corrosion. Also, additive CeO{sub 2} shifted the coating’s electrode potential in a positive direction, minimizing the current density of corrosion, creating a stable passivation film, and improving the coating’s corrosion resistance. The coating performance (hardness and corrosion behavior) was optimal when 2% CeO{sub 2} was employed as the powder mass.

36 MATERIALS SCIENCE↗

Atomic Layer-Deposited Al{sub 2}O{sub 3} Interlayer for Improved Tribological and Anti-corrosion Properties of TiN Hard Coating on 316L Stainless Steel

A dense Al{sub 2}O{sub 3} interlayer was inserted into TiN to enhance the tribological and anti-corrosion properties of TiN hard coating via a hybrid process of magnetron sputtering and atomic layer deposition (ALD). The influence of the ALD-Al{sub 2}O{sub 3} layer on the microstructure, mechanical, tribological and anti-corrosion properties of TiN was examined. The TiN-Al{sub 2}O{sub 3} coating exhibits low friction coefficient and specific wear rate, due to the structure change and columnar refinement caused by the addition of amorphous ALD-Al{sub 2}O{sub 3} interlay which improves the mechanical properties of hard coating. The improved corrosion properties of TiN are attributed to the fact that the insulating ALD-Al{sub 2}O{sub 3} used as a sealing layer can prevent the corrosive chlorine ions migrating into the lower TiN layer and block the charge transport in coatings. Moreover, raising the insertion position of ALD-Al{sub 2}O{sub 3} layer away from the steel substrate results in a further increase in the anti-corrosion property of TiN-Al{sub 2}O{sub 3} composite coating.

36 MATERIALS SCIENCE↗

Effects of the rolling temperature on microstructure and mechanical properties of 2Cr13/316L laminated composites prepared by accumulative roll-bonding (ARB)

Highlights: • The rolling temperature affects the grain size and microstructural phases of the composite plates. • The rolling temperature affects tensile strength and bending strength of 2Cr13/316L properties of the composite plates. • The temperature gradient and thermal deformation of center and outside regions are different during rolling process. • Composite plate with higher strength and elongation can be obtained by rolling processes. - Abstract: The microstructure and mechanical properties of 2Cr13/316L composite plates by hot-rolling at different rolling temperatures of 1130 °C, 1180 °C, 1250 °C, 1300 °C are investigated in details. With the increase of the rolling temperature, the tensile strength and bending strength of 2Cr13/316Lwere reduced first and then increased slightly due to the coarsening of grains and the increasing of ferrite content in 2Cr13 layers. The highest tensile elongation is obtained at the composite plate with rolling temperature of 1180 °C. 2Cr13/316L composite plates obtained by hot rolling processes were able to withstand larger bending deformation, and no cracks or interfacial delamination can be found in the bending process because of a strong combined interface.

36 MATERIALS SCIENCE↗

Micro- and macro-structural heterogeneities in 316L stainless steel prepared by electron-beam melting

Highlights: • Electron beam melting manufactured parts has a complicated thermal history. • The microstructure varies with the position in the sample. • Pronounced molybdenum segregation at the top disappears at the bottom. • Fast molybdenum diffusion in cell boundaries as well as grain boundaries. - Abstract: This is a study of the micro- and macrostructural variations in samples of stainless steel with the overall composition of the grade 316L, produced using electron beam melting. Electron beam melting is one of the processing methods under consideration for manufacturing some of the International Thermo- Nuclear Experimental Reactor In-Vessel components. Therefore further studies of the homogeneity of the material were conducted. Electron beam melting results in a complicated thermal history of the manufactured part giving a significant impact on the microstructure. A cellular structure that is often observed in samples prepared by selective laser melting was found in the top layers of the specimens. Further down, the structure changed until the cellular structure was almost non-existing, and the grain boundaries had become more pronounced. This revelation of a heterogeneous structure throughout the entire part is crucial for large-scale industrial applications like the Thermo- Nuclear Experimental Reactor to make sure that it is understood that the properties of the material might not be the same at every point, as well as to assure that the correct post-treatment is done. It is also exposed that a significant part of this change is due to molybdenum redistribution inside the sample when it diffuses from the cell boundaries into the cells, and into bigger agglomerates in the grain boundaries. This diffusion seems not to affect the microhardness of the samples.

36 MATERIALS SCIENCE↗

Effect of build geometry on the microstructural development of 316L parts produced by additive manufacturing

Highlights: • Stainless steel ribs were created via direct metal laser sintering to investigate microstructural effect of part design. • EBSD confirmed the presence of large elongated grains in the center of the part, with preferred orientation. • Small grains at the rib surface were found to grow towards the center of the rib with random orientation. • By changing rib thickness and build angle varying texture was observed in the final products. • Large intragranular misorientations were observed in all samples. - Abstract: Additive manufacturing (AM) technology has shown great potential in manufacturing complex products, such as lattice structures without extensive tooling. The focus of this study was to understand the effect of the part geometry on the resulting microstructure. Direct metal laser sintering was used for fabrication of ribs with thicknesses varying between 0.2 and 3.0 mm as well as inclined ribs the with build angles of 30° and 45°. The investigation showed that grains were growing in an epitaxial manner parallel to the building direction. The large elongated grains had a preferential orientation, resulting from the temperature gradient. Additionally, it was found that small grains had formed close to the part surface which were inclined towards the center of the rib. In contrast to the elongated grains, they had a random orientations. The results also indicated that at build angles below 45°, the formed microstructure consisted of the large grains elongated in the building direction. For the used process parameters, the critical part thickness to avoid large elongated grains was found to be about 0.4 mm. These findings allowed us to establish the basics for design rules when it comes to thin wall structures.

36 MATERIALS SCIENCE↗