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All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

Nuclear Data Sheets for A = 75

The experimental nuclear spectroscopic data for known nuclides of mass number 75 (Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Br, Kr, Rb, Sr) have been evaluated and presented together with Adopted properties for levels and γ rays. New high-spin data are available for {sup 75}Ga, and {sup 75}Rb; and lifetime data for high-spin states in {sup 75}Br and {sup 75}Kr. For ΔJ =1, M1+E2 transitions in two rotational bands in {sup 75}Kr, several B(E2)(W.u.) values are anomalously high, deviating by 2–3 σ values from currently accepted RUL(E2) = 300. In the opinion of the evaluators, there is need to remeasure level lifetimes and multipole mixing ratios in {sup 75}Kr to resolve this serious discrepancy. New precise single-particle transfer cross section data are available for {sup 75}Ga, {sup 75}Ge, {sup 75}As and {sup 75}Se from several different reactions (2009Ka06,2008Sc03); these data give information for occupancy of valence neutron orbitals in the ground states of target nuclides: {sup 76}Ge, {sup 76}Se and {sup 78}Se. No significant new data since the 1999 NDS for A = 75 have been reported for {sup 75}As and {sup 75}Se. No data are yet available for excited states in {sup 75}Co, {sup 75}Ni and {sup 75}Sr. For {sup 75}Fe, only the isotopic identification is made with one observed event. The radioactive decay schemes of {sup 75}Co and {sup 75}Ni are unknown while those for {sup 75}Rb and {sup 75}Sr are incomplete. This work supersedes the data presented in the previous NDS evaluation of A = 75 published by 1999Fa05.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2018

Specific features of the ferroelectric state in two-layer barium strontium titanate-based heterostructures

The structural properties of one- and two-layer heterostructures based on the barium–strontium titanate of various compositions deposited by the Frank–Van der Merve on a magnesium oxide substrate have been studied. The heterostructures have been prepared by the rf sputtering of the stoichiometric ceramic targets in a Plazma 50 SE deposition system. The principal difference of this method of deposition from known analogs is that the growth of single-crystal films occurs from a disperse oxide phase formed in the plasma of a high-current rf discharge during the ceramic target sputtering at the cluster level. The peculiarities of the manifestation of the ferroelectric state in the two-layer heterostructures when changing the sequence order of the films with various compositions of barium–strontium titanate.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Synergy of elastic and inelastic energy loss on ion track formation in SrTiO 3

While the interaction of energetic ions with solids is well known to result in inelastic energy loss to electrons and elastic energy loss to atomic nuclei in the solid, the coupled effects of these energy losses on defect production, nanostructure evolution and phase transformations in ionic and covalently bonded materials are complex and not well understood due to dependencies on electron-electron scattering processes, electron-phonon coupling, localized electronic excitations, diffusivity of charged defects, and solid-state radiolysis. Here we show that a colossal synergy occurs between inelastic energy loss and pre-existing atomic defects created by elastic energy loss in single crystal strontium titanate (SrTiO 3 ), resulting in the formation of nanometer-sized amorphous tracks, but only in the narrow region with pre-existing defects. These defects locally decrease the electronic and atomic thermal conductivities and increase electron-phonon coupling, which locally increase the intensity of the thermal spike for each ion. This work identifies a major gap in understanding on the role of defects in electronic energy dissipation and electron-phonon coupling; it also provides insights for creating novel interfaces and nanostructures to functionalize thin film structures, including tunable electronic, ionic, magnetic and optical properties.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

The influence of the concentration of Sr ions on the crystal and magnetic structures of Ba{sub 2} –{sub x}Sr{sub x}FeMoO{sub 6} double perovskites (x = 0–1.6)

The crystal and magnetic structures of a solid solution of double perovskite Ba{sub 2–} {sub x}Sr{sub x}FeMoO{sub 6} (x = 0–1.6) have been investigated by neutron diffraction. The high-resolution diffraction patterns have provided precise information about the changes in the crystal and magnetic structures with an increase in the strontium content and data on the behavior of the sample microstructure. Replacement of barium with strontium leads to a change in the lattice symmetry from cubic (x = 0, sp. gr. Fm3̄m)) to tetragonal (x = 0.4, sp. gr. I4/m). At x = 1.0, the symmetry is either tetragonal (sp. gr. I4/m) or orthorhombic (sp. gr. Fmmm), and at x = 1.6 the symmetry becomes again tetragonal (sp. gr. I4/m). The values of the Curie temperature and microstrain increase with an increase in the strontium content.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Misfit strain phase diagrams of epitaxial PMN–PT films

Misfit strain–temperature phase diagrams of three compositions of (001) pseudocubic (1 − x)·Pb (Mg{sub l/3}Nb{sub 2/3})O{sub 3} − x·PbTiO{sub 3} (PMN–PT) thin films are computed using a phenomenological model. Two (x = 0.30, 0.42) are located near the morphotropic phase boundary (MPB) of bulk PMN–PT at room temperature (RT) and one (x = 0.70) is located far from the MPB. The results show that it is possible to stabilize an adaptive monoclinic phase over a wide range of misfit strains. At RT, the stability region of this phase is much larger for PMN–PT compared to barium strontium titanate and lead zirconate titanate films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Superconductivity in SrTiO{sub 3}: Dielectric Function Method for Non-Parabolic Bands

The dielectric function method for superconductivity has been applied to SrTiO{sub 3} accounting for the non-parabolic dispersion of charge carriers in the conduction band and for the dispersion of optical phonons based on density functional theory calculations. The obtained critical temperatures of the superconducting phase transition in SrTiO{sub 3} are in agreement with experiments in the density range n ∼ 5 × 10{sup 18} to 5 × 10{sup 20}cm{sup − 3}. The dielectric function method predicts also the sign of the anomalous isotope effect in strontium titanate, in line with recent observations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

The Influence of High-Frequency Discharge on Substrate Temperature during Film Deposition

The process of discharge-induced substrate heating at the initial stage of film synthesis by method of high-frequency cathode sputter deposition has been studied. The temperature to which the substrate was heated after the discharge switch-on was determined using the optical interferometry technique. In a working regime of barium strontium titanate film deposition onto a magnesium oxide substrate, the substrate temperature exceeded 1000°C.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Piezoelectricity above the Curie temperature? Combining flexoelectricity and functional grading to enable high-temperature electromechanical coupling

Most technologically relevant ferroelectrics typically lose piezoelectricity above the Curie temperature. This limits their use to relatively low temperatures. In this Letter, exploiting a combination of flexoelectricity and simple functional grading, we propose a strategy for high-temperature electromechanical coupling in a standard thin film configuration. We use continuum modeling to quantitatively demonstrate the possibility of achieving apparent piezoelectric materials with large and temperature-stable electromechanical coupling across a wide temperature range that extends significantly above the Curie temperature. With Barium and Strontium Titanate, as example materials, a significant electromechanical coupling that is potentially temperature-stable up to 900 °C is possible.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Crystal Structure of Cl-Deficient Analogue of Taseqite from Odikhincha Massif

An eudialyte group mineral, found in pegmatites of the Odikhincha massif (the northern part of the Siberian platform), has been investigated using X-ray diffraction, IR spectroscopy, and Raman spectroscopy. The mineral is characterized by a high strontium content and a low chlorine content. It has a trigonal unit cell with the following parameters: a = 14.2700(6) Å and c = 30.057(1) Å; V = 5300.6(1) Å{sup 3}; sp. gr. R3m. The structure has been refined to R = 0.047 in the anisotropic approximation of atomic displacements using 1697F > 4σ(F). The idealized formula (Z = 3) was found to be Na{sub 12}Sr{sub 2}Ca{sub 6}Fe{sub 3}{sup 2+} Zr{sub 3}NbSi{sub 25}O{sub 72}(OH,O){sub 4}Cl(Н{sub 2}О){sub 0.2}. The chemical composition and structure of this mineral are close to those of taseqite; however, it differs from the holotype sample by a low chlorine content and peculiarities of cation distribution over basic structure sites. A comparative analysis of strontium-rich eudialytes has revealed their important crystallochemical feature: selective concentration of strontium in the N4 site. Thus, taseqite, along with heterophyllosilicates, may play a role of strontium concentrator in agpaitic pegmatites.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Injection locking of a low cost high power laser diode at 461 nm

Stable laser sources at 461 nm are important for optical cooling of strontium atoms. In most existing experiments, this wavelength is obtained by frequency doubling infrared lasers, since blue laser diodes either have low power or large emission bandwidths. Here, we show that injecting less than 10 mW of monomode laser radiation into a blue multimode 500 mW high power laser diode is capable of slaving at least 50% of the power to the desired frequency. We verify the emission bandwidth reduction by saturation spectroscopy on a strontium gas cell and by direct beating of the slave with the master laser. We also demonstrate that the laser can efficiently be used within the Zeeman slower for optical cooling of a strontium atomic beam.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Short Thermionic-Cathode Discharge in Alkaline-Earth Metal Vapor

A short (without a positive column) Knudsen thermionic discharge initiated in barium and strontium vapor has been investigated. It has been shown that the behavior of these discharges and their formation mechanism, effective heating of the plasma electrons by a cathode electron beam, are, in general, similar to the discharge in cesium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Photoelastic Properties of Potassium Sulfate Crystals

The spectral dependences of the absolute piezooptic coefficients of potassium sulfate crystals are studied. It is established that their dispersion dependence is insignificant. The matrix of elastooptic coefficients p{sub in} of these crystals is filled using the elastic stiffness coefficients and the absolute piezooptic coefficients. The coefficient of acoustooptical efficiency M{sub 2} is calculated. It is shown that, considering the maximum values, it is more than an order of magnitude higher than that of quartz and strontium borate crystals. Potassium sulfate crystals are proposed for use for acoustooptic modulation of ultraviolet radiation, taking into account the short-wavelength limit of their transparent region (~170 nm).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Ternary crystals Sr{sub 1−y}Eu{sub y−x}{sup 2+}Eu{sub x}{sup 3+}F{sub 2+x} of fluorite phases with a variable europium valence and their thermal conductivity (50–300 K)

Crystals of new fluorite materials: ternary nonstoichiometric Sr{sub 0.9}Eu{sub 0.086}Eu{sub 0.014}F{sub 2.014} and Sr{sub 0.5}Eu{sub 0.432}Eu{sub 0.068}F{sub 2.068} phases with a structure of fluorite (CaF{sub 2}) type, containing europium ions in different oxidation states (Eu{sup 2+}, Eu{sup 3+}), have been grown for the first time from a melt by the Bridgeman method. The variation in their thermal conductivity k(T) in a temperature range of 50–300 K has been experimentally studied. The equivalent cation positions with a large difference in cation masses (m{sub Sr} = 87.62 amu and m{sub Eu} = 151.96 amu) lead to low k(T) values of ternary (Sr{sub 1-y}Eu{sub y-x}{sup 2+}Eu{sub x3+}F{sub 2+x}) and binary (Eu{sub 0.864}{sup 2+}Eu{sub 0.136}{sup 3+}F{sub 2.136}) crystals. One can obtain crystals with thermal characteristics specified in a wide range by adjusting the ratio of strontium and europium (regardless of the valence). Since the thermal conductivity of Sr{sub 0.5}Eu{sub 0.432}Eu{sub 0.068}F{sub 2.068} and Eu{sub 0.864}Eu{sub 0.136}F{sub 2.136} is independent of temperature in the range of 200–300 K, they can be recommended as reference materials with k(T) = const.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Grain boundary scavenging through reactive sintering of strontium and iron in samarium doped ceria electrolyte for ITSOFC applications

Highlights: • Addition of iron and strontium to Samarium doped ceria by combustion method and sintered at 1000 °C, 1200 °C, 1300 °C. • Viscous phase sintering of iron at 1200 °C modified to reactive sintering of iron and strontium at 1300 °C. • Grain boundary activation energy lowered without compensating the grain activation energy. • The highest scavenging factor of 10.52 with the lowest activation energy of 1.02eV was achieved. - Abstract: Lowering the operational temperature of ceria based electrolytes is important for commercialization of solid oxide fuel cells. Here, we report the effect of iron, strontium and iron/strontium co-addition in samarium (20 mol %) doped ceria (SDC) with respect to sintering, microstructural modifications and ionic conductivity. The nanoparticle synthesized through glycine-nitrate combustion method was sintered at 1000, 1200 and 1300 °C. An increase in density was observed in iron doped SDC due to viscous flow sintering while co-addition of strontium and iron lead to the reactive sintering at 1300 °C by forming a eutectic liquid phase which resulted in the density of 99%. The presence of iron and strontium generated a compensatory tensile strain in the lattice and an enhancement in oxygen vacancy concentration which resulted in higher ionic conductivity. Co-addition of strontium and iron in SDC, not only increases the density but also reduces the activation energy for grain boundary conductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

A study of structural, optical and dielectric properties of crystalline Sr{sub 2}Nb{sub 2}O{sub 7} nanoparticles synthesized by a modified combustion technique

Nanocrystalline Strontium Pyroniobate is synthesized by a novel auto-igniting combustion technique. The X-Ray diffraction studies reveal that Strontium Niobate possesses orthorhombic structure. Phase purity and structure of the nanopowder is further examined using Fourier-Transform Infrared and Raman spectroscopy. The average particle size of the as prepared nanoparticles from the Transmission Electron Microscopy is 30 nm. Sr{sub 2}Nb{sub 2}O{sub 7} is a photoluminescent material and the optical band gap determined from the UV-DRS spectrum is 2.7eV. The sample is sintered at an optimized temperature of 1350°C for 2 hours and obtained maximum density. The dielectric constant and loss factor values obtained at 5MHz for a well-sintered Strontium Niobate pellet is found to be 40 and 3.9×10{sup −3} respectively, at room temperature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Atomic and electronic structure of the SrNbO{sub 3}/SrNbO{sub 3.4} interface

We have determined the atomic-scale structure of the SrNbO{sub 3}/SrNbO{sub 3.4} interface and related it to the electronic structure. Experimentally, transmission electron microscopy observations reveal that SrNbO{sub 3} and SrNbO{sub 3.4} show orientation relationships [1{sup ¯}10]{sub SrNbO{sub 3}} // [010]{sub SrNbO{sub 3{sub .{sub 4}}}} and (110){sub SrNbO{sub 3}} // (001){sub SrNbO{sub 3{sub .{sub 4}}}}, and that their interface is coherent and atomically abrupt. Theoretically, this interface is found to be strongly anisotropic in electronic structure, and takes on quasi-one-dimensional nature. We also find that the interface impacts greatly the electron occupation of Nb d orbitals, particularly d{sub z}{sup 2} orbital. The combined study represents a relevant advance in atomically bridging structures to properties of heterointerfaces.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗