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SnSb is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sn2+ is bonded in a body-centered cubic geometry to eight equivalent Sb2- atoms. All Sn–Sb bond lengths are 3.29 Å. Sb2- is bonded in a body-centered cubic geometry to eight equivalent Sn2+ atoms.
SnSb is Zincblende, Sphalerite structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Sn2+ is bonded to four equivalent Sb2- atoms to form corner-sharing SnSb4 tetrahedra. All Sn–Sb bond lengths are 3.00 Å. Sb2- is bonded to four equivalent Sn2+ atoms to form corner-sharing SbSn4 tetrahedra.
SnSb is SC16 CuCl, stable at 5GPa-like structured and crystallizes in the trigonal R3m space group. The structure is three-dimensional. Sn2+ is bonded to four equivalent Sb2- atoms to form corner-sharing SnSb4 trigonal pyramids. There are one shorter (2.90 Å) and three longer (2.98 Å) Sn–Sb bond lengths. Sb2- is bonded to four equivalent Sn2+ atoms to form corner-sharing SbSn4 trigonal pyramids.