Materials Data on SbH3OF6 by Materials Project
H3OSbF6 is Tetraauricupride structured and crystallizes in the cubic I2_13 space group. The structure is zero-dimensional and consists of eight hydrogen hydrate molecules and eight SbF6 clusters. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is three shorter (1.90 Å) and three longer (1.94 Å) Sb–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Sb5+ atom.
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