Materials Data on SbPC3Cl5O by Materials Project
C3ClSbPOCl4 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four allyl chloride molecules and four SbPOCl4 clusters. In each SbPOCl4 cluster, Sb2- is bonded in a distorted square pyramidal geometry to one O2- and four Cl1- atoms. The Sb–O bond length is 2.09 Å. There are a spread of Sb–Cl bond distances ranging from 2.32–2.41 Å. P5+ is bonded in a single-bond geometry to one O2- atom. The P–O bond length is 1.60 Å. O2- is bonded in a distorted bent 120 degrees geometry to one Sb2- and one P5+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb2- atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb2- atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb2- atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb2- atom.