Results for “SbPH4(O2F3)2”

Materials Data on SbPH4(O2F3)2 by Materials Project

P(HO)4SbF6 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four tetrahydroxyphosphanium molecules and four SbF6 clusters. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.91–1.94 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.