Materials Data on SbRhS by Materials Project
RhSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Rh3+ is bonded to three equivalent Sb1- and three equivalent S2- atoms to form RhSb3S3 octahedra that share corners with twelve equivalent RhSb3S3 octahedra, corners with three equivalent SbRh3S tetrahedra, and corners with three equivalent SSbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. All Rh–Sb bond lengths are 2.61 Å. All Rh–S bond lengths are 2.48 Å. Sb1- is bonded to three equivalent Rh3+ and one S2- atom to form SbRh3S tetrahedra that share corners with three equivalent RhSb3S3 octahedra, corners with six equivalent SbRh3S tetrahedra, and corners with nine equivalent SSbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 79°. The Sb–S bond length is 2.53 Å. S2- is bonded to three equivalent Rh3+ and one Sb1- atom to form SSbRh3 tetrahedra that share corners with three equivalent RhSb3S3 octahedra, corners with six equivalent SSbRh3 tetrahedra, and corners with nine equivalent SbRh3S tetrahedra. The corner-sharing octahedral tilt angles are 78°.