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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Relationships of soil, grass, and bedrock over the Kaweah Serpentinite Melange through spectral mixture analysis of AVIRIS data

A linear mixing model is used to model the spectral variability of an AVIRIS scene from the western foothills of the Sierra Nevada and calibrate these radiance data to reflectance. Five spectral endmembers from the AVIRIS data, plus an ideal 'shade' endmember were required to model the continuum reflectance of each pixel in the image. Three of the endmembers were interpreted to model the surface constituents green vegetation, dry grass, and illumination. Comparison of the fraction images to the bedrock geology maps indicates that substrate composition must be a factor contributing to the spectral properties of these endmembers. Detailed examination of the reflectance spectra of the three soil endmembers reveals that differences in the amount of ferric and ferrous iron and/or organic constituents in the soils is largely responsible for the differences in spectral properties of these endmembers.

Mustard, John F.↗

Testing Destruction of Clay Minerals By Silica-Poor Brines in Gale Crater, Mars Using Laboratory and Field Experiments

The Mars Science Laboratory (MSL) Curiosity rover landed in Gale crater to investigate the cause for mineralogical changes seen from orbit, including the clay-sulfate mineral transition observed on its central mound, Aeolis Mons. The lower strata show spectral signatures of clay minerals, hematite, and hydrated Mg sulfates, and the upper strata are dominated by hydrated Mg sulfate signatures. This significant transition has been observed in other locations on Mars, and therefore processes related to the clay mineral-sulfate transition are likely important broadly across Mars. The bulk mineralogy of ~3.7 Ga sedimentary rocks in Gale crater is a product of variations in sediment sources and depositional processes, with overprinting by episodes of early and late diagenetic alteration. Sedimentary analyses of the smectite clay minerals observed in the Glen Torridon (GT) region of Mount Sharp suggest formation in a lacustrine aqueous environment. Examination of the Vera Rubin ridge (VRR) strata indicate that it was formed at the same time as GT and later altered by extensive diagenesis. Recent work suggests that the observed mineral transition from smectites and talc-serpentinites in GT to iron oxides and oxyhydroxides and VRR may have resulted from extensive diagenetic alteration by density driven, silica-poor brines sourced from the overlying sulfur-bearing unit on Mount Sharp. This process of alteration by silica-poor brines is observed in limited locations on Earth. We are therefore working to demonstrate the impacts of silica poor brines on clay mineral alteration in laboratory column and terrestrial analog burial experiments. Column experiments allow the investigation of dissolution and precipitation under conditions that represent a closer analog to natural environments, while burial experiments allow examination of weathering reactions of a known starting material after a specific period of time in a natural field environment. Both methods are valuable for interpreting the water-rock interactions between clay minerals and brines. In preparation for these longer-term column and burial experiments, we are performing preliminary batch dissolution experiments on materials relevant to Glen Torridon: nontronite and serpentinite. We are using magnesium sulfate brine solutions relevant to those proposed on Mars. The results of this study can provide constraints on the characteristics of the diagenetic fluids that formed the altered minerals in Gale crater. They can also provide insights into the role of brine density-driven diagenesis in past aqueous environments on Mars, which have been proposed to be widespread.

J E Valdueza↗

Research and investigation of geology, mineral, and water resources of Maryland

The authors have identified the following significant results. Field work in Baltimore County revealed that the signature returns of serpentinitic and nonserpentinitic rocks correlates with the vegetation cover and land use pattern. In Maryland Piedmont, bedrock lithology and structure are enhanced only to the extent that land use is geologically dictated. Two prominent sets of linear features are detected on ERTS-1 imagery at N 45 deg E and N 20 deg E. Beaches of Chesapeake Bay are classified as broad and narrow beaches based on the width of the backshore zone. It is shown by comparing historical shorelines of Ocean City, from the inlet to the Maryland-Delaware line that reversal zones of erosion and accretion occur at different locations for different periods. High reflectance levels (high marsh-high topographic areas) for the lower Eastern Shore are found to be distributed as two distinct trending linear ridge systems. Observations of MSS band 5 dated 9 April 1974 exhibited an unique sedimentation pattern for Chesapeake Bay. Following a 1.5 inch rainfall, heavy concentration of suspended sediments is observed on the imagery, particularly in the area of the turbidity maximum.

Weaver, K. N.↗

Hydrothermal alteration in the 3.5 b.y. old Onverwacht Group of South Africa

K-Ar studies of authigenic and alteration phases from the 3.5 b.y. old Onverwacht group of South Africa delineate hydrothermal metamorphism that ended 3.3 b.y. years ago. A whole rock K-Ar errochron from analysis of barite, dolomite, chert, and serpentinite (komatiite) gives an age of 3.3 b.y. with an intercept of 1,678 + or - 103. The 3.3. b.y. age for the metamorphism in the Onverwacht was confirmed by the Argon isotopes stepwise heating experiments of komatiites and basaltic komatiites from the Onverwacht Group. In addition, the errochron suggests all the phase studied equilibrated with a reservoir of hydrothermal argon with relatively uniform isotopic composition. The concept of hydrothermal activity in the Onverwacht Group is discussed and illustrated with photographs.

Hart, R.↗

A new class of natural magnetic materials - The ordering alloys

It is shown that tetrataenite (approximately FeNi), found in many meteorites, and Josephinite (approximately FeNi3), found in many serpentinized peridotites and possibly in Allende, are atomically ordered alloys. Data are presented, showing magnetic hysteresis loops, coercivity-temperature behavior at cryogenic temperatures, and thermomagnetic curves, that show that these ordered magnetic materials have unique magnetic properties and do not fit the conventional rock magnetism paradigms represented by Fe3O4 serpentinites. The ordered state is characterized by induced magnetic anisotropy, reaching the extreme for the tetragonal truly uniaxial anisotropy in FeNi. It is suggested that these ordered magnetic alloys should be considered a new class of natural magnetic materials.

Wasilewski, Peter↗

Simplified Meteorite Parent Body Alteration of Amino Acids By Hydrothermal Processes

Amino acids have been identified in extraterrestrial materials such as meteorites and returned samples from asteroids and comets. Some of these amino acids or their precursors may have formed on icy interstellar dust grains or at a later phase when these grains became incorporated into larger parent bodies. In this work, we simulated parent body aqueous alteration of the residues from irradiated interstellar ice analogs in the presence of relevant minerals (pulverized serpentinite and Allende meteorite). We tracked the change in amino acid abundances as a function of hydrothermal processing time and examined how these differed based on the presence of minerals. We find that the presence of minerals and their mineralogy can have a significant impact on the formation and destruction of amino acids during simulated aqueous alteration experiments.

Christopher K Materese↗