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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Implementing the Simple Biosphere Model (SiB) in a general circulation model: Methodologies and results

The Simple Biosphere MOdel (SiB) of Sellers et al., (1986) was designed to simulate the interactions between the Earth's land surface and the atmosphere by treating the vegetation explicitly and relistically, thereby incorporating biophysical controls on the exchanges of radiation, momentum, sensible and latent heat between the two systems. The steps taken to implement SiB in a modified version of the National Meteorological Center's spectral GCM are described. The coupled model (SiB-GCM) was used with a conventional hydrological model (Ctl-GCM) to produce summer and winter simulations. The same GCM was used with a conventional hydrological model (Ctl-GCM) to produce comparable 'control' summer and winter variations. It was found that SiB-GCM produced a more realistic partitioning of energy at the land surface than Ctl-GCM. Generally, SiB-GCM produced more sensible heat flux and less latent heat flux over vegetated land than did Ctl-GCM and this resulted in the development of a much deeper daytime planetary boundary and reduced precipitation rates over the continents in SiB-GCM. In the summer simulation, the 200 mb jet stream and the wind speed at 850 mb were slightly weakened in the SiB-GCM relative to the Ctl-GCM results and equivalent analyses from observations.

Sato, N.↗
NASA NTRS1989

A global climatology of albedo, roughness length and stomatal resistance for atmospheric general circulation models as represented by the Simple Biosphere Model (SiB)

Components of the Simple Biosphere Model (SiB) of Sellers et al. (1986) were used to generate global monthly fields of surface albedo (0.4-4.0 microns), roughness length and minimum surface (stomatal) resistance. SiB consists of three submodels which describe the roles of radiative transfer, turbulent transfer and surface resistance in determining the energy balance of the vegetated land surface. These three submodels were detached from SiB and used on the SiB parameter set (total and green leaf area index, leaf angle orientation, canopy dimensions, etc.) to calculate global monthly fields of albedo, roughness length and minimum stomatal resistance at 1 x 1 deg resolution. Time series of various parameters are also displayed for each vegetation type for specified grid points. The SiB results compare reasonably well with appropriate measurements obtained from the literature and have the additional merit of being mutually consistent; the three submodels use many common parameters, which ensures that, for each grid area, the calculated surface properties are closely interrelated as is the case in nature. The derived fields provide a check on the operation of the submodels and the correctness of the parameter set. They can also be used as prescribed fields for GCMs that do not have biophysically based land surface parameterizations.

Dorman, J. L.↗
NASA NTRS1986

Thigmomorphogenesis: anatomical, morphological and mechanical analysis of genetically different sibs of Pinus taeda in response to mechanical perturbation

Twenty-three open pollinated families (half-sibs) and four controlled pollinated families (full-sibs) of Pinus taeda L. (loblolly pine) were grown in a greenhouse and analyzed for changes induced by mechanical perturbation (MP). These changes included inhibition of stem and needle elongation, bracing of branch nodes, and increased radial growth in the direction of the MP. Inhibition of stem elongation was the least variable feature measured. Leaf extension and stem diameter were highly variable between half-sibs. MP induced increased drag in greenhouse grown P. taeda in wind-tunnel tests. In P. taeda, MP induced decreased flexibility and increased elasticity and plasticity of the stem. The increased radial growth of the stems overrode the increase in elasticity, resulting in an overall decrease in flexibility. MP trees had a higher rupture point than non-MP controls. Increased radial growth is a result of more rapid cell divisions of the vascular cambium, resulting in increased numbers of tracheids. The decreased leader growth is partly due to a decreased tracheid length in response to MP.

Non-NASA Center↗
NASA NTRS1987

Testing the Simple Biosphere model (SiB) using point micrometeorological and biophysical data

The suitability of the Simple Biosphere (SiB) model of Sellers et al. (1986) for calculation of the surface fluxes for use within general circulation models is assessed. The structure of the SiB model is described, and its performance is evaluated in terms of its ability to realistically and accurately simulate biophysical processes over a number of test sites, including Ruthe (Germany), South Carolina (U.S.), and Central Wales (UK), for which point biophysical and micrometeorological data were available. The model produced simulations of the energy balances of barley, wheat, maize, and Norway Spruce sites over periods ranging from 1 to 40 days. Generally, it was found that the model reproduced time series of latent, sensible, and ground-heat fluxes and surface radiative temperature comparable with the available data.

Sellers, P. J.↗
DOE OSTI2026

BLUP and mean yields of selected top 25 high yielding half-sib families

BLUP and mean yields of selected top 25 high yielding half-sib families. The yield BLUP were estimated using mixed linear models. The family column indicates the families with progeny column showing the corresponding progenies to selected families. ‘Wat’ here has been used to denote Watkinsville, ‘Tif’ for Tifton and ‘TN’ for Tennessee.

09 BIOMASS FUELS↗
NASA NTRS1991

A simplified treatment of SiB's land surface albedo parameterization

The earlier presented surface albedo parameterization is simplified by assuming that the reflectance of direct solar radiation is a simple function of solar zenith angle. The function chosen contains three parameters that vary with vegetation type, greenness, and leaf area index. Tables of parameter values are presented. Using these tables, SiB's (Simple Biosphere model) absorbances of direct solar radiation can be reproduced with an average relative error of less than 0.5 percent. Finally, the direct reflectance function is integrated over zenith angle to produce an equation for the surface reflectance of diffuse radiation.

Koster, Randal D.↗
NASA NTRS1999

Soil Surface Runoff Scheme for Improving Land-Hydrology and Surface Fluxes in Simple SiB (SSiB)

Evapotranspiration on land is hard to measure and difficult to simulate. On the scale of a GCM grid, there is large subgrid-scale variability of orography, soil moisture, and vegetation. Our hope is to be able to tune the biophysical constants of vegetation and soil parameters to get the most realistic space-averaged diurnal cycle of evaporation and its climatology. Field experiments such as First ISLSCP Field Experiment (FIFE), Boreal Ecosystem-Atmosphere Study (BOREAS), and LBA help a great deal in improving our evapotranspiration schemes. However, these improvements have to be matched with, and coupled to, consistent improvement in land-hydrology; otherwise, the runoff problems will intrinsically reflect on the soil moisture and evapotranspiration errors. Indeed, a realistic runoff simulation also ensures a reasonable evapotranspiration simulation provided the precipitation forcing is reliable. We have been working on all of the above problems to improve the simulated hydrologic cycle. Through our participation in the evaluation and intercomparison of land-models under the behest of Global Soil Wetness Project (GSWP), we identified a few problems with Simple SiB (SSIB; Xue et al., 1991) hydrology in regions of significant snowmelt. Sud and Mocko (1999) show that inclusion of a separate snowpack model, with its own energy budget and fluxes with the atmosphere aloft and soil beneath, helps to ameliorate some of the deficiencies of delayed snowmelt and excessive spring season runoff. Thus, much more realistic timing of melt water generation was simulated with the new snowpack model in the subsequent GSWP re-evaluations using 2 years of ISLSCP Initiative I forcing data for 1987 and 1988. However, we noted an overcorrection of the low meltwater infiltration of SSiB. While the improvement in snowmelt timing was found everywhere, the snowmelt infiltration has became excessive in some regions, e.g., Lena river basin. This leads to much reduced runoff in many basins as compared to observations. We believe this is a consequence of neglect of the influence of subgrid-scale variations in orography that affects the production of surface runoff.

Sud, Y. C.↗
DOE OSTI2020

Materials Data on SiB by Materials Project

BSi is Wurtzite structured and crystallizes in the hexagonal P6_3mc space group. The structure is three-dimensional. B is bonded to four equivalent Si atoms to form corner-sharing BSi4 tetrahedra. There are one shorter (1.99 Å) and three longer (2.06 Å) B–Si bond lengths. Si is bonded to four equivalent B atoms to form corner-sharing SiB4 tetrahedra.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Nb10(SiB)3 by Materials Project

Nb10(BSi)3 crystallizes in the orthorhombic Fmm2 space group. The structure is three-dimensional. there are four inequivalent Nb+2.10+ sites. In the first Nb+2.10+ site, Nb+2.10+ is bonded to two B3- and three Si4- atoms to form NbSi3B2 trigonal bipyramids that share corners with four equivalent NbSi3B3 octahedra, corners with twelve NbSi3B2 trigonal bipyramids, edges with seven NbSi3B2 trigonal bipyramids, faces with two equivalent NbSi3B3 octahedra, and a faceface with one NbSi3B2 trigonal bipyramid. The corner-sharing octahedra tilt angles range from 42–62°. There are one shorter (2.51 Å) and one longer (2.53 Å) Nb–B bond lengths. There are a spread of Nb–Si bond distances ranging from 2.54–2.69 Å. In the second Nb+2.10+ site, Nb+2.10+ is bonded to three B3- and two equivalent Si4- atoms to form NbSi2B3 trigonal bipyramids that share corners with four equivalent NbSi3B3 octahedra, corners with twelve NbSi3B2 trigonal bipyramids, edges with seven NbSi3B2 trigonal bipyramids, faces with two equivalent NbSi3B3 octahedra, and a faceface with one NbSi2B3 trigonal bipyramid. The corner-sharing octahedra tilt angles range from 42–60°. There are two shorter (2.44 Å) and one longer (2.49 Å) Nb–B bond lengths. Both Nb–Si bond lengths are 2.69 Å. In the third Nb+2.10+ site, Nb+2.10+ is bonded to two equivalent B3- and three Si4- atoms to form NbSi3B2 trigonal bipyramids that share corners with four equivalent NbSi3B3 octahedra, corners with twelve NbSi3B2 trigonal bipyramids, edges with seven NbSi3B2 trigonal bipyramids, faces with two equivalent NbSi3B3 octahedra, and a faceface with one NbSi3B2 trigonal bipyramid. The corner-sharing octahedra tilt angles range from 44–63°. Both Nb–B bond lengths are 2.44 Å. There are one shorter (2.61 Å) and two longer (2.72 Å) Nb–Si bond lengths. In the fourth Nb+2.10+ site, Nb+2.10+ is bonded to three B3- and three Si4- atoms to form distorted NbSi3B3 octahedra that share corners with six equivalent NbSi3B3 octahedra, corners with sixteen NbSi3B2 trigonal bipyramids, and faces with eight NbSi3B2 trigonal bipyramids. The corner-sharing octahedra tilt angles range from 2–56°. There are a spread of Nb–B bond distances ranging from 2.48–2.57 Å. There are one shorter (2.57 Å) and two longer (2.94 Å) Nb–Si bond lengths. There are two inequivalent B3- sites. In the first B3- site, B3- is bonded in a 9-coordinate geometry to eight Nb+2.10+ and one B3- atom. The B–B bond length is 2.06 Å. In the second B3- site, B3- is bonded in a 9-coordinate geometry to eight Nb+2.10+ and one Si4- atom. The B–Si bond length is 2.19 Å. There are two inequivalent Si4- sites. In the first Si4- site, Si4- is bonded in a 9-coordinate geometry to eight Nb+2.10+ and one B3- atom. In the second Si4- site, Si4- is bonded in a 10-coordinate geometry to ten Nb+2.10+ atoms.

36 MATERIALS SCIENCE↗
NASA NTRS1986

A simple biosphere model (SiB) for use within general circulation models

A simple realistic biosphere model for calculating the transfer of energy, mass and momentum between the atmosphere and the vegetated surface of the earth has been developed for use in atmospheric general circulation models. The vegetation in each terrestrial model grid is represented by an upper level, representing the perennial canopy of trees and shrubs, and a lower level, representing the annual cover of grasses and other heraceous species. The vegetation morphology and the physical and physiological properties of the vegetation layers determine such properties as: the reflection, transmission, absorption and emission of direct and diffuse radiation; the infiltration, drainage, and storage of the residual rainfall in the soil; and the control over the stomatal functioning. The model, with prescribed vegetation parameters and soil interactive soil moisture, can be used for prediction of the atmospheric circulation and precipitaion fields for short periods of up to a few weeks.

Sellers, P. J.↗
NASA NTRS1986

A brief description of the simple biosphere model (SiB)

A biosphere model for calculating the transfer of energy, mass, and momentum between the atmosphere and the vegetated surface of the Earth was designed for atmospheric general circulation models. An upper vegetation layer represents the perennial canopy of trees or shrubs, a lower layer represents the annual ground cover of grasses and other herbacious species. The local coverage of each vegetation layer may be fractional or complete but as the individual vegetation elements are considered to be evenly spaced, their root systems are assumed to extend uniformly throughout the entire grid-area. The biosphere has seven prognostic physical-state variables: two temperatures (one for the canopy and one for the ground cover and soil surface); two interception water stores (one for the canopy and one for the ground cover); and three soil moisture stores (two of which can be reached by the vegetation root systems and one underlying recharge layer into and out of which moisture is transferred only by hydraulic diffusion).

Sellers, P. J.↗
NASA NTRS1986

Preliminary analyses of SIB-B radar data for recent Hawaii lava flows

The Shuttle Imaging Radar (SIR-B) experiment acquired two L-band (23 cm wavelength) radar images (at about 28 and 48 deg incidence angles) over the Kilauea Volcano area of southeastern Hawaii. Geologic analysis of these data indicates that, although aa lava flows and pyroclastic deposits can be discriminated, pahoehoe lava flows are not readily distinguished from surrounding low return materials. Preliminary analysis of data extracted from isolated flows indicates that flow type (i.e., aa or pahoehoe) and relative age can be determined from their basic statistics and illumination angle.

Kaupp, V. H.↗
NASA NTRS1989

Effects of implementing the Simple Biosphere Model in a general circulation model

The Simple Biosphere Model (SiB) of Sellers et al., was designed to simulate the interactions between the earth's land surface and the atmosphere by treating the vegetation explicitly and realistically, thereby incorporating the biophysical controls on the exchanges of radiation, momentum, sensible and latent heat between the two systems. This paper describes the steps taken to implement SiB in a modified version of the National Meteorological Center's global spectral general circulation model (GCM) and explores the impact of the implementation on the simulated land surface fluxes and near-surface meteorological conditions. The coupled model (SiB-GCM) was used to produce summer and winter simulations. The same GCM was used with a conventional hydrological model (Ctl-GCM) to produce comparable 'control' summer and winter simulations for comparison. It was found that SiB-GCM produced a more realistic partitioning of energy at the land surface than Ctl-GCM. Generally, SiB-GCM, produced more sensible heat flux and less latent heat flux over vegetated land than did Ctl-GCM and this resulted in a much deeper daytime planetary boundary layer and reduced precipitation rates over the continents in SiB-GCM. In the summer simulation, the 200 mb jet stream was slightly weakened in the SiB-GCM relative to the Ctl-GCM results and analyses made from observations.

Sato, N.↗
DOE OSTI2025

A Perspective on Pathways Toward Commercial Sodium‐Ion Batteries

Lithium-ion batteries (LIBs) have been widely adopted in the automotive industry, with an annual global production exceeding 1000 GWh. Despite their success, the escalating demand for LIBs has created concerns on supply chain issues related to key elements, such as lithium, cobalt, and nickel. Sodium-ion batteries (SIBs) are emerging as a promising alternative due to the high abundance and low cost of sodium and other raw materials. Nevertheless, the commercialization of SIBs, particularly for grid storage and automotive applications, faces significant hurdles. This perspective article aims to identify the critical challenges in making SIBs viable from both chemical and techno-economic perspectives. First, a brief comparison of the materials chemistry, working mechanisms, and cost between mainstream LIB systems and prospective SIB systems is provided. The intrinsic challenges of SIBs regarding storage stability, capacity utilization, cycle stability, calendar life, and safe operation of cathode, electrolyte, and anode materials are discussed. Furthermore, issues related to the scalability of material production, materials engineering feasibility, and energy-dense electrode design and fabrication are illustrated. Finally, promising pathways are listed and discussed toward achieving high-energy-density, stable, cost-effective SIBs.

25 ENERGY STORAGE↗
DOE OSTI2025

Transforming CO 2 to Porous Carbon as a High-Performing Sodium-Ion Battery Anode via Electrochemical Reduction in Molten Carbonates

The prevalence of sodium over lithium prompts exploration of sodium-ion batteries (SIBs) as a viable alternative to lithium-ion batteries (LIBs). Hard carbon has emerged as a promising anode material for SIBs, yet its synthesis poses sustainability challenges and emits pollutants. Here, in this study, we introduce CO 2 -derived porous carbon (graphitic and amorphous) as an anode for SIBs via electrochemical reduction of CO 2 in a molten eutectic carbonate salt at a lower temperature that yields materials with controlled microstructure, morphology, and porosity conducive to energy storage. Our CO 2 -derived carbon demonstrates remarkable specific capacity, superior rate capability, and stable cycling performance as a SIB anode. This innovative strategy harnesses waste CO 2 toward advancing SIB energy technology.

CO2-derived carbon↗
DOE OSTI2023

A Self‐Healing Chemistry‐Enabled Organic Cathode for Sustainable and Stable Sodium‐Ion Batteries

Sodium‐on batteries (SIBs) are promising alternatives to lithium‐ion batteries (LIBs) because of the low cost, abundance, and high sustainability of sodium resources. Analogous to LIBs, the high‐capacity electrodes in SIBs always suffer from rapid capacity decay upon long‐term cycling due to the particle pulverization induced by a large volume change. Circumventing particle pulverization plays a critical role in developing high‐energy and long‐life SIBs. Herein, tetrahydroxy‐1,4‐benzoquinone disodium salt (TBDS) that can self‐heal the cracks by hydrogen bonding between hydroxyl group and carbonyl group is employed as a cathode for sustainable and stable SIBs. The self‐healing TBDS exhibits long cycle life of 1000 cycles with a high rate capability up to 2 A g −1 due to the fast Na‐ion diffusion reaction in the TBDS cathode. The intermolecular hydrogen bonding has been comprehensively characterized to understand the self‐healing mechanism. The hydrogen bonding‐enabled self‐healing organic materials are promising for developing high‐energy and long‐cycle‐life SIBs.

25 ENERGY STORAGE↗
DOE OSTI2023

Understanding High-Voltage Behavior of Sodium-Ion Battery Cathode Materials Using Synchrotron X-ray and Neutron Techniques: A Review

Despite substantial research efforts in developing high-voltage sodium-ion batteries (SIBs) as high-energy-density alternatives to complement lithium-ion-based energy storage technologies, the lifetime of high-voltage SIBs is still associated with many fundamental scientific questions. In particular, the structure phase transition, oxygen loss, and cathode–electrolyte interphase (CEI) decay are intensely discussed in the field. Synchrotron X-ray and neutron scattering characterization techniques offer unique capabilities for investigating the complex structure and dynamics of high-voltage cathode behavior. In this review, to accelerate the development of stable high-voltage SIBs, we provide a comprehensive and thorough overview of the use of synchrotron X-ray and neutron scattering in studying SIB cathode materials with an emphasis on high-voltage layered transition metal oxide cathodes. We then discuss these characterizations in relation to polyanion-type cathodes, Prussian blue analogues, and organic cathode materials. Finally, future directions of these techniques in high-voltage SIB research are proposed, including CEI studies for polyanion-type cathodes and the extension of neutron scattering techniques, as well as the integration of morphology and phase characterizations.

25 ENERGY STORAGE↗