Materials Data on Sn4BRh6 by Materials Project
Rh6BSn4 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Rh is bonded in a 1-coordinate geometry to one B and five Sn atoms. The Rh–B bond length is 2.10 Å. There are a spread of Rh–Sn bond distances ranging from 2.72–2.87 Å. B is bonded in an octahedral geometry to six equivalent Rh atoms. There are three inequivalent Sn sites. In the first Sn site, Sn is bonded in a 6-coordinate geometry to six equivalent Rh atoms. In the second Sn site, Sn is bonded in a 6-coordinate geometry to six equivalent Rh atoms. In the third Sn site, Sn is bonded in a distorted q6 geometry to nine equivalent Rh atoms.
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