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The Effects of Turbulence on Heliosheath Ions and Implications for Energetic Neutral Atoms

The distribution of ions in the heliosheath—the region between the heliospheric termination shock and the heliopause—is important for understanding remote observations of energetic neutral atoms (ENAs). The ion distributions were estimated previously based on hybrid simulations of the heating and evolution of solar wind and interstellar pickup ions across the solar wind termination shock, but these estimates only provide the distributions near the shock. In this work, we use self-consistent hybrid kinetic simulations to investigate the effects of turbulence on ion distributions in the heliosheath. The simulations are compared against Voyager observations, constraining the feasible amplitude and compressibility of turbulence. We find that the heating due to turbulent dissipation can lead to a significant increase in the temperature of thermal solar wind ions. Both turbulent velocity fluctuations and the heating of solar wind ions increase the charge-exchange source for ENAs at low energies (around 100 eV), where current ENA models underpredict observations by more than an order of magnitude. However, the effects of turbulence are likely not strong enough to fully explain these discrepancies.

79 ASTRONOMY AND ASTROPHYSICS↗

Interaction of Inner Heliosheath Ions with Electromagnetic Ion Cyclotron Waves

Abstract Inner heliosheath (IHS) ions are expected to be exposed to various waves, shocks, and turbulence, which can affect ion distributions and thus their charge-exchange rates with interstellar neutral atoms. This work addresses the potential significance of electromagnetic ion cyclotron (EMIC) waves under expected IHS conditions. From a kinetic dispersion relation, we find the possibility of frequent triggering of EMIC instability in the IHS. The threshold anisotropy of proton temperatures required for the instability is small, ( T ⊥ – T ∣∣ )/ T ∣∣ ≈ 0.1 or less, mainly due to high plasma β (ratio of the plasma to magnetic pressures). Numerical calculations on the scattering of ions (protons, He + , and He 2+ with energy of 0.01–50 keV) based on two models for EMIC waves with a moderate intensity indicate significant scattering in the pitch angle (mostly a few tens of degrees) and energy (mostly a few tens of percent) although details depend on the energy and pitch angle of each species and adopted EMIC wave models. This occurs on a short timescale (<100 times the gyro-period of each ion species). Resonant scattering in a few to a few tens of keV (corresponding to the expected pickup ion energy in the IHS) is easily expected unless the wavenumber is too large. The scattering effect is distinguished among different species such that for lower gyrofrequency ions (He + versus He 2+ and He 2+ versus protons), the main scattering effect moves toward a lower energy domain. All these results imply continuous disturbance of ion distributions by possibly prevailing EMIC waves in the IHS.

79 ASTRONOMY AND ASTROPHYSICS↗

Turbulence, Waves, and Taylor’s Hypothesis for Heliosheath Observations

Magnetic field fluctuations measured in the heliosheath by the Voyager spacecraft are often characterized as compressible, as indicated by a strong fluctuating component parallel to the mean magnetic field. However, the interpretation of the turbulence data faces the caveat that the standard Taylor’s hypothesis is invalid because the solar wind flow velocity in the heliosheath becomes subsonic and slower than the fast magnetosonic speed, given the contributions from hot pickup ions (PUIs) in the heliosheath. We attempt to overcome this caveat by introducing a 4D frequency-wavenumber spectral modeling of turbulence, which is essentially a decomposition of different wave modes following their respective dispersion relations. Isotropic Alfvén and fast mode turbulence are considered to represent the heliosheath fluctuations. We also include two dispersive fast wave modes derived from a three-fluid theory. We find that (1) magnetic fluctuations in the inner heliosheath are less compressible than previously thought, an isotropic turbulence spectral model with about 25% in compressible fluctuation power is consistent with the observed magnetic compressibility in the heliosheath; (2) the hot PUI component and the relatively cold solar wind ions induce two dispersive fast magnetosonic wave branches in the perpendicular propagation limit, PUI fast wave may account for the spectral bump near the proton gyrofrequency in the observable spectrum; (3) it is possible that the turbulence wavenumber spectrum is not Kolmogorov-like although the observed frequency spectrum has a −5/3 power-law index, depending on the partitioning of power among the various wave modes, and this partitioning may change with wavenumber.

79 ASTRONOMY AND ASTROPHYSICS↗

Turbulent Acceleration of Interstellar Pickup Ions at the Heliospheric Termination Shock Forms the Global ENA Spectrum

The heliospheric energetic neutral atom spectrum observed by the Interstellar Boundary Explorer (IBEX) reveals that the heliosheath proton distribution is consistent with a power law. The origin of the spectrum is likely from interstellar pickup ions (PUIs) accelerated at the heliospheric termination shock (HTS). We present an explanation of the proton spectrum origin using a test particle simulation of PUIs accelerated at the HTS. PUIs experience preferential heating by the motional electric field in the shock foot, but do not develop a power-law tail without the presence of turbulence at wavenumbers (k) close to the PUI gyroradius scale (R g ). Voyager 2 observations of the magnetic field downstream of the HTS indicate a moderate amount of turbulence at kR g ≅ 1, (δB /B 0 ) 2 @ 0.01, which we find to be sufficient for producing a downstream suprathermal PUI tail but not at intensities observed by IBEX. Within the shock ramp, however, Voyager observed the turbulence power at much smaller scales to be nearly 100 times stronger, suggesting the possibility of strong turbulence at the PUI gyroradius scale. We show that a proton distribution can develop a power law downstream of the HTS consistent with IBEX observations if (δB /B 0 ) 2 ≳ 0.1 at kR g ≅ 1 in the shock foot. Shock drift acceleration of PUIs by the motional electric field is aided by interactions with turbulence upstream of the shock overshoot. Steepening of the IBEX proton spectrum in directions farther from the heliospheric nose suggests the HTS compression ratio and/or turbulence power weakens near the heliotail.

79 ASTRONOMY AND ASTROPHYSICS↗

Evolving Outer Heliosphere: Tracking Solar Wind Transients from 1 au to the VLISM with IBEX and Voyager 1

Abstract Interstellar Boundary Explorer (IBEX) observations of energetic neutral atom (ENA) fluxes from the heliosphere have greatly enriched our understanding of the interaction of the solar wind (SW) with the local interstellar medium (LISM). However, there has been recent controversy surrounding the inability of most ENA models to produce as high an intensity of ∼0.5–6 keV ENAs as IBEX observes at 1 au, especially as a function of time. In our previous study (E. J. Zirnstein et al.), we introduced a new model that utilizes a data-driven magnetohydrodynamic simulation of the SW–LISM interaction to propagate pickup ions through the heliosheath (HS) after they are nonadiabatically heated at the heliospheric termination shock. E. J. Zirnstein et al. only simulated and analyzed IBEX observations from the direction of Voyager 2. In this study, we expand our model to include fluxes from the direction of Voyager 1, as well as in the low-latitude part (middle) of the ribbon (10° below the ecliptic plane). We show that the model results at Voyager 1 are consistent with E. J. Zirnstein et al.’s results at Voyager 2 in terms of a secondary ENA source contribution of ≲20% from both directions. Our results in the middle of the ribbon also reproduce the data, when including a time-dependent secondary ENA source. Finally, we demonstrate with our simulation that three large pressure waves likely merged in the VLISM and were observed by Voyager 1 as “pf2,” while at least one of the wave’s effects in the HS was observed by IBEX as a brief enhancement in ENA flux in early 2016.

79 ASTRONOMY AND ASTROPHYSICS↗

Capacity contributions of Southern Oregon offshore wind to the Pacific Northwest and California

Variable renewable energy generation poses unique capacity challenges, which increasingly depend on weather events at varying timescales. Facilitated by transmission planning, geographic and technological diversity of the generation fleet may provide a mitigation to capacity shortfalls. In this work, offshore wind (OSW) energy is sited in the areas off the West Coast between Coos Bay, Oregon, and Crescent City, California. Three generation and transmission scenarios are modeled within the Western Interconnection: (i) 3.4 gigawatts (GW) of installed OSW capacity connected to Southern Oregon through a High Voltage Alternating Current (HVAC) Radial Topology in 2030; (ii) 12.9 GW of installed OSW capacity connected to Washington, Oregon, and California through a High Voltage Direct Current (HVDC) Radial Topology post-2030, and (iii) the same 12.9 GW connected to the same locations through a Multi-terminal DC (MTDC) Backbone Topology post-2030. Zonal dispatch simulations assuming coincident wind, solar, and hydropower production and loads over 18 meteorological years, accounting for temperature-dependent equipment derating and forced outages, serve as inputs to the Associated System Capacity Contribution (ASCC) methodology. The capacity credit is 33%, 25% and 34% for the 2030 HVAC Radial Topology, 2030+ HVDC Radial Topology, and 2030+ MTDC Backbone Topology, respectively. Transmission design is shown to mitigate the typical erosion of marginal capacity contribution as more OSW is developed, underscoring the opportunity for grid modernization while decarbonizing the generation mix.

17 WIND ENERGY↗

Rotation‐Controlled Diurnal Evolution of Uranus' Asymmetric Bow Shock at Equinox

Uranus possesses the most extreme magnetic and rotational geometry in the solar system, resulting in a uniquely dynamic and asymmetric interaction between its magnetosphere and the solar wind. Here we investigate the diurnal evolution of the Uranian bow shock (BS) at equinox using global multifluid magnetohydrodynamic simulations constrained by Voyager 2 observations. The BS structure and variability are quantified using the stand‐off distance, terminator distance, flaring parameter, and BS parameter, enabling a systematic assessment of its global asymmetry over one planetary rotation. Our results show that the BS exhibits pronounced diurnal asymmetry that is primarily controlled by planetary rotation. Even under steady upstream solar wind conditions, the BS undergoes periodic expansion and contraction, reflecting rotation‐driven reconfiguration of the planetary magnetospheric topology. This diurnal modulation represents a remarkably large asymmetry in planetary BS geometry within the solar system. These results establish planetary rotation as the intrinsic primary driver of Uranus' BS dynamics at equinox and provide essential constraints for the design and formulation of future space missions to the ice giants. These findings also offer a unique framework for understanding shock physics in the abundant population of ice‐giant exoplanets.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Global heliospheric termination shock strength in the solar–interstellar interaction

A heliospheric termination shock (HTS) surrounds our Solar System at approximately 100 astronomical units from the Sun, where the expanding solar wind (SW) is compressed and heated before encountering the interstellar medium. HTS-accelerated particles govern the pressure balance with the interstellar medium, but little is known about the global properties of the HTS beyond in situ measurements from Voyager in only two directions of the sky. Here we fill this gap by extracting the HTS strength using particle-in-cell, test particle and magnetohydrodynamic simulations, constrained by Interstellar Boundary Explorer observations of energetic neutral atoms produced from HTS-accelerated particles. Our results reveal there is a higher compression near the poles during solar minimum compared with solar maximum due to the higher Mach number flow. North–south asymmetries arise from the disparate evolution of the polar coronal holes, while minimum compression near the flanks is probably due to SW slowing from mass loading over a greater distance to the HTS. The results imply a strong connection between the HTS strength and the SW and interstellar medium dynamics.

Astrophysical plasmas↗

Coal Power Plant Reinvestment Visualization Tool

This tool, available at https://energycommunities.gov/coal-power-plant-reinvestment-visualization-tool/, serves as a public database and map for the purposes of enabling state and local economic development officials, project developers, and power plant owners to identify and pursue opportunities for plant and community reinvestment. The Coal Power Plant Reinvestment Visualization Tool focuses on coal power plants that have been closed or set-to-retire, alongside key infrastructure characteristics that are relevant for potential redevelopment reinvestment opportunities, including the opportunity to query these data based off pre-defined or user-set queries to identify opportunities for coal power facility reinvestment to support solar, wind, manufacturing, and nuclear. These Data for visualization and query include, but are not limited to: • Electric Transmission Lines • EPA Brownfield Sites (assessed with Federal funding) • Petroleum Terminals • Ports • Railroads • Others The tool will be updated periodically to provide relevant information to enable state and local economic development officials, project developers, and power plant owners to identify and pursue opportunities for economic revitalization and community reinvestment. Within this application data are focused on U.S. power plants with coal generation, where at least one on-site generator utilizes or utilized coal as a fuel source, including planned retirements through 2058 (EIA, 2024). Additional information on energy communities and revitalization opportunities can be accessed on the Interagency Working Group on Coal & Power Plant Communities & Economic Revitalization Energy Communities website (https://energycommunities.gov).

Closures↗

Response of the Indian Summer Monsoon to Global Warming, Solar Geoengineering and its Termination

The response of the Indian Summer Monsoon (ISM) to global warming, solar geoengineering and its termination is examined using the multi-model mean of eight global climate model simulations from G2 experiment of the Geoengineering Model Intercomparison Project. Under the global warming scenario, land-ocean temperature contrasts and low-level monsoon circulation progressively strengthen accompanied by enhanced precipitation over the Indian subcontinent. Notably, in the solar geoengineered scenario, marginal surface cooling is projected over the majority of the ISM region, and there is strengthening of both upper and lower level circulation. Upon the termination of the geoengineering, the climatic conditions temperature, precipitation, and winds — would abruptly change to what it would have been under the global warming scenario, and such abrupt change may cause devastating consequences.

Bhowmick, Mansi↗

Oblique and rippled heliosphere structures from the Interstellar Boundary Explorer

Abstract Past analysis has shown that the heliosphere structure can be deduced from correlations between long-scale solar wind pressure evolution and energetic neutral atom emissions. However, this required spatial and temporal averaging that smoothed out small or dynamic features of the heliosphere. In late 2014, the solar wind dynamic pressure increased by roughly 50% over a period of 6 months, causing a time and directional-dependent rise in around 2–6 keV energetic neutral atom fluxes from the heliosphere observed by the Interstellar Boundary Explorer. Here, we use the 2014 pressure enhancement to provide a simultaneous derivation of the three-dimensional heliospheric termination shock (HTS) and heliopause (HP) distances at high resolution from Interstellar Boundary Explorer measurements. The analysis reveals rippled HTS and HP surfaces that are oblique with respect to the local interstellar medium upwind direction, with significant asymmetries in the heliosphere structure compared to steady-state heliosphere models. We estimate that the heliosphere boundaries contain roughly ten astronomical unit-sized spatial variations, with slightly larger variations on the HTS surface than the HP and a large-scale, southwards-directed obliquity of the surfaces in the meridional plane. Comparisons of the derived HTS and HP distances with Voyager observations indicate substantial differences in the heliosphere boundaries in the northern versus southern hemispheres and their motion over time.

79 ASTRONOMY AND ASTROPHYSICS↗

Probing the Magnetosheath Boundaries Using Interstellar Boundary Explorer (IBEX) Orbital Encounters

Inside the magnetosheath, the IBEX-Hi energetic neutral atom (ENA) imager measures a distinct background count rate that is more than 10 times the typical heliospheric ENA emissions observed when IBEX is outside the magnetosheath. The source of this enhancement is magnetosheath ions of solar wind (SW) origin that deflect around the Earth's magnetopause (MP), scatter and neutralize from the anti-sunward part of the IBEX-Hi sunshade, and continue into the instrument as neutral atoms, behaving indistinguishably from ENAs emitted from distant plasma sources. While this background pollutes observations of outer heliospheric ENAs, it provides a clear signature of IBEX crossings over the magnetospheric boundaries. In this study, we investigate IBEX encounters with the magnetosheath boundaries using ~8 yr of orbital data, and we determine the MP and bow shock (BS) locations derived from this background signal. We find 280 BS crossings from X GSE ~ 11 R e to X GSE ~ –36 R e and 241 MP crossings from X GSE ~ 6 R e to X GSE ~ –48 R e . We compare IBEX BS and MP crossing locations to those from IMP-8, Geotail, Cluster, Magion-4, ISEE, and Magnetospheric Multiscale Mission, and we find that IBEX crossing locations overlap with the BS and MP locations inferred from these other data sets. In this paper, we demonstrate how IBEX can be used to identify magnetosheath crossings, and extend boundary observations well past the terminator, thus further constraining future models of magnetosheath boundaries. Furthermore, we use the IBEX data set to show observational evidence of near-Earth magnetotail squeezing during periods of strong interplanetary magnetic field B y .

79 ASTRONOMY AND ASTROPHYSICS↗

Electrolyte and Cutoff Potential Effects on Cycle Life of Li4Ti5O12/LiNi0.9Mn0.1O2 Batteries for Behind-the-Meter Storage Applications

Behind-the-Meter Storage (BTMS) is a stationary battery energy storage system that is connected to the electrical distribution system on the customer's side of the utility's service meter. BTMS systems are used to store electrical energy from the grid as well as inconstant, renewable energy, such as local solar and wind generation. A successful BTMS system will allow the customer to pair their energy generation and storage to optimize electrical consumption from the grid, improving reliability and minimizing cost. For BTMS applications, batteries must be designed and optimized with different set of criteria from other leading segments of the Li-ion battery market, like transportation, due the system being stationary and proximal to the residential or commercial building it's benefitting. BTMS applications prioritize safety, cost (low/no-critical materials), reliability (20-year calendar life), and durability (10,000 cycle life), while having the ability to (minimally) compromise energy density and rate capability. Lithium titanate (Li4Ti5O12-, LTO) is a promising anode candidate for BTMS applications due to its high safety and capacity retention, while maintaining a reasonable 160 mAhg-1 reversable capacity and composition of relatively abundant materials. (1) Specifically, LTO has a high working voltage which helps to prevent Li dendrite formation, improving safety. Furthermore, LTO also has negligible lithiation-based volume change, leading to less mechanical pulverization, or loss of active material, upon cycling. For the cathode, materials with little or no Co are of high interest due to the high cost and low abundance of Co. LiMn2O4 (LMO) has been paired with LTO for BTMS applications in the past due to its safety, low cost (abundancy), and reasonably high operating voltage. (2-4) However, the low capacity of LMO limits energy density and specific energy. While not the highest priority for BTMS applications, increasing energy density will enable deployment in space constrained BTMS applications and decrease total cost. LiNi0.9Mn0.1O2 (LN-MO) is a recently developed material with promise due to its high operating voltage and relatively low price. (5) However, Ni-rich layered oxides, including LNMO, tend to struggle with capacity retention during high-voltage cycling due to mechanical pulverization, irreversible phase transitions, and unstable solid-electrolyte interphase. The study presented here focuses on building an understanding of how electrolyte solvent and varied cutoff potentials will impact the cycle life of LTO/LN-MO cells. Specifically, a comparison is provided between ethylene carbonate (EC), ethyl methyl carbonate (EMC), fluoroethylene carbonate (FEC), and Gen2 electrolyte solvents with 1M Lithium hexafluorophosphate (LiPF6) salt, cycling to two upper termination potentials, 2.6V and 2.7V. Electrochemical testing and diagnostics (e.g., differential capacity analysis, area specific impedance, constant voltage hold, and rate capability) and post-mortem characterization will be used to understand the aging behavior and failure mechanisms of the 8 cell combinations (four electrolytes and two voltage cutoffs). Cells with FEC electrolyte showed a lower initial capacity compared to cells with Gen2, EMC, and EC cycling at both voltages; however, the cells with FEC showed consistent trends in capacity retention with 2.6V and 2.7V termination potentials, while the cells with the other electrolytes showed much higher rates of capacity loss when cycling to the higher voltage. These results indicate that FEC may play a role in improving durability of high-voltage, Ni-rich electrode systems for use in high-cycle applications, such as BTMS.

electrolyte↗

Photoelectrocatalytic reduction of CO 2 to formate using immobilized molecular manganese catalysts on oxidized porous silicon

The reduction of carbon dioxide (CO 2 ) to formate using molecular catalysts immobilized on high surface area porous silicon is described. Manganese complexes of the type ( R bpy)Mn(CO) 3 Br (bpy = 2,2′-bipyridine) were prepared with silatrane groups on the bpy ligand for attachment to oxide-coated porous silicon (SiO x -porSi). SiO x -porSi wafers were formed by heating hydrogen-terminated p-type porous silicon wafers under air, and the manganese complexes were immobilized on SiO x -porSi by heating at 80°C. The resulting hybrid photoelectrodes are photoelectrocatalysts for CO 2 reduction in acetonitrile containing 2.0 M triethylamine and 2.0 M isopropanol, yielding formate with high selectivity (>96%) and current density (∼0.6 mA/cm 2 ), excellent reproducibility, and a photovoltage of 280 mV at −1.75 V (versus ferrocenium/ferrocene) under 1 sun illumination. Here, the applied potential is close to the equilibrium potential for CO 2 reduction to formate. This work presents rare examples of immobilized molecular catalysts for CO 2 reduction to formate and the first on semiconducting silicon.

13 HYDRO ENERGY↗