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Results for “Spatially Resolved Thermochemistry”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2018

Characterization of CO Thermochemistry in Incident Shockwaves

Incident shock waves in pure CO have been characterized in the Electric Arc ShockTube facility at NASA Ames Research Center. Spectrally and spatially resolved emissionspectra characterize radiative signatures from CO in the VUV and mid-infrared and atomiccarbon and C2 in the visible. CO absorption of a single vibrational line is also measuredwith a tunable diode laser. The experimental data analyzed here are at a pressure of 0.25Torr in the driven section and span a shock velocity range from 3.4-9.5 km/s. The emissionand absorption signals are analyzed to extract temperature relaxation behind the shockwhich is used to derive the rate of CO dissociation. The emission spectra are compared toresults using different kinetic parameters for CO dissociation and C2 dissociation andexchange. Different rates from the literature are found to match the data from 3.4-6.6 km/sand 6.6-9.5 km/s. Areas for improvement in CO and C2 radiation modeling are suggested onthe basis of the analysis.

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NASA NTRS2018

Characterization of CO Thermochemistry in Incident Shockwaves

Incident shock waves in pure CO have been characterized in the Electric Arc Shock Tube facility at NASA Ames Research Center. Spectrally and spatially resolved emission spectra characterize radiative signatures from CO in the VUV (Vacuum Ultra-Violet) and mid-infrared and atomic carbon and C2 in the visible. CO absorption of a single vibrational line is also measured with a tunable diode laser. The experimental data analyzed here are at a pressure of 0.25 Torr in the driven section and span a shock velocity range from 3.4-9.5 km/s. The emission and absorption signals are analyzed to extract temperature relaxation behind the shock which is used to derive the rate of CO dissociation. The emission spectra are compared to results using different kinetic parameters for CO dissociation and C2 dissociation and exchange. Different rates from the literature are found to match the data from 3.4-6.6 km/s and 6.6-9.5 km/s. Areas for improvement in CO and C2 radiation modeling are suggested on the basis of the analysis.

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