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Charge-state model for lead/acid batteries proposed as part of effort to make equivalent of fuel gage for battery-powered vehicles. Models based on equations that approximate observable characteristics of battery electrochemistry. Uses linear equations, easier to simulate on computer, and gives smooth transitions between charge, discharge, and recuperation.
Detailed measurements of the charge state composition of energetic heavy ions in the diffuse component are presented for the first time. Spectral characteristics and charge state measurements for 12 diffuse ion events observed upstream of the earth's bow shock are reported. One event is analyzed in order to illustrate the basic assumptions and general techniques involved in the determination of charge state composition from the data. The probable solar wind origin of the seed population of the diffuse component is used together with the charge state composition of these heavy ions to estimate the charge state composition in the concurrent solar wind, and hence to infer the equilibrium coronal temperatures associated with a variety of solar wind flows. The results are compared with predicted solar wind values.
The charge states of ions injected during substorms are discussed. Observations from the Medium Energy Particle Analyzer (McEntire et al., 1985) are used to time the arrival of peak proton, helium, and oxygen fluxes at the Charge Composition Explorer satellite. In addition, the dominant ion charge states of these species in the energy range 72-1000 keV are determined. It is found that the freshly-injected heluim (72-240 keV) and oxygen (137-365 keV) are singly ionized, but that more energetic oxygen (greater than 365 keV) is multiply charged. It is suggested that this result implies either a dominant ionospheric source at the lower energies with a solar-wind source at the higher energies, or an energization of the preexisting ring-current population.
Observations of charge state distributions of oxygen and carbon are presented that were obtained with the charge-energy-mass spectrometer onboard the AMPTE/CCE spacecraft. Data were selected for two different local time sectors (apogee at 1300 LT and 0300 LT, respectively), three L-ranges (4-6, 6-8, and greater than 8), and quiet to moderately disturbed days (Kp less than or equal to 4). The charge state distributions reveal the existence of all charge states of oxygen and carbon in the magnetosphere. The relative importance of the different charge states strongly depends on L and much less on local time. The observations confirm that the solar wind and the ionosphere contribute to the oxygen population, whereas carbon only originates from the solar wind. The L-dependence of the charge state distributions can be interpreted in terms of these different ion sources and of charge exchange and diffusion processes that largely influence the distribution of oxygen and carbon in the magnetosphere.
The paper describes an experiment consisting of the acceleration of N(+) and N2(+) ions to energies between 0.25 and 1.75 MeV and their injection through a thin carbon foil, whereupon they were charge-state analyzed with an electrostatic analyzer. A foil-covered electrically suppressed Faraday cup, connected to a stepping motor, moved in the plane of the dispersed beams. The Faraday cup current, which was proportional to the number of incident ions, was sent to a current digitizer and computer programmed as a multiscaler. The energy-dependent charge-state fractions, the mean charge and the distribution width were calculated. It was shown that for incident atoms, the charge state distribution appeared to be spread over more charge states, while for the incident molecules, there was a greater fraction of charge states near the mean charge.
The Solar Wind Ion Composition Spectrometer (SWICS) onboard Ulysses allows determination of the elemental composition of the solar wind and the charge states of all major solar wind ion species. Ulysses left the ecliptic plane in early 1992, crossed the Sun's south polar region in late 1994 and made a fast approach back towards the ecliptic in the first half of 1995. Data from this period were investigated for long-term variations in the solar wind composition. At midlatitudes Ulysses encountered periodically the fast solar wind stream emerging from the south coronal hole. As a consequence, dramatic variations in the charge-states arise, between high charge-states dominating in the current sheet solar wind and low charge states in the coronal hole stream. However, the initial analysis indicates that from midlatitudes onwards, with Ulysses permanently immersed in the coronal hole stream, the charge state and elemental abundance ratios of the major solar wind ion species stayed essentially constant. This implies that the temperature profile in the coronal hole at solar wind source altitudes exhibit no variation with solar latitude. It confirms that the south coronal hole is essentially unstructured down to scale lengths of several degrees in solar latitude.
The ionic charge states of helium, carbon, oxygen, and iron have been determined for three solar particle enhancements by an electrostatic deflection analyzer, which is combined with a thin window proportional counter dE/dX vs. E system. The observations are obtained during the periods September 23 to 29, 1978, June 6 to 8, 1979, and September 15 to 26, 1979, with an instrument onboard the ISEE-3 spacecraft. The mean ionic charge states for He, C, and oxygen exhibit a high degree of ionization with values of Q equals 2, 6, and 7.2, respectively. The charge state of iron is near 13 charge units. Variations from flare to flare and within the September 23, 1978 flare are small. The most surprising feature of the charge state measurement is the observation of a small (about 10%) but finite contribution of singly ionized helium.
The ionic charge state of anomalous cosmic-ray oxygen has been determined by comparing measurements obtained inside the magnetosphere on a series of Cosmos satellite flights with simultaneous observations outside the magnetosphere from IMP 8 and ICE. A mean charge state of 0.9 + 0.3, - 0.2 is found for abount 10 MeV/nucleon anomalous oxygen, consistent with the model of Fisk et al. (1974), in which the anomalous cosmic rays originate from the neutral component of the local interstellar medium. This same approach gives results consistent with a mean charge state of +7 for solar energetic oxygen ions.
Iron and silicon/sulfur charge state and velocity measurements and iron density measurements in the shocked solar wind which preceded the flare-related driver plasma observed on September 29, 1978 by ISEE 3 are reported. Given the assumption that the driver plasma is magnetically isolated from the ambient solar wind, the contact surface separating these two plasma regimes is expected to form an distinct boundary in the charge state composition. Instead, an apparent transition in the ionization state of the shocked solar wind from ambient solar wind values to those typical of the driver plasma is observed. This result may reflect X-ray ionization of the solar wind plasma near the flare site.
The charge states of energetic iron have been measured directly for the first time in a solar particle event. In the energy interval 0.01 to 0.25 MeV per nucleon, iron is not fully stripped but has a mean ionization state of 11.6. This value is remarkably similar to the mean ionization state of iron in the quiet solar wind and suggests that the charge states were "frozen-in" at a coronal temperature of approximately 1,500,000 K.
The charge states of energetic iron have been measured directly in a solar particle event on May 14-15, 1974. It is found that in the energy interval 0.01-0.25 MeV per nucleon, iron is not fully stripped but has a mean ionization state of 11.6 to 150 keV per nucleon. This value is remarkably similar to the mean ionization state of iron in the quiet solar wind and suggests that the charge states were 'frozen-in' before acceleration at a coronal temperature of about 1.5 million K.
The excited state charge transfer for a series of highly fluorescent dyes containing thiophenylimidazole moiety was investigated. These systems follow the Twisted Intramolecular Charge Transfer (TICT) model. Dual fluorescence was observed for each substituted dye. X-ray structures analysis reveals a twisted ground state geometry for the donor substituted aryl on the 4 and 5 position at the imidazole ring. The excited state charge transfer was modeled by a linear solvation energy relationship using Taft's pi and Dimroth's E(sub T)(30) as solvent parameters. There is linear relation between the energy of the fluorescence transition and solvent polarity. The degree of stabilization of the excited state charge transfer was found to be consistent with the intramolecular molecular charge transfer. Excited dipole moment was studied by utilizing the solvatochromic shift method.
Numerical calculations of the charge state distributions of test ions in a hot plasma under nonequilibrium conditions are presented. The mean ionic charges of heavy ions for finite residence times in an instantaneously heated plasma and for a non-Maxwellian electron distribution function are derived. The results are compared with measurements of the charge states of solar energetic particles, and it is found that neither of the two simple cases considered can explain the observations.
Ionic charge state measurements of carbon, oxygen, and iron in He(+)-rich energetic particle events are presented. The data have been obtained with the Max-Planck-Institut/University of Maryland sensor system on the ISEE 3 spacecraft. The ionic charge states cannot be explained in terms of a model in which the coronal temperature determines a charge equilibrium which is subsequently frozen-in nor in terms of charge exchange during transition through coronal matter after acceleration. It is concluded that the acceleration and probably also the injection process is biased against particles with high mass-to-charge ratios. The plasma injected into the acceleration process must consist of material of cold (not greater than 8.5 x 10 to the 4th K) as well as hot (2.5 x 10 to the 6th K) origin. The cold material must be more abundant than the hot material.
The study carried out in order to demonstrate that high minor ion outflow speeds of the order of O(5+) outflow speed are consistent with charge state observations is presented. The calculations were based on atomic data, observational constraints concerning electron temperatures, electron densities and flow speeds. Minor ion charge state observations were used in order to place limits on solar wind acceleration and heating mechanisms. The charge states of C, O, Fe and Si ions measured in situ were compared to those calculated from two solar wind models. The use of the planned ultraviolet and charge state observations in order to constrain both the ion outflow speeds and electron temperature is discussed.
Charge states of argon produced by bombardment with 100-keV to 1-MeV H+ and He+ projectiles were studied by examining high-resolution L-shell X-ray satellite spectra. Large differences appear in charge-state populations determined from X-ray data and Auger-electron data.-
The elemental composition and charge state distributions of heavy ions of the solar wind provide essential information about: (1) atom-ion separation processes in the solar atmosphere leading to the 'FIP effect' (the overabundance of low First Ionization potential (FIP) elements in the solar wind compared to the photosphere); and (2) coronal temperature profiles, as well as mechanisms which heat the corona and accelerate the solar wind. This information is required for solar wind acceleration models. The SWICS instrument on Ulysses measures for all solar wind flow conditions the relative abundance of about 8 elements and 20 charge states of the solar wind. Furthermore, the Ulysses high-latitude orbit provides an unprecedented look at the solar wind from the polar coronal holes near solar minimum conditions. The MASS instrument on the WIND spacecraft is a high-mass resolution solar wind ion mass spectrometer that will provide routinely not only the abundances and charge state of all elements easily measured with SWICS, but also of N, Mg, S. The MASS sensor was fully operational at the end of 1994 and has sampled the in-ecliptic solar wind composition in both the slow and the corotating fast streams. This unique combination of SWICS on Ulysses and MASS on WIND allows us to view for the first time the solar wind from two regions of the large coronal hole. Observations with SWICS in the coronal hole wind: (1) indicate that the FIP effect is small; and (2) allow us determine the altitude of the maximum in the electron temperature profile, and indicate a maximum temperature of approximately 1.5 MK. New results from the SMS instruments on Wind will be compared with results from SWICS on Ulysses.
It has long been known that low-energy solar energetic particles (SEP's) are partially-ionized. For example, in large, so-called 'gradual' solar energetic particle events, at approximately 1 MeV/nucleon the measured mean ionic charge state, Q, of Fe ions is 14.1 +/- 0.2, corresponding to a plasma temperature of approximately 2 MK in the coronal or solar-wind source material. Recent studies, which have greatly clarified the origin of solar energetic particles and their relation to solar flares, suggest that ions in these SEP events are accelerated not at a flare site, but by shocks propagating through relatively low-density regions in the interplanetary medium. As a result, the partially-ionized states observed at low energies are expected to continue to higher energies. However, up to now there have been no high-energy measurements of ionic charge states to confirm this notion. We report here HIIS observations of Fe-group ions at 50-600 MeV/nucleon, at energies and fluences which cannot be explained by fully-ionized galactic cosmic rays, even in the presence of severe geomagnetic cutoff suppression. Above approximately 200 MeV/nucleon, all features of our data -- fluence, energy spectrum, elemental composition, and arrival directions -- can be explained by the large SEP events of October 1989, provided that the mean ionic charge state at these high energies is comparable to the measured value at approximately 1 MeV/nucleon. By comparing the HIIS observations with measurements in interplanetary space in October 1989, we determine the mean ionic charge state of SEP Fe ions at approximately 200-600 MeV/nucleon to be Q = 13.4 plus or minus 1.0, in good agreement with the observed value at approximately 1 MeV/nucleon. The source of the ions below approximately 200 MeV/nucleon is not yet clear. Partially-ionized ions are less effectively deflected by the Earth's magnetic field than fully-ionized cosmic rays and therefore have greatly enhanced access to low-Earth orbit. Moreover, at the high energies observed in HIIS, these ions can penetrate typical amounts of shielding. We discuss the significance of the HIIS results for estimates of the radiation hazard posed by large SEP events to satellites in low-Earth orbit, including the proposed Space Station orbit. Finally, we comment on previous reports of low-energy below-cutoff Fe-group ions, which some authors have interpreted as evidence for partially-ionized galactic cosmic rays. The LDEF flux levels are much smaller than the corresponding fluxes in these previous reports, implying that the source of these ions has an unusual solar-cycle variation and/or strongly increases with decreasing altitude.