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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Direct URCA process in neutron stars

It is shown that the direct URCA process can occur in neutron stars if the proton concentration exceeds some critical value in the range 11-15 percent. The proton concentration, which is determined by the poorly known symmetry energy of matter above nuclear density, exceeds the critical value in many current calculations. If it occurs, the direct URCA process enhances neutrino emission and neutron star cooling rates by a large factor compared to any process considered previously.

Lattimer, James M.↗

Low energy, left-right symmetry restoration in SO(N) GUTS

A general n step symmetry breaking pattern of SO(4K+2) down to SU sub C (3)xSU sub L (2)xU sub Y (1), which uses regular subgroups only, does not allow low energy left right symmetry restoration. In these theories, the smallest mass scale at which such restoration is possible is approximately one billion GeV as in the SO(10) case. The unification mass in SO(4K+2) GUTS must be at least as large as that in SU(5). These results assumed standard values of the Weinberg angle and strong coupling constant.

Holman, R.↗

Frequency based localization of structural discrepancies

The intent of modal analysis is to develop a reliable model of a structure by working with the analytical and experimental modal properties of frequency, damping and mode shape. In addition to identifying these modal properties, it would be desirable to determine spatially which parts of the structure are modelled poorly or well. It is shown how the pattern of discrepancies in the analytical and experimental test values for the pole and the driving point zero frequencies of a structure can be linked to discrepancies in the mass or stiffness of the structural elements. The success of the procedure depends on the numerical conditioning of a modal reference matrix. Strategies to insure adequate numerical conditioning require a formulation which avoids geometric and energy storage symmetries of the structure, and ignores structural elements which contribute negligibly small potential or kinetic energy to the excited modes. Physical insight into the numerical conditioning problem is provided by a numerical example and by localization of a mass discrepancy in a real structure based on lab tests.

Shepard, G. D.↗

Tropical Ocean Surface Energy Balance Variability: Linking Weather to Climate Scales

Radiative and turbulent surface exchanges of heat and moisture across the atmosphere-ocean interface are fundamental components of the Earth s energy and water balance. Characterizing the spatiotemporal variability of these exchanges of heat and moisture is critical to understanding the global water and energy cycle variations, quantifying atmosphere-ocean feedbacks, and improving model predictability. These fluxes are integral components to tropical ocean-atmosphere variability; they can drive ocean mixed layer variations and modify the atmospheric boundary layer properties including moist static stability, thereby influencing larger-scale tropical dynamics. Non-parametric cluster-based classification of atmospheric and ocean surface properties has shown an ability to identify coherent weather regimes, each typically associated with similar properties and processes. Using satellite-based observational radiative and turbulent energy flux products, this study investigates the relationship between these weather states and surface energy processes within the context of tropical climate variability. Investigations of surface energy variations accompanying intraseasonal and interannual tropical variability often use composite-based analyses of the mean quantities of interest. Here, a similar compositing technique is employed, but the focus is on the distribution of the heat and moisture fluxes within their weather regimes. Are the observed changes in surface energy components dominated by changes in the frequency of the weather regimes or through changes in the associated fluxes within those regimes? It is this question that the presented work intends to address. The distribution of the surface heat and moisture fluxes is evaluated for both normal and non-normal states. By examining both phases of the climatic oscillations, the symmetry of energy and water cycle responses are considered.

Roberts, J. Brent↗

Electron impact spectroscopy

The concepts of electron impact spectroscopy are discussed, comparing the electron spectroscopy techniques with those of the optical spectroscopy. The main advantage of the electron spectroscopy is to be found in the elimination of optical selection rules in excitation processes and the ability to scan the spectrum from the infrared to the X-ray region. The range of the method is indicated through a review of several examples, including electron impact excitation of Ba and rotational excitation of H2. The sensitivity of the method is demonstrated by vibrational excitation spectrum of N2. It is shown that the application of the method to the inner-shell excitation allows to obtain information about molecular species which are not commonly available, while spectroscopy of negative ions yields information about their energy and symmetry properties. However, the techniques are still under development and more data are expected to become available in the coming years.

Trajmar, S.↗

Ground and lower excited states of methyl peroxy, CH3O2, radical - A computational investigation

The ground and lower excited states of methyl peroxy, CH3O2, radical have been investigated at the selected pseudofirst-order configuration interaction level by use of a double-zeta basis set. Selected singles and doubles calculations using a polarized double-zeta basis have been carried out on the two lowest states in the A-double prime symmetry. Dissociation energies with respect to CH3O2 yields CH3 + O2 and CH3O + O are computed to be 2.01 and 3.37 eV, respectively. Curve crossings between various states and photodissociation products are discussed and the dipole moment along various slices through the potential energy surface is evaluated.

Jafri, Jawed A.↗

Concerted hydrogen atom exchange between three HF molecules

We have investigated the termolecular reaction involving concerted hydrogen exchange between three HF molecules, with particular emphasis on the effects of correlation at the various stationary points along the reaction. Using an extended basis, we have located the geometries of the stable hydrogen-bonded trimer, which is of C(sub 3h) symmetry, and the transition state for hydrogen exchange, which is of D(sub 3h) symmetry. The energies of the exchange reation were then evaluated at the correlated level, using a large atomic natural orbital basis and correlating all valence electrons. Several correlation treatments were used, namely, configration interaction with single and double excitations, coupled-pair functional, and coupled-cluster methods. We are thus able to measure the effect of accounting for size-extensivity. Zero-point corrections to the correlated level energetics were determined using analytic second derivative techniques at the SCF level. Our best calculations, which include the effects of connected triple excitations in the coupled-cluster procedure, indicate that the trimer is bound by 9 +/- 1 kcal/mol relative to three separate monomers, in excellent agreement with previous estimates. The barrier to concerted hydrogen exchange is 15 kcal/mol above the trimer, or only 4.7 kcal/mol above three separated monomers. Thus the barrier to hydrogen exchange between HF molecules via this termolecular process is very low.

Komornicki, Andrew↗

Gyroscopic Motion of an Unsymmetrical Satellite Under No External Forces

This report gives the results of an investigation on the transition from spin about the axis of minimum moment of inertia to spin about the axis of maximum moment of inertia by dissipation of internal mechanical energy. A mathematical discussion, together with charts and diagrams, shows that angular velocities and nutation angle are dependent on the energy and symmetry factors. The low stability of rotation about the axis of maximum moment of inertia, when this inertia is only slightly greater than the mean moment of inertia, is shown.

Kuebler, Manfred E.↗

The calculation of the contributions to low energy e+H2 scattering from sigma u+ and Pion u symmetries using the Kohn variational method

Above incident energies of about 2 eV, the contribution to the total cross section in positron+H2 scattering from the sigma g+ symmetry is insufficient to account for the experimental value. Calculations carried out of the lowest partial waves of sigma u+ symmetry and Pion u symmetry using the Kohn variational method are described. The contributions to the total cross section from the two equivalent partial waves of Pion u symmetry significantly reduce the discrepancy with experiment up to incident energies of 4 to 5 eV. Comparisons are made with recent R-matrix calculations performed by Danby and Tennyson.

Armour, E. A. G.↗