Analysis of failures of thermionic converters.
Thermionic converters failure, discussing life tests, mechanical defects and design and processing deficiencies
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Thermionic converters failure, discussing life tests, mechanical defects and design and processing deficiencies
Thermionic converters with chloride and fluoride vapor deposited tungsten emitters, comparing performance characteristics and stability
Thermionic converter metallography relationship between materials and fabrication methods and reliable performance life
SET program developments, and four-converter thermionic generator thermal analysis and performance characteristics
Improving thermionic power conversion devices through various material design configurations
Thermionic research has been conducted to investigate a hybrid-mode thermionic converter as a candidate for reducing the barrier index. The hybrid-mode thermionic converter is designed to operate in a combination ignited mode and unignited mode by using a series of parallel grooves in the emitter. The emitter material is molybdenum and the non-grooved land area is thinly coated with rhenium metal. When the emitter is exposed to cesium vapor, as it is during the converter operation, the rhenium-coated land area achieves a lower work function than the grooved molybdenum surface by as much as 0.5 eV. The low work function land area provides a major portion of electron emission, and the high work function grooved area provides cesium ions required for efficient transport of electrons generated in adjacent land areas to the collector. Experimental results obtained from two different converters and a numerical analysis of converter characteristics are presented in this paper.
Cylindrical thermionic converter with vapor deposited rhenium emitter and niobium collector, measuring efficiency and power density
Thermionic converter tests, discussing W emitter with Nb and Mo-on-Nb collectors, surface and electrode combinations
Thermionic cesium diode converter with cavity emitters
Performance of thermionic converters, discussing voltage output, interelectrode spacing, rhenium- rhenium and rhenium-molybdenum electrode systems
A thermionic system concept is described which incorporates a heat-pipe cooled fast spectrum reactor and six-cell thermionic converter modules located in the space radiator. Much of the technology being developed for the in-core thermionic reactor concept is directly applicable to this out-of-core concept, particularly the fuel and converter development activity. The major technology extension required is in the area of heat-pipes for cooling the reactor and carrying thermal energy from the reactor station to the converters. The performance characteristics of an out-of-core thermionic system at power levels between 40 and 70 kWe are summarized, the adaptation of in-core technology to the out-of-core concept is described and applicable heat-pipe technology programs now underway are discussed.
Cesium vapor thermionic converters are an attractive method of converting high-temperature heat directly to electricity, but theoretical descriptions of the systems have been difficult due to the multi-step ionization of Cs through inelastic electron–neutral collisions. This work presents particle-in-cell simulations of these converters, using a direct simulation Monte Carlo collision model to track 52 excited states of Cs. Here, these simulations show the dominant role of multi-step ionization, which also varies significantly based on both the applied voltage bias and pressure. The electron energy distribution functions are shown to be highly non-Maxwellian in the cases analyzed here. A comparison with previous approaches is presented, and large differences are found in ionization rates due especially to the fact that previous approaches have assumed Maxwellian electron distributions. Finally, an open question regarding the nature of the plasma sheaths in the obstructed regime is discussed. The one-dimensional simulations did not produce stable obstructed regime operation and thereby do not support the double-sheath hypothesis.
Mo/Mo cylindrical thermionic converter steady state performance, measuring efficiency and power density at various low emitter and collector temperatures
Two cylindrical thermionic energy converters similar to those in a flashlight thermionic fuel element were tested electrically at the Jet Propulsion Laboratory. One converter was not fueled, but the other was fueled with UO2 imbedded in six pencil-lead-size holes in the emitter, which was made of rhenium. The nonfueled converters showed no change in its performance during 4000 hr of testing, whereas the output current of the UO2-fueled converter degraded 15% during 2400 hr of testing at 2000 K. Measurements on the UO2-fueled converter showed an increase in the collector work function and an increase in the bare emitter work function. The degradation appears to be caused primarily by foreign deposits on the collector, probably uranium that diffused from the UO2 fuel through the emitter.
A thermionic converter module simulating a configuration for an out-of-core thermionic nuclear reactor was designed, fabricated, and tested. The module consists of three cylindrical thermionic converters. The tungsten emitter of the converter is heated by a tungsten, lithium heat pipe. The emitter heat pipes are immersed in a furnace, insulated by MULTI-FOIL thermal insulation, and heated by tungsten radiation filaments. The performance of each thermionic converter was characterized before assembly into the module. Dynamic voltage, current curves were taken using a 60 Hz sweep and computerized data acquisition over a range of emitter, collector, and cesium-reservoir temperatures. An output power of 215 W was observed at an emitter temperature of 1750 K and a collector temperature of 855 K for a two diode module. With a three diode module, an output power of 270 W was observed at an average emitter temperature of 1800 K and a Collector temperature of 875 K.
Rhenium Nb cylindrical thermionic converter, measuring efficiency and power density in emitter temperature range 1600-2050 K and collector temperature range 873-1173 K
Low temperature cylindrical thermionic converters with CVD Re electrodes, discussing design, fabrication and performance
An externally configured thermionic converter was operated for 200 h. The converter was disassembled and examined to determine internal changes as a result of operation. The metal/ceramic seals and all joints were unaffected by operation. Converter output voltage and operational time were sufficient to produce electrolysis of stabilized zirconia spacers used in the converter. Surface analysis of the electrode surfaces indicated the presence on the tungsten emitter of only oxygen, carbon, and silicon. The niobium collector was, however, 25 to 40% covered with other elements. This coverage represented all elements present within the converter as construction materials other than silicon and tungsten, which were not detected on the collector, and carbon, which was detected only in small amounts.