Nanodomains and Their Temperature Dependence in a Phosphonium-Based Ionic Liquid: A Single-Molecule Tracking Study
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Summary of western burrowing owl satellite-tracking study on the NNSS for the Fall issue of the Nevada Chapter of The Wildlife Society Newsletter.
It is essential to understand the effectiveness of any training program so it can be improved accordingly. Various studies have applied standard metrics for the evaluation of visual behavior to recognize the areas of interest that attract individuals’ attention as there is a high correlation between attentional behavior and where one is focusing on. However, through reviewing the literature, we believe that studies that applied eye-tracking technologies for training purposes are still limited, especially in the industrial energy assessment training field. In this paper, the effectiveness of industrial energy assessment training was quantitatively evaluated by measuring the attentional allocation of trainees using eye-tracking technology. Moreover, this study identifies the areas that require more focus based on evaluating the performance of subjects after receiving the training. Additionally, this research was conducted in a controlled environment to remove the distractions that may be caused by environmental factors to only concentrate on variables that influence the learning behavior of subjects. The experiment results showed that after receiving the training, the subjects’ performance in energy assessment was significantly improved in two areas: production, and recycling and waste management, and the designed training program enhanced the knowledge of participants in identifying energy-saving opportunities to the knowledge level of experienced participants.
The Cornell-Brookhaven Energy-Recovery-Linac Test Accelerator will have two splitter sections responsible for and guiding beams of 42, 78, 114, and 150 MeV energies between the Fixed-Field Alternating Gradient return loop and the Main Linac Cryomodule [6], correcting optics, and providing path length adjustments. Modeling of all 36 H-dipole magnets under contract with Elytt Energy has been completed. Four common dipoles, two of which are needed for next year’s Fractional Arc Test, will be added to the order with Elytt. The design of these magnets is underway. This report describes the findings of the tracking studies of the 36 H-dipoles and gives the status of the common dipoles.
Understanding the properties of solvent-swollen block copolymer (BCP) microdomains is important for better solvent-based control of microdomain morphology, orientation, and permeability. In this study, single-molecule tracking (SMT) was explored to assess the permeability and transverse width of individual cylindrical microdomains in solvent-swollen polystyrene- block -poly(ethylene oxide) (PS-b-PEO) films. PS-b-PEO films comprising shear-elongated cylindrical PEO microdomains were prepared by sandwiching its benzene or tetrahydrofuran (THF) solution between two glass substrates. In this paper, SMT measurements were performed at different drying times to investigate the effects of solvent evaporation on the microdomain properties. SMT data showed one-dimensional (1D) motions of single fluorescent molecules (sulforhodamine B) based on their diffusion within the cylindrical microdomains. Microdomain permeability and transverse width were assessed from the single-molecule diffusion coefficients (D SMT ) and transverse variance of the 1D trajectories (σ δ 2 ), respectively. The D SMT and σ δ 2 values from individual 1D trajectories were widely distributed with no evidence of correlation on a single molecule basis, possibly because the individual microdomains in a film were swollen to different extents. On average, microdomain permeability (D) and effective radius (r) gradually decreased within the first 3 days of drying due to solvent evaporation, and changed negligibly thereafter. PS-b-PEO films prepared from THF solutions exhibited larger changes in D and r as compared with those from benzene solutions due to the better swelling of the PEO microdomains by THF. Importantly, changes in D were more prominent than those in r, suggesting that the permeability of the PEO microdomains is very susceptible to the presence of solvent. Finally, these results reveal the unique capability of SMT to assess the properties of individual cylindrical microdomains in a solvent-swollen BCP film.
In the majority of cases, the primary means of information input to operators in nuclear power plants (NPPs) control rooms is through the visual channel. In this study, eye movement patterns of NPP operators are analyzed with eye tracking data obtained from simulator-based experimental studies. Two eye tracking measures of attentional-resource effectiveness in monitoring and detection tasks in NPPs which had been developed by the authors are introduced and several applications with the two eye tracking measures are discussed for the use of the measures. The underlying principle of the measures is that information sources should be selectively attended according to their importance. One of the two measures is the fixation to importance ratio (FIR), which represents attentional resource (eye fixations) spent on an information source compared to the importance of the information source. The other measure is selective attention effectiveness (SAE), which incorporates the FIRs of all information sources. The FIR represents the effectiveness on an information source, whereas the SAE represents the overall effectiveness on all information sources. Frequency and the duration of eye fixations of an operator on information sources are used as attentional resource. Finally feasible future applications with eye tracking data were discussed in terms of plant systems automation and operator training. (authors)
It is well-known that toxic organic micropollutants (OMs) accumulate on the surfaces of microplastics. However, much remains to be learned about the exact molecular level mechanisms of OM accumulation and how these evolve as the plastics age. In this work, super-resolved single-molecule tracking (SMT) is used for the first time to investigate the accumulation of Rhodamine B (RhB) dye on fresh and artificially aged polyethylene terephthalate (PET) surfaces. PET thin films serve as models for microplastics, while RhB serves as a proxy for the OMs they accumulate. Artificial aging of the films is accomplished by exposing them in a UV-ozone chamber. Water contact angle, spectroscopic ellipsometry, and carbonyl index measurements reveal a gradual decrease in film hydrophobicity, thickness, and carbonyl content with age. Atomic force microscopy (AFM) data reveal an increase in surface roughness and confirm that the films remain largely intact and continuous across the aging times explored. In SMT experiments, wide-field fluorescence videos acquired from the water/PET interface under 7.5 pM RhB reveal both mobile and immobile dye molecules. Measurements of the frame-to-frame displacements of the dye show that diffusion occurs by a desorption-mediated mechanism and that the diffusion rate varies with PET film age. The surface density of mobile dye molecules decreases with increasing PET age, while the population of immobile molecules becomes relatively larger, suggesting an age-dependent transformation of the mechanism(s) by which the dye is accumulated. SMT data reveal that both mobile and immobile molecules repeatedly adsorb over the same surface sites, consistent with the emergence of nanoscale PET surface heterogeneity also revealed by AFM. Estimates of the adsorption coefficients are obtained using a nearest-neighbor analysis, giving values from 9.9 × 10 5 to 2.1 × 10 6 M –1 for immobile molecules and from 1.8 × 10 5 to 2.5 × 10 5 M –1 for mobile molecules on fresh and 5 min aged PET, respectively. Here, anomalous age-dependent variations in the velocity of molecular motion on the PET surface and in the population of immobile molecules are shown to correlate with changes in the strength of RhB adsorption.
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Research into the processability of NiTiHf high-temperature shape memory alloys (HTSMAs) via laser powder bed fusion (LPBF) is limited; nevertheless, these alloys show promise for applications in extreme environments. This study aims to address this limitation by investigating the printability of four NiTiHf alloys with varying Hf content (1, 2, 15, and 20 at. %) to assess their suitability for LPBF applications. Solidification cracking is one of the main limiting factors in LPBF processes, which occurs during the final stage of solidification. To investigate the effect of alloy composition on printability, this study focuses on this defect via a combination of computational modeling and experimental validation. To this end, solidification cracking susceptibility is calculated as Kou’s index and Scheil–Gulliver model, implemented in Thermo-Calc/2022a software. An innovative powder-free experimental method through laser remelting was conducted on bare NiTiHf ingots to validate the parameter impacts of the LPBF process. The result is the processability window with no cracking likelihood under diverse LPBF conditions, including laser power and scan speed. This comprehensive investigation enhances our understanding of the processability challenges and opportunities for NiTiHf HTSMAs in advanced engineering applications.
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Explore the source record for details and available documents.
Explore the source record for details and available documents.
Assessing the potential impacts of proposed offshore wind farm developments on seabird populations requires estimation of nocturnal flight activity of seabirds for input into collision risk models. One of the seabirds considered most at risk from collision with offshore wind turbines is the northern gannet Morus bassanus. The recommended correction for gannet nocturnal flight activity is currently a highly precautionary value. Here we use data from tracking studies to derive evidence-based correction factors for nocturnal flight activity of adult gannets during the breeding and nonbreeding seasons, and of immature gannets during the summer prospecting phase. Flight and diving activity of gannets was minimal during the night, astronomical and nautical twilight, for adults during the breeding season and nonbreeding season, and for immatures. Some flight activity occurred during the short period of civil twilight, but on average at about half the level seen during the day. Based on evidence from numerous tracking studies, we recommend that precautionary values of the nocturnal (sunset to sunrise) flight activity factor for estimating collision risk should be 8% of daytime flight activity during the breeding season and 3% of daytime flight activity during the nonbreeding season. Use of these evidence-based correction factors will improve the accuracy, and reduce the uncertainty of collision risk models, providing a more reliable assessment of the impacts of offshore wind farms on gannets.
The two common dipole magnets in each of the two CBETA splitter sections serve to direct the beams of 42, 78, 114 and 150 MeV from the linac or FFAG return loop exit into the separate splitter lines for path length adjustment and to direct the beams from the splitter into the linac or FFAG return loop entrance. Here we report the results of design and tracking studies based on the Opera V18R2 software. The choice of the H-magnet design included consideration of using the coil design developed for the internal splitter H-dipoles by Elytt Energy. Considerations of transverse space constraints and the bend angle of about 30 degrees for the 42-MeV beam led to the adoption of a T-shape for the pole. The XYZ magnet dimensions are 34 × 42 × 16 cm. The central field value is 3.6-3.9 kG, but the magnet can operate as high as 4.9 kG, allowing for tests of a beam energy as high as 54 MeV in the S1 splitter line. We include results of tracking studies showing optimal placement of the magnets based on bend angle uniformity for the four beam energies. The project now proceeds to the full engineering design and fabrication to be performed by Elytt Energy.
Co-processing bio-oils with petroleum-derived feeds in the existing multitrillion dollar refining and distribution infrastructure is an attractive option for introducing renewable energy into the fuels marketplace. Considerable research on co-processing bio-oils and vacuum gas oil (VGO) in fluid catalytic cracking units (FCC) using equilibrium catalysts (E-Cats) demonstrated that biomass-derived molecules decreased activity of and increased carbon laydown on E-Cat. In this work, 13 C-labeled biomass was co-processed with VGO using either an E-Cat or a proprietary zeolite Johnson Matthey catalyst (CP758), which is optimzed for upgrading biomass vapors in a riser reactor, to evaluate the fate of biogenic carbon in FCC products. The results from both catalysts indicate that biogenic carbon was incorporated into alkenes and aromatic hydrocarbons. While no biogenic carbon was found in linear alkanes, it was observed in cycloalkanes during experiments with E-Cat but not with CP758. All produced CO2 was biogenic as was most of the carbon laydown on the catalysts. Several partially deoxygenated biomass compounds, such as alkylphenols and benzofurans, unexpectedly contained small amounts of carbon from VGO. Although this study was conducted with labeled biomass and not bio-oil, it provides insights to reaction mechanisms for co-processing bio-oil and VGO in an FCC, which is required to develop catalysts that efficiently convert bio-oil components during FCC co-processing. This work also demonstrates that comprehensive catalyst development utilizing both biomass- and fossil-derived feeds is required to maximize the incorporation of biogenic carbon into transportation fuels.
Fission track thermochronology is routinely used to investigate the thermal history of sedimentary basins, as well as tectonic uplift and denudation rates. While the effect of temperature on fission track annealing has been studied extensively to calibrate the application of the technique, the effect of pressure during annealing is generally considered to be negligible. However, a previous study suggested elevated pressure results in a significantly different annealing behaviour that was previously unknown. Here, we present a method to study track annealing in situ under high pressure by using synchrotron- based small angle x-ray scattering (SAXS). To simulate fission tracks in a controlled environment, ion tracks were created in apatite from Durango, Mexico using 2 GeV Au or Bi ions provided by an ion accelerator facility. Samples were annealed at 250°C at approximately 1 GPa pressure using diamond anvil cells (DAcs) with heating capabilities. Additional in situ annealing experiments at ambient pressure and temperatures between 320 and 390°C were performed for comparison. At elevated pressure a significantly accelerated annealing rate of the tracks was observed compared with annealing at ambient pressure. However, when extrapolated to geologically relevant temperatures and pressures, the effects become very small. The measurement methodology presented provides a new avenue to study materials behaviour in extreme environments.
ABSTRACT Body size varies widely among species, populations and individuals, depending on the environment. Transitioning between proliferation and differentiation is a crucial determinant of final organ size, but how the timing of this transition is established and maintained remains unknown. Using cell proliferation markers and genetic analysis, we show that CHIQUITA1 (CHIQ1) is required to maintain the timing of the transition from proliferation to differentiation in Arabidopsis thaliana. Combining kinematic and cell lineage-tracking studies, we found that the number of actively dividing cells in chiquita1-1 plants decreases prematurely compared with wild-type plants, suggesting CHIQ1 maintains the proliferative capacity in dividing cells and ensures that cells divide a specific number of times. CHIQ1 belongs to a plant-specific gene family of unknown molecular function and genetically interacts with three close members of its family to control the timing of proliferation exit. Our work reveals the interdependency between cellular and organ-level processes underlying final organ size determination.
This study from the National Academies of Sciences, Engineering, and Medicine was launched to explore the foundational research gaps and opportunities for digital twins. As part of the information gathering process, the committee organized three targeted workshops—in engineering, climate sciences, and biomedical sciences—to better understand domain-specific nuances and barriers to developing digital twins. These sessions enabled cross-sector experts to surface field-specific needs, challenges, and open questions related to digital twins. Thousands of participants across multiple domains engaged in the discussions, which workshops were summarized in three separate Proceedings-in-Brief.