Materials Data on TaAgF6 by Materials Project
AgTaF6 crystallizes in the tetragonal P4_2/mcm space group. The structure is three-dimensional. Ta5+ is bonded in an octahedral geometry to six F1- atoms. All Ta–F bond lengths are 1.93 Å. Ag1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are four shorter (2.49 Å) and four longer (2.96 Å) Ag–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Ta5+ and two equivalent Ag1+ atoms. In the second F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ta5+ and one Ag1+ atom.
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