Materials Data on Tb2S2F by Materials Project
Tb2S2F is Cyanogen Chloride-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Tb2S2F cluster. Tb is bonded in a linear geometry to one S and one F atom. The Tb–S bond length is 2.54 Å. The Tb–F bond length is 2.25 Å. S is bonded in a single-bond geometry to one Tb atom. F is bonded in a linear geometry to two equivalent Tb atoms.
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