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Materials Data on TbInPt4 by Materials Project

TbPt4In is Cubic Laves-derived structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Tb3+ is bonded in a 12-coordinate geometry to twelve equivalent Pt1- atoms. All Tb–Pt bond lengths are 3.18 Å. Pt1- is bonded to three equivalent Tb3+, six equivalent Pt1-, and three equivalent In1+ atoms to form a mixture of corner, edge, and face-sharing PtTb3In3Pt6 cuboctahedra. There are three shorter (2.70 Å) and three longer (2.72 Å) Pt–Pt bond lengths. All Pt–In bond lengths are 3.17 Å. In1+ is bonded in a 12-coordinate geometry to twelve equivalent Pt1- atoms.

36 MATERIALS SCIENCE↗